لیڈی ڈیانا
جوملک ابھی کچھ عرصہ تک دنیا کے بہت بڑے حصّے پرحکمراں تھا اور جس ملک کے باشندوں کواپنے ملک کی تہذیب اورانسانیت پر بڑافخروناز تھااس ملک کی ملکہ ڈائنا اپنے خاوند شہزادہ پرنس چارلس کی اپنے سے بے وفائی اوردوسری بے نکاحی عورتوں کے ساتھ معاشقے سے پریشان ہوکر اس سے علیحدگی وطلاق حاصل کرنے پربالآخر مجبورہوئی اورپھر جب اس نے اپنی طلاق کے بعد شہزادی ملکہ نے کسی دوسرے مرد سے عشق کی پینگیں بڑھائیں تووہ کسی کار حادثہ شکار ہوکر ملک الموت کے آغوش میں جاپہنچی۔یہ ہے مہذب ملک کے لوگوں کاکردار ․․․ دوسرے لفظوں میں ماڈرن انسانوں کے کنگ میکرس․․․مغربی ملکوں کے اخلاق و انسانیت کاحال وخاکہ، جہاں مرد کے لیے کوئی قید ہے کہ وہ کسی سے بھی کوئی تعلق قائم کرے چاہے کسی بھی قسم کااورنہ ہی عورت کے لیے کوئی پابندی ہے کہ وہ کسی ضابطہ میں مقید ہونے کی تکلیف گوارہ کرے۔پرنس چارلس اورلیڈی ڈائنا کی شادی۱۹۸۱ء میں انگلینڈ کے دارالحکومت لندن میں ہوئی تھی اورجس کے نتیجے میں دونوں کے یہاں دوبیٹے ولیم اور ہینری پیداہوئے جو اب جوانی کی دہلیز پر چڑھنے والے ہیں۔کہتے ہیں کہ پرنس چارلس ایک خاتون کومیلاپارکر کے عشق میں مبتلا ہوگئے، ان کی رنگ رلیوں کی خبریں جب شہزادی ڈائنا کے کانوں میں پڑیں توپہلے انھیں ان خبروں پریقین ہی نہیں آیامگر جب آئے دن یہ خبریں باوثوق ذرائع سے شہزادی ڈائنا کے کانوں میں چھید ڈالتی رہیں توپھراس نے بھی اپنے معاشقے شروع کردیئے اورموت سے دس بارہ دن پہلے ہی شہزادی ڈائنا کی محبت میں پھنسے ہوئے ایک مصری مسلمان ارب پتی مسٹرڈوڈی الفہد تھے جن کے والد کامغربی ممالک کے بڑے بڑے شہروں میں ڈیپارٹمینٹل اسٹور ہوٹلس وغیرہ کاکاروبار ہے جن کے یہاں رات بھی دن کی روشنی کے مانند ہے اورجن کا ہردن ہررات عشق کی رنگینیوں...
Women are confronted with a lot of problems. In different parts of the world, some social and cultural attitudes still discourage the women from getting their established and assigned rights. The factors which are responsible for this phenomenon include societal norms, orthodoxy and some social customs contrary to islamic instructions. For instance, discrimination against women could be in terms of inadequate nutrition, denial or limited access to education, health and property rights, child labor, domestic violence and forceful marriage. So far as the Islamic instructions are concerned, these are derived from Quran and Sunnah and clearly describe women’s rights but, due to some socio-religious customs and undesirable behaviors the societal status and role of women have been badly affected. An international document, the convention on the elimination of all forms of discrimination against women also lists the rights of all girls and women. CEDAW recommends that all discriminations against girls and women must be ended. In this paper, the terms have been analyzed in the context of islamic instructions and teachings, in order to provide academic material for bringing positive change in the society.
In this study, polymer/silica hybrid compositeswere developed using grafting techniques for potential applications as adsorbent, heterogeneous catalyst, and ion exchange resin. Two commonly used grafting techniques i.e., radiation-induced grafting and emulsion graft polymerization have been explored to modify the surface of the commercially available silica microparticles with different monomers to fabricate composite materials for environmental applications. The mesoporous silica particles with high surface area, tunable pore size, and narrow pore size distribution were modified by treating with vinyltriethoxysilane to introduce polymerizable vinyl functionality on the particle surface for in-situ polymerization of various monomers to achieve polymer/silica hybrid composites. Silica/poly(acrylonitrile) and silica/polystyrene hybrid composites were fabricated by in-situ grafting of acrylonitrile (AN) and styrene (St), from surface of the modified silica (MS) microparticles, respectively. Radiation induced grafting was achieved by using the Co-60 irradiator. Systematic and detailed studies have been carried out to investigate the influence of various grafting parameters, i.e., gamma absorbed dose and monomer concentration, on the grafting of acrylonitrile. Under the optimized conditions of 1:12 silica to monomer ratio (w/v) and 20 kGy absorbed dose, afforded the highest grafting (748 %, the value indicates the % increase in weight of the silica particles after the AN grafting). Radiation induced grafting in a solvent free system provided eco-friendly route by avoiding hazardous organic solvents. The emulsion graft polymerization AN was carried out with potassium persulfate as initiator and tween 80 as surfactant in aqueous medium. Systematic investigations were carried out to elucidate the effect of monomer, initiator, and surfactant concentration on the grafting. The optimized conditions were found to be 6% monomer, 0.15 % initiator, and 1 % surfactant concentration that afforded the highest grafting (296 %). The nitrile (-CN) groups of the grafted poly(acrylonitrile) were converted into amidoxime functionality by treating with hydroxylamine. The emulsion grafting route is free from the requirements of using higher monomer concentration, costly organic solvents, and special equipment. In 2nd study, styrene was grafted onto modified silica particles to afford silicagrafted-styrene composite via radiation induced grafting and subsequent sulfonation of the grafted polystyrene. The effect of grafting conditions, such as absorbed dose, monomer concentration, and the type of solvent used was investigated in detail. The structural and morphological investigations of the hybrid composites were carefully performed by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and Brunauer–Emmett–Teller (BET) nitrogen adsorption-desorption isotherms. The amidoxime grafted silica materials prepared were evaluated as adsorbent for Cu(II) ions from the aqueous solution and were found to have higher loading capacities of 172 mg/g and 130 mg/g, respectively, for radiation-induced and emulsion grafted samples. The hybrid materials after loading with Cu(II) ions were also employed as heterogeneous catalyst for the reductive degradation of methylene blue (MB) in the presence of NaBH4 as reductant. The reduction process followed pseudo-first-order kinetics and the rate constant (k) was calculated 0.6224 min-1. The hybrid catalyst was found to be highly effective for the degradation of MB and can be easily recovered and reused several times with no appreciable loss of catalytic activity. The ion exchange capacity (IEC) of the fabricated silica-grafted-sulfonated styrene composite resin was evaluated by ion exchange titrations (back titration method). The IEC was found to be in the range of 0.43-2.97 meq/g depending on the degree of grafting. The facile fabrication method and high IEC value could lead to potential application of the fabricated resin in ion exchange resin in waste water treatment and metal recovery.