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Synthesis and Characterization of Copper Ii Complexes With Diamines and Thiolates

Thesis Info

Author

Khurram

Department

Chemistry Department UET

Institute

University of Engineering and Technology

Institute Type

Public

Campus Location

UET Main Campus

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2007

Thesis Completion Status

Completed

Page

83 . HB.

Subject

Chemical engineering

Language

English

Other

Call No: 669.305 K 45 S

Added

2021-02-17 19:49:13

Modified

2023-02-17 21:08:06

ARI ID

1676712394210

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جے کوئی آوے تینوں چج

جے کوئی تینوں آوے چج
عشقے توں جا بیبا بھج
جھوٹا ایں تے چپ کر بہہ
سچا ہیں بن بدل گج
جے اوہ جاوے نظریں آ
ویکھ کے اکھیاں جاون رج
عظمت کالی کملی دی
جو رکھدی اے عیباں دی لج
ڈِھڈ دی گل سناویں ہا
اینویں لا نہ جھوٹے پج
جنہوں عشق حضورؐ دا اے
اونہاں دے نت ہوندے حج

الحديث الضعيف وما يتعلق به من الأحكام

Legitimation among scholars, since they fall to category of hadith dho’if (weak). Therefrom, several scholars argued that we might use them for hujjah mutlaq (absolute argumentation), while some others said it might be wiser not to use them at all. Yet there is also another opinion which said it could be used under special conditions. Based on this, this study aims to uncover and shed light the disagreements above scientifically, as well as to find he differences and the influence of the jurisprudence of law-making (fiqh). Then, the researchers sought to raise a strong opinion based on the arguments presented in the thesis, so which the researchers and or anyone who wants to practice the Hadith may find helpful.

Phylogenetic Relationships in Apocynaceae Based on Both Nuclear and Plastid Molecular Datasets

The phylogenetic relationships within Apocynaceae were investigated in the present study. In addition trnL-F intron-spacer region and atpB promoter, a part of PHYA exon, a low-copy nuclear gene were sequenced from Apocynaceae. Different taxa of the family were collected from Pakistan and different regions of the world, representing major groups of the family. Separate phylogenetic trees were constructed using trnL-F and PHYA sequences and then combined datasets were used for simultaneous analysis. In the separate trnL-F analyses (comprised of 178 taxa with updated nomenclature) both parsimony and Bayesian, yield a number of stable clades, but placement of tribes (Vinceae, Tabernaemontaneae, Hunterieae and Melodineae) in Rauvolfioideae is uncertain and lack high level of support. A clade comprising Ceropegieae and Marsdenieae receives good support confirming the monophyly of both tribes. The grouping of taxa in Asclepiadeae is not satisfactory to define a subtribal classification. Malagasy Cynanchum group forms a separate clade in both analyses while the monophyly of New World Cynanchineae is not supported here. In the combined phylogenetic analyses, 112 taxa were included representing most major caldes in Apocynaceae. The study confirms that Periplocoideae are nested within Apocynoideae. The APSA clade (Apocynoideae, Periplocoideae, Secamonoideae and Asclepiadoideae) is strongly supported here, but the crown clade of Apocynaceae (comprised of subfamilies Asclepiadoideae, Secamonoideae, Periplocoideae and Echiteae, Mesechiteae, Odontadenieae and Apocyneae of Apocynoideae) has only moderate support. The present study places Periplocoideae as part of the sister group to the rest of the crown clade and the tribe Baisseeae emerges as sister group of Secamonoideae-Asclepiadoideae clade. Old World Cynanchinae form a well-supported clade with the New World MOG (Metastelmatinae, Oxypetalinae and Gonolobinae) tribes rather than with the largely Old World Asclepiadinae and Tylophorinae, as suggested by earlier studies. By addition of atpB promoter sequences of Rauvolfioideae’s taxa in combined dataset (trnL-F and PHYA), the inter-generic resolution was not improved in the subfamily. In the present study, resolution among most groups (such as inter-tribal relationships of Asclepiadoideae) is improved in combined analyses as compared to previous phylogenies, based on only plastid regions. However, there is a need to sequence vmore nuclear loci like PHYA from greater number of taxa to further improve relationships in the family.