External and Internal Factors of Political-Religious Violence and Pakistan’s Role: Unravel Threats for the Security of Modern Islamic State

Political scientists and Islamic philosophers have long been discussing the different phenomena of violence. This article analyzes external and internal factor of violence in Pakistan, interpreting the religious and political dimension of the violence. The presence of external and more specifically internal factors are the real threats for the security of the country. Building from theoretical approaches, I fielded two dimensions of the political-religious violence, violence inside the country and outside the country. It is found out, on the one hand, that the both dimensions can be met with the profound enforcement of the law. On the other hand, both dimensions of the violence can be the big contributory factors of violence due to the poor promulgation of the law. Unjust political-religious dispensation inside the country rise the frustration, and outside support make it fertile and leads it towards violence. It is proposed that on equity bases, political-religious deprivation and absolute deprivation of the minority elite class can be disposed of. I also come up with balanced educational system, which should be the blend of traditionalism and modernism for the fulfilment of our spiritual dimension and for the greater understanding of our political-religious outlook.

Condensation of Thiols With Amino Esters and Synthesis of Pyridyl Guanidinium Receptors As Self-Assembling Systems for the Investigation of Amino Acids Interactions in Biological Systems

A major part of this thesis comprises synthesis of pyridyl guanidinium carboxylate receptors and investigation of their self-assembling properties. It also describes synthesis of sulfenamides derived from amino esters. Chapter I provides an introduction to supramolecular chemistry, its underlying principles, types of receptors, self-assembling systems, application of supramolecular systems and also brief introduction to organosulfur compounds. Chapter II describes synthesis of pyridyl guanidinium based receptors. Chapter III includes experimental work and spectroscopic data obtained for pyridyl guanidinium based receptors and intermediates involved in their synthesis. Chapter IV describes dimerisation studies of synthesised receptors. Synthesised systems were found to be highly stable dimers in DMSO with dimerisation constants up to 8.1 × 105 M-1 and in 60% H2O/DMSO with a dimerisation constant 24.5 M-1. Chapter V includes synthesis of sulfenyl chlorides and their use in the synthesis of sulfenamides. Spectroscopic data obtained for these compounds is also a part of this chapter. Chapter VI describes general conclusions and future perspectives of the work.