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Application of Advanced Oxidation Process for Bleaching Textile Materials

Thesis Info

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Author

Arooj, Fariha

Program

PhD

Institute

University of the Punjab

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2014

Thesis Completion Status

Completed

Subject

Public Adminisration

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/2559/1/2864S.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676724511901

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This study discusses the application of ozone to bleach raw cotton fabric using both laboratory scale set up and pilot plant. The quality of ozone bleached fabric was determined in terms of CIE whiteness, absorbency, degree of polymerisation (DP), copper number (CN) and tendering factor (TF) with regard to the conventionally bleached fabric (reference material). The application of ozonation process was also extended for color stripping of dyed cotton fabric at laboratory scale. The efficiency of ozone stripping process was measured in terms of lightness (L*), lightness difference (∆L*) and total color difference (∆E*) with respect to reference (conventionally stripped fabric samples). In case of laboratory scale application of ozone bleaching process, the maximum CIE whiteness (60-62) and best quality of bleached fabric was obtained at an ozone dose of 6 g/h, pH 5 and exposure time of 45 min. Strong acidic environment (pH 2-3) and exposure time longer than 45 min though marginally improved the degree of whiteness but deteriorated the quality of the fabric as indicated by higher copper number (0.19) and TF (0.94). Statistical analysis of experimental data confirmed that process parameters (ozone dose, pH and treatment time) significantly affected the efficiency of ozone bleaching process and pH had the greatest effect on whiteness and DP of bleached fabric followed in turn by ozone dose and treatment time. The dyeing quality of ozone bleached fabric in terms of colour difference (∆L*, ∆a*, ∆b* and ∆E*) and wash fastness properties was almost similar to the reference. The ozone bleaching waterbath was also reused several times to bleach multiple lots of raw cotton fabric and results demonstrated that CIE whiteness (60) remained stable even at 20 th reuse of same waterbath. This approach reduced the pollution load of effluent and saved water and chemicals. Since the efficiency of ozone bleaching process at pilot scale was not in parallel with its laboratory scale performance, various additives were used to enhance process efficiency. The best results in terms of whiteness (63.79), absorbency (10 sec) and strength of bleached fabric were achieved with an addition of 2 g/l of surfactant at optimal process conditions (ozone dose of 50 g/h, pH 5 and ozone treatment time of 45 min). However, other additives (peracetic acid and H2O2) did not show promising results. Dyed ozone bleached fabric samples were a bit lighter (ΔL* > 0.4) than reference. The values of ΔL*, Δa* and Δb* showed minor color difference between ozone bleached fabric and reference. However, total color difference values (ΔE* = 0.13 – 1.06) were within acceptable limit (ΔE*<1). Wash fastness properties of ozone bleached fabric were identical to the reference. The whiteness of ozone bleached fabric, however, did not stand firm with increasing storage time due to the presence of aldehyde groups and ozone residues. Among various treatments performed (hot washing at 50 ◦C, rinsing at 80 ◦C, reductive treatment) to avoid the decrease in degree of whiteness of ozone bleached fabric, washing with sodium borohydride was proved as one of the best treatments for color stability. Ozone color stripping efficiency was a function of pH, ozone dose and treatment time and maximum color stripping was achieved at an ozone dose of 10 g/h, pH 5 and treatment time of 45 min. The stripping efficiency decreased as the % owf of dyed fabric increased from 2% to 4% which implied that deceolorization of dyed fabric with higher initial dye concentration required higher ozone dose and/or longer exposure time. The color stripping efficiency of ozone for fabric samples dyed at different shades was almost similar to the reference (conventional stripping method). The ozone bleaching process was proved to be environmentally friendly because it decreases water consumption (no rinsing and neutralizing treatment), it is less energy intensive (applicable at ambient temperature), and reduces effluent load (involves no chemicals).
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۔غزل

غزل ---فرحت شکور(پاکپتن)

