مقدراں دی کھیڈ
ناہید اک وڈے سرکاری افسر دی اکلی اولاد سی۔ ایس لئی اوس دی پرورش بہت ای چنگے ڈھنگ نال ہوئی اوس نوں ماں تے پیو دا رجھواں پیار وی ملیا۔ جدوں اوس نے بی ایس سی دا امتحان دتا تاں اوس دے گھر کئی رشتے آنا شروع ہوگئے۔ اک دن ناہید دی ماں دی سہیلی اوہناں دے گھر آئی تے مینوں اپنے پتر اعجاز لئی منگ لیا۔ حالے اوہدا نتیجہ وی نئیں سی آیا کہ اوہ ناہید اعجاز بن گئی۔
اعجاز اک چنگا، سوہنا تے کماؤ پتر سی۔ گھر دے سارے جی ناہید دا خیال رکھدے سن۔ کیوں جے اعجاز اک سرکاری ملازم سی ایس لئی اک سال لنگھن دا پتہ وی نہ لگا۔ ویاہ توں اک سال بعد میں اک پتر دی دی ماں بن گئی۔ پتر دا ناں آصف رکھیا گیا۔ آصف دے جمن تے سارے گھر والے خاص کر سس سوہرا تے جیٹھانی بہت خوش سن۔ اوس دی وڈی وجہ ایہہ سی کہ میرے جیٹھ دی کوئی اولاد نئیں سی۔ سارے ای آصف نال انتہا دا پیار کردے سن۔
ایہناں دناں وچ بہت کم ہوون پاروں اعجاز بوہتا مصروف ہوگیا، کدے رات نوں چھیتی گھر...
The way the religion of Islam has emphasized the human rights, might be any other religion has given importance to this very specific topic. Although in Islam, there has no any chapter making been made in Quran and hadith on the permanent bases on the topic of basic human rights, yet if some search is made to find out these Quran and Sunnah, these are also present in expended form in various places and along with these guided principles are also present there. In Quran there is admonition in many places for the protection of human soul, goods and honor as well. Whereas Hadith along with the other various teachings, specifically on the eve of the last sermon known as ( Khutba hajja tul wida) of the Rasool(PBUH) the prescribed charter of human rights is enough to highlight its importance, but no distinctive laws are cited with a special regarded to children. Anyhow, in 18th century, issues relevant to children came into view those also became the cause of many movements and all the countries are formulated unanimous laws which are still being applied. In present era, the social issues of the children are becoming obnoxious severe. On the behalf of these issues their growth, training and many other facts of life are also attention catching. In this article, an analysis of Islamic and International laws with respect to children will be made and those causes will also be cited due to which social issues of children are continuously being generated.
Phthalonitrile resins are high temperature thermosetting polymers, which are considered ideals materials for marine, aerospace, and electronic applications. The synthesis of phthalonitrile monomers with self-catalyzing nature and with large processing window – defined as the temperature between the melting temperature of the monomer and the gelation temperature of the polymer network–, are gaining much more importance because of ease in processability and high thermal stability. In the present study, some novel phthalonitrile resins were synthesized using ortho- linked phthalonitrile monomers and self-catalyzing phthalonitrile monomers with different linkages such as: ether, imide-ether, and amide-ether between the reactive ends. All the synthesized monomers were characterized by spectroscopic techniques such as FT-IR, 1 H-NMR and 13 C-NMR. FT-IR indicated absorption peaks around 1522 and 1355 cm -1 and around 1010 cm -1 indicated the formation of triazine and phthalocynine rings (heterocyclic rings formed as a result polymerization) respectively after post curing. The thermal analyses were carried using DSC, TGA, DMA, and Rheometery. DSC and rheometric studies showed that the monomers with ortho linkages have low melting point and high crosslinking temperature. In self-catalyzed monomers, the monomers having amino group at ortho position or 1,2-linked (ortho) monomers have broad processing window. The complex viscosity (η*) was very low (<1 Pa.s) in between melting and the crosslinking temperature, which is highly suitable for resin transfer molding, resin infusion molding, and filament winding. TGA studies revealed that the resin synthesized from the monomer with heterocyclic ring shows high thermal stability and residual mass (char yield). The thermal stability of the polymer having ether or imide-ether linkages are nearly the same but more than the polymer having amide-ether linkage, indicating the effect of crosslinking density and structural changes. DMA measurements showed that storage muduli (E'') and glass transition temperature (Tg) enhance with the increase of curing temperature. These meaurements also indicated that the polymers having imide-ether and amide-ether linkages have higher storage moduli than the polymers have only ether linkages.