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Synthesis and Characterization of Thiourea Based Cationic and Non-Ionic Surfactants

Thesis Info

Author

Ahmad Naveed

Department

Department of Chemistry, QAUid-I-Azam University

Program

Mphil

Institute

Quaid-i-Azam University

Institute Type

Public

City

Islamabad

Province

Islamabad

Country

Pakistan

Thesis Completing Year

2013

Thesis Completion Status

Completed

Page

72

Subject

Chemistry

Language

English

Other

Call No: Diss. M.Phil / CHE/1167

Added

2021-02-17 19:49:13

Modified

2023-02-19 12:33:56

ARI ID

1676715168225

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ہوٹل والے کا بچہ

ہوٹل والے کا بچہ

اک ہوٹل والا بے چارہ
چائے ہے بناتا دن سارا
ہوٹل کا چولہا جلتا ہے
تو گھر کا چولہا چلتا ہے
اُس کا چھوٹا سا بیٹا ہے
دن سارا چائے دیتا ہے

برتن دھوتا تھک جاتا ہے
چائے دے دے اَک جاتا ہے
ہم دن بھر چائے پیتے ہیں
سب چھوٹو چھوٹو کہتے ہیں

اُس کے ہم عمر سبھی بچے
جاتے ہیں سکول اپنے اپنے
ہر شام پتنگ اڑاتے ہیں
پیزا ، برگر بھی کھاتے ہیں
کھیلیں ، کودیں ، بھاگیں ، دوڑیں
اک دوجے کے دھاگے توڑیں
چائے دینا ، برتن دھونا
کیا اُس بچے کی قسمت ہے؟

کتنے ایسے بچے ہیں جو
چھوٹو ، نکّو ، ساجو ، طوطی
بھولا ، بالا ، کالا ، جیلا
جانے کیا کیا کہلاتے ہیں
بچے یہ کہاں سے آتے ہیں؟

M.H. Panhwar as a Historian

The scope of this article is to find out the strengths and weaknesses of M.H. Panhwar’s historical work and to compare it with other scholars of Sindh. He is the initiator of scientific history writing of Sindh and the only historian who tried to uncover the face behind the social organisation of Sindh. According to him, ‘History is the history of production, control over the means of production and production to its final distribution’. The history is more about people than that of the ruling class as people are makers of history. He had vision to analyze things in their correct historical perspective and, in this context, he took support of archeology, as it is the source of scientific truth. Writing history with data acquired through carbon testing is a new phenomenon in Sindh, which was locally introduced by M. H Panhwar.1 M. H. Panhwar, therefore, was one of the pioneers in giving a new meaning to history by including both ruling elites and the common folk, progressive science, crop technology, forest, wildlife, etc.2 He was the first to throw light on areas which were ignored by other historians. According to him, history written before him is full of the accounts of the rulers’ role in relation to their nobles and foes, battles they fought, attacks, palace plotting, mausoleums, folklore, fiction and so on. Accounts regarding contemporary climate, environments, diversion of rivers, courses and the resultant ruination of irrigation systems, migrations, shifting of people, occupations, social life of the populace etc. Found little room in written histories. For instance changes in production and its means, administration and justice, agriculture, land, animal husbandry, irrigation sources and methods of mining, metallurgy, industry and industrial goods, matrimonial institutions, family and children, houses and interiors, art, architecture, archaeology, personal appearance, dresses, ornaments, foods and drinks, taxes, coins and currency, science and technology, foreign contacts, international trades and traders, routes of trades, religious beliefs, philosophy, hygiene, medicine and doctors, superstitions, common citizens, economic conditions, historical geography of bygone ages, classes of work and their relation with one another, household life, customs, entertainments, pastimes, leisure, attitude of man to nature, languages, literature, literary contacts with outside word, learning and thoughts, status of women and children in affluence and extreme poverty.3 Hence, in real sense M.H Panhwar was scholar of Haig’s Raverty’s and Lambrick’s calibre.

Effect of Processing Methods and Antioxidants on the Reduction of Aflatoxins in Red Chillies Capsicum Annuum L.

Chili is an important spice and used as salad, complementary dish, medicine, industrial product, or as decoration. It is consumed as fresh, dry, powder, paste or as sauce. It enhances food palatability, inducing the consumption of other foods. It is a rich source of Vitamin A & C. In Asia, chili is an important component in the cropping system. In terms of area, it is ranked first in Asia and third in the world as most important vegetable. Chilies are subject to various pest and disease constraints to optimal production. The contamination of the crops with mycotoxins from the growth of Aspergillus flavus and/or Aspergillus parasiticus is one of the most serious problems. Mycotoxins are secondary metabolites of fungi. Due to the widespread distribution of fungi in the environment, mycotoxins are considered to be one of the most important contaminants of foods and feeds. Aflatoxins are important class of mycotoxins. The toxins can be produced in the field prior to harvest, or alternatively, can arise due to fungal growth under poor storage conditions. Mycotoxins can produce both in temperate and tropical regions of the world, depending on the species of fungi. The extraction, clean up and analysis methodology for aflatoxins in chilies were validated and found it efficient and good in respect of recovery, reproducibility, repeatability, resolution and cost-effective. The collected chili samples from Faisalabad Division, Pakistan exhibited high level of aflatoxins but after treatment with γ-irradiation, more than 95% reduction in AFB 1 and ≥ 97% in Total (∑AFB 1 + AFB 2 +AFG 1 + AFG 2 ) were observed at a dose of 6 kGy. Citric acid was effective for the reduction of AFs in chilies and reduced 89% AFB 1 and 90% total AFs in contaminated chilies. Propionic acid is also used for the reduction of AFs in red chilies and it reduced 80% AFB 1 and 76% total AFs in chilies. Antioxidants like butylated hydroxyl-anisole (BHA) and butylated hydroxyl-toluene (BHT) were effective to reduce fungal load and the of (20:20 mM) of BHA and BHT were inhibit 100% of fungal load in malt extract agar of chilies. From the results it is evident that among aflatoxin reduction techniques, γ-irradiation is a good technology to remove contaminants like AFs from chilies. The food quality of irradiated cereals was evaluated to study any chemical change in vitamin E and fungal biomass. The total biomass (CFU g -1 ) showed linear behavior as increasing the dose level of gamma irradiation. In some samples of chilies, no microflora (fungi) was observed after 72 h. of incubation. From the results however, it is revealed that with increasing γ-irradiation doses a decrease in vitamin E content was observed in chilies but this decrease is not significant (p > 0.05). In the present study, phenolics, flavonoids and antioxidant activity of chilies and selected spices (cloves, turmeric, oregano, black pepper and cinnamon) have been evaluated in the Department of Food Science, Cornell University, USA. From the results, it has been evident that chilies and spices are good source of antioxidants. Special attention is urgently needed to create awareness of the high level of AFs contamination in chilies, among farmers, consumers, and traders. Special emphasis should also be given to adopt GHP and GSP in order to minimize the toxin in chilie