مت پوچھ کہ ہم کیسی بلاؤں میں گھرے ہیں
بے یارو مدد گار تیرے چاہنے والے
جینے کا ہمیں حق ہے نہ مرنے کی اجازت
آنکھوں میں کوئی خواب نہ دل میں کوئی خواہش
سینچا ہے لہو دے کے سدا لالہ و گل کو
حسرت ، کبھی نفرت ، کبھی غربت ہمیں بخشی
افلاس و فلاکت کی چلی آندھیاں ہر سو
اے میرے خدا کیوں یہ میرے دیس کے باسی
سچ ، سوچ ، قدم اور قلم محدود ہیں اپنے
ہوتے ہی نہیں پست کبھی حوصلے میرے
لوٹے نہ میرے صاحب اس شہرِ فسوں جا کر
آیا نہ خیال ان کو میری صحرا گری کا
یکسر نہیں میرا ، تو رقیبوں کو مبارک
کیا پوچھتے ہو حالِ دلِ زار ہمارا
کس موڑ پہ لے آیا یہ عشق ہمیں فرحتؔ

 

خوابوں سے جو نکلے تو صداؤں میں گھرے ہیں
صحراؤں کی جاں سوز ہواؤں میں گھرے ہیں
ہم اہلِ وفا کیسی سزاؤں میں گھرے ہیں
ہم زیست کی بے رنگ خلاؤں میں گھرے ہیں
کیوں اہلِ چمن پھر بھی خزاؤں میں گھرے ہیں
ہم لوگ مقدر کی عطاؤں میں گھرے ہیں
کیوں اہلِ وطن اتنی وباؤں میں گھرے ہیں
ڈر خوف کی محبوس فضاؤں میں گھرے ہیں
ہم اہلِ سخن ایسے خداؤں میں گھرے ہیں
شاید کسی اپنے کی دُعاؤں میں گھرے ہیں
کسی دلرُبا کی دلکش اداؤں میں گھرے ہیں
کس زُلفِ گرہ گیر کی چھاؤں میں گھرے ہیں
ہم اہلِ طلب اب کہ اناؤں میں گھرے ہیں
اک یار بے وفا کی جفاؤں میں گھرے ہیں
دُکھ درد کی گھنگھور گھٹاؤں میں گھرے ہیں

ACADEMIC MOTIVATION LEVEL AND ATTITUDE TOWARDS SOCIAL STUDIES AMONG PUBLIC SCHOOL SECONDARY STUDENTS IN ZAMBOANGA SIBUGAY PHILIPPINES

In a Social Studies, students' academic motivation and attitudes will be useful to their academic progress. If a student is enthusiastic about a subject, he or she will do better in class and learn faster. There have been a lot of studies that have looked into students' academic motivation and attitudes toward social studies, but there does not appear to be any study that focuses on the learners themselves. This quantitative study aims to determine the level of academic motivation as well as the attitude toward social studies of 458 secondary students from public schools using the Academic Motivation Scale High School Version and Secondary Students Attitudes Towards Social Studies Scale. It also looked at whether there was a significant difference in academic motivation and attitude toward social studies when respondents were sorted by gender. Finally, it investigates the link between academic motivation and attitude towards social studies. Students are found to be "highly motivated" in terms of academic motivation and have a “positive attitude” toward social studies, according to the findings. Furthermore, when respondents were divided into gender groups, no significant differences in academic motivation and attitude toward social studies were found. Finally, academic motivation and attitude toward social studies show a significant favorable relationship.

Promoting Moral Values in the Social Studies Classroom

Generally people perceive moral education as vital for the overall development of children as well as essential for the welfare and development of the country they live in. Venkatiah (1998) says A nation with atomic power is not a strong nation, but a nation with strong character is indeed a strong nation. If a nation is to be strong, then the character of the people of the nation needs to be elevated. (p.12). Though there are various sources to equip children with good morals including parents, media, etc. however, the role of a teacher is considered essential by various educational thinkers and well- meaning people of society. In the context of Pakistan, people have divergent views about the teachers' roles. A majority of these people seem to be satisfied with their performance with specific reference to promote children's moral values. I thought I would ascertain the teachers' perceptions and their instructional strategies focussing on the social studies' classroom. The underlying purpose is that teachers, including myself, can devise more effective strategies keeping in view the existing practices in school. The study was carried out in a private school in Karachi and two teachers of secondary level were my respondents. The qualitative paradigm of research was used with the aim to subsume teachers' theories and practices as well as students' views and make meaning which could meet the purpose of my study. It was largely found in the process of the study that the teachers give a lot of importance to imparting moral values and try to impart them by taking help from religious sayings. They can use some strategies which are also considered effective in literature but they largely use those techniques they had learnt from their teachers and parents. Not being exposed to any professional program focusing moral values, dilemmas of syllabus completion seem to be seen to be the major hindrances in the field of teaching moral values.