دنیا اس وقت گلوبل وِلج بن چکی ہے۔ ایک دوسرے سے آزادانہ تجارت ،دفاع،تعلیم ، ٹیکنالوجی ، توانائی اور ماہرین کے تبادلوں کے معاہدے ہو رہے ہیں۔کوئی بھی ملک معاشرتی ، معاشی، تجارتی اور سیاسی طور پر ایک دوسرے کے رابطے اور تعاون کے بغیر نہیں چل سکتا اور یہ وقت کی ضرورت بھی ہے کہ ایک دوسرے کے ساتھ اچھے تعلقات رکھے جائیں ۔ دفاع ، توانائی ، تعلیم ، جدیدٹیکنالوجی ، تجارت، ماہرین اور قرضوں کی وجہ سےمسلمان ممالک عالمی برادری کے ساتھ تعاون پر مجبور ہیں حالانکہ سب سے زیادہ وسائل مسلمانوں کے پاس ہیں لیکن ان وسائل کوصحیح طورپر استعمال نہ کرنے اور آپس میں اتفاق واتحاد نہ ہونے اورصحیح منصوبہ بندی نہ کرنے کی وجہ سے عالمی ادارے اور عالمی برادری مسلمانوں سے اپنی مرضی کے مطابق کام کرواتی ہے، پا لیسیاں تبدیل کرواتی ہے اور ان کی ہدایات پر عمل کرنا ہماری حکومتوں ومقتدرشخصیات کی مجبوری ہے۔ حدود و قصاص سے متعلق قانون سازی اور ان قوانین پر عمل درآمد کے سلسلے میں مسلم دنیا کو بین الاقوامی طور پرعالمی برادری کے رویوں کی وجہ سے کافی مشکلات کا سامنا ہے ۔ یہ مشکلات اور مسائل مندرجہ ذیل ہیں:
Islamic law consists hundreds of rulings that encourages the trends and cultural norms of a society in one or other. Similarly, it also strongly confine such mannerisms and social traits, though considers righteous and good, which affect the order of society and may the cause of rights exploitation of any gender. Sharia’s Teachings counts it illegitimate & unlawful. “Honour Killing” is one of the prevailed custom across the nation with different local names, extremely brutal act, violating not only sharia’s law but also the reflection of mercilessness and inhumanity. Regrettably, in Pakistan this awful deed is measured as an act of appreciation and is not only regarded likeable and acceptable but also considered a thing to be proud of. This study mainly focus on highlighting the sharia’s rulings about the nature of Honour killings along with disclosing distractions extent of prevailed custom from the main stream of Islamic law coupled with emphasis on administrative loopholes of the conventional justice system of Government of Pakistan in this regard.
Lanthanide complexes play a crucial role both stoichiometrically and clinically. The best known Gadolinium complexes are use in cancer therapy, but due to high toxicity its activity is not always satisfactory and side effects are frequently encountered. The aim of present work is to identify noval metal based complexes with reported heterocyclic ligand which are cheaper and easily available in market. If ligand is much more expensive then it not attractive for large scale of application in industry. No doubt much of the interest arises from the potential commercial importance of lanthanide complexes however most of the earlier work was concerned with the preparative aspect of organometallic chemistry. The present work focused on the development of metal based drugs that could act against large number of strains of bacteria and fungus, available from Institute of Agriculture Science University of the Punjab Lahore.New metal ion complexes of Erbium and Praseodymium with easily synthesized hetrocyclic ligands are prepared in search of interesting biological activity. Metal complexes of lanthanide as well as transition metals are synthesized and characterized by the use of spectroscopic methods, elemental analysis, high performance liquid chromatography and thermo gravimetric analysis. Most of the complexes synthesized in this work were tested for series of biological assay. In particular lanthanide complexes exhibit excellent antibacterial and anti-fungal activity as compare to transition metal complexes which show moderate activity against tested microbs. By considering the stability of Lanthanides complexes new metal chelates are synthesized. These complexes acts as effective catalyst in many reactions. My work aims at the study of thermal degradation and stability of synthetic compounds. The compounds exhibited mainly two stage degradation. The weight loss characterized by low activation energy correspond to loss of moisture. The major degradation stage represents a loss of high boiling volatile components which are observed in case of lanthanide complexes. The lanthanide complexes are more stable which is shown by TGA analysis, it means ionic breaking occurs at high temperature. Much of the interest during my research project is to determine and separate metal cations in much less time, so a rapid simple and reliable technique has been developed by HPLC. The different parameters such as PH during extraction, solvent mobile phase and type of columns used is studied. The retention time for elution is different for different complexes, still I am working on other lanthanide metals to synthesize complexes in order to bring advancement in organometallic chemistry and to enhance its applications in biomedical sciences.