Despite extant literature on job stress, little is known about the perspective of dealing with it in a cost-effective way. This research offers a more prudent approach by examining the effects of teachers’ psychological capital (Psycap) and problemfocused coping on organizational outcomes such as job stress and organizational citizenship behavior (OCB). A cross-sectional data of 384 faculty members from all over Pakistan was analyzed through structural equation modeling (SEM). The results confirmed thatpsycap played a significant role in elimination of job stress, and fostering OCB. Moreover, the current data suggested problem-focused coping to be a suppressor in the model of a research. Lastly, the research suggests possible directions for future research and concludes with a practical implications for developing teachers’ psycap and problem-focused to ensure OCB and eliminating job stress.