اتوں بھولا وچوں ٹھگ
وکھری یار اے تیری رگ
آخر سجن ملسی آ
کجھ دیہاڑے ہور وی تگ
صبح ویلے پیندا اے بندہ
چاہ دا بھریا ہویا مگ
جے توں شملہ اچا چاہویں
لہویں نہ کسے دی پگ
مکھ سجن دا اینویں چمکے
جیویں مندری اتے نگ
اس کولوں وی نیڑے رہندا
بندیا جو تیری شہ رگ
In this article an effort has been made to describe Hazrat ‘ishah (R. A) ’s methodology of derivation of Ahkm from Holy Quran. Holy Quran and Sunnah of Holy Prophet (S. A. W) is basic source of Islamic Shar‘ah. Hazrat ‘ishah Siddqah (R. A) was the wife of the Holy Prophet (S. A. W), and the daughter of Hazrat Ab Bakr (R. A). She spent her time in learning and acquiring knowledge of the two most important sources of Islam, the Qur'an and the Sunnah of His Prophet (S. A. W). Hazrat ‘ishah (R. A) narrated 2210 Ahdth out of which 174 Ahdth are commonly agreed upon by Bukhri and Muslim. She was an ardent and zealous student of Islamic jurisprudence. She has not only described Ahdth and reported her observations of events, but interpreted them for derivation of Ahkm. Umm Al-Mu’minn Hazrat ‘ishah (R. A) is a great scholar and interpreter of Islam, providing guidance to even the greatest of the Companions (R. A) of the Holy Prophet Muhammad (S. A. W). She has not only described Ahdth and reported her observations of events, but interpreted them for derivation of Ahkm. Whenever necessary, she corrected the views of the greatest of the Companions of the Holy Prophet (S. A. W). It is thus recognized, from the earliest times in Islam, that about one-fourth of Islamic Shar‘ah is based on reports and interpretations that have come from Hazrat ‘ishah (R. A). As a teacher she had a clear and persuasive manner of speech. Hazrat ‘ishah (R. A) is a role model for women. She taught Islam many people. She was an authority on many matters of Islamic Law, especially those concerning women.
The growing demand for multi-layer ceramic capacitor (MLCCs) in electronic industry has attracted immense research interest due their high capacitance, small size, reliability and excellent high frequency characteristics. Furthermore, a decrease in the sintering temperature of BaTiO3 (BT) based compounds without too much compromise on the dielectric properties is technologically important in the fabrication of MLCCs. The objective of the present study was to investigate the effect of Li3PO4 and Li2WO4 addition on the sintering temperature and dielectric properties of BT-based ceramics for their possible applications in MLCCs. A number of compositions in the (1-x)BaTiO3–xLi3PO4 (x = 0, 0.01, 0.03, 0.05, 0.10) and (1-x)BaTiO3–xLi2WO4 (x = 0, 0.01, 0.05, 0.10) series were prepared via a solid state reaction route and characterized in terms of phase purity, microstructure and electrical properties. Both the additives were found effective in lowering the sintering temperature of BT from ~1350 ºC to ~1150 ºC. X-ray diffraction analysis revealed the formation of tetragonal BT along with BaLiPO4 at x = 0.01-0.05 and another additional secondary LiPO3 phase at x = 0.10 in the case of (1-x)BaTiO3–xLi3PO4. The Li2WO4 added BT samples revealed the formation of tetragonal BT with an additional phase BaWO4 at x = 0.01-0.10. The dielectric constant for Li3PO4 added samples decreased from ~4288 to ~3600, remnant polarization from 6.70 μC/cm2 to 3 μC/cm2 and coercive field from 3.32 kV/cm to 2.5 kV/cm with an increase in x from 0 to 0.05. In the case of Li2WO4 added samples, the dielectric constant decreased from ~4288 to ~1064. The Curie temperature (Tc) peak of Li2WO4 added samples became more diffused and shifted towards room temperature with an increase in x from 0 to 0.10. The IV remnant polarization of Li2WO4 added samples decreased from ~6.70 μC/cm2 to ~2 μC/cm2 while the coercive field increased from ~3.32 kV/cm to ~7.5 kV/cm, when x was increased from 0 to 0.10. Moreover, for the (1-x)BaTiO3–xLi3PO4 (x = 0, 0.01, 0.03, 0.05, 0.10) compositions, the bulk and grain boundary conductivities decreased as x was increased to 0.05, possibly due to a decrease in the grain size. While the activation energy of the grain boundary increased with an increase in x from 0.01 to 0.05 as a consequence of an increase in grain boundary area. Upon further increase in x to 0.10, the observed decrease in the activation energy (grain boundary) indicated a decrease in the concentration of grain boundaries and an increase in grain size of the secondary phases, for x = 0.10. The bulk and grain boundary conductivities of (1-x)BaTiO3–xLi2WO4 compositions also decreased with increasing x. The activation energy for the bulk decreased due to Li2WO4 addition (x = 0.01) and then increased upon further increase in the concentration of Li2WO4 (up to x = 0.05). On the other hand, activation energy for the grain boundary, initially increased with the addition of Li2WO4 (at x = 0.01) and decreased upon further increase in the concentration of the additive to x = 0.10. This may be due to the consequent increase in the concentration of the secondary phase (BaWO4) as well as a small increase in the grain size. These two electro-active regions (i.e., grain and grain boundary) having different thermal activation energies suggested two different transport mechanisms in the (1-x)BaTiO3–xLi2WO4 (where x = 0, 0.01, 0.05, and 0.10) ceramics investigated in the present study. V In conclusion, these results suggest that Li3PO4 and Li2WO4 were effective in lowering the sintering temperature for BT–based ceramics and may be considered as potential candidate materials for the fabrication of MLCCs.