الفت ہے اُس کو مجھ سے بھی پر مسئلہ یہ ہے
پڑتی ہے اپنی راہ میں دیوار ذات کی
This research deals with the power of language in politics, specifically in the dimension of Metaphors and the Rhetorical Philosophy of Aristotle's Ethos, which famous politicians significantly used. It determines the art of speech of three politicians, Former Prime Minister Imran Khan and former Presidents of the United States, Donald Trump and Barack Obama, who are consistently in the public eye for a great command of rhetorical language. Furthermore, the data combines and fusion of their pre-election and post-election speeches. The structure and layout of the research are first to emphasize and identify their art of speaking and delivery by comparing and contrasting these speakers and, secondly, analyzing their characteristics of how each one of them has chosen the tool of rhetorical and persuasive strategies in a unique style to make a striking impression upon the audience. These public speakers are specifically chosen for this research as they are renowned for their great competence and excellence in stump oratory, which built massive trust and created a socio-cognitive influence upon the audience’s mind. His research paradigm is based on a qualitative approach, and the design used in this study focuses on content analysis.
Green Synthesis of Fluorinated Arenes, Benzoxazinones and Benzamides Three different types of reactions (Suzuki-Miyaura reaction, carbonylation reaction and oxidation reaction) were employed to synthesize an assortment of diverse aromatic and heterocyclic compounds. Fluorinated heterocycles are frequently found in pharmaceuticals, drug candidates, ligands for transition metal catalysts and other molecular functional materials, so efficient methods for the synthesis of these compounds are of significant value. We described a selective strategy for the synthesis of poly-substituted pyridines. The Suzuki-Miyaura reaction of 2,6-dichloro-3-(trifluoromethyl)pyridine with one equivalent of aryl boronic acids resulted in site-selective formation of 2-aryl-6-chloro- 3-(trifluoromethyl)pyridine. Due to electronic reasons, the reaction takes place at the sterically more hindered position. The reactions proceeded smoothly in the absence of phosphine ligands. A general and convenient methodology for 2-amino benzoxazinones synthesis has been developed. Radially available 2-bromoanilines and isocyanates were used as substrates and diverse products have been prepared in good yields. Notably, Mo(CO)6 as a solid CO source was applied instead of gas. x A general procedure for oxidation of both benzyl alcohols and alkyl alcohols to primary amides under catalyst free conditions has been developed. More than 25 examples of primary amides were produced from their corresponding alcohols in moderate to excellent yields. This is a practical procedure for primary amides synthesis, water and tert-butanol are the only by-products.