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Natural Colorants As Photosensitizers for Dye-Sensitized Solar Cells Dsscs for Green Enconomy

Thesis Info

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Author

Ayesha Altaf

Program

PhD

Institute

Lahore College for Women University

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2018

Thesis Completion Status

Completed

Subject

Environmental Sciences

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/10794/1/Ayesha%20Altaf_Env%20Sci_2018_LCWU_PRR.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676724881140

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Twenty five natural dyes (D1-D25) were extracted through maceration from local plants species categorized as A= D1-D6, B= D7-D17, C= D18-D20, D= D21-D22, E= D23 and F= D24-D25 on the basis of their parts used for the application in dye sensitized solar cells (DSSCs). The photo-physical and electro-chemical behaviors of natural dye were evaluated through UV-visible spectrophotometry and cyclic voltammetry respectively. The UV-Visible absorption spectrum of the individual dye extracts D1-D25 revealed two distinct bands i.e. First band corresponds to π-π* transition while the second band corresponds to intermolecular charge transfer (ICT) band. Out of all the extracted natural dyes, S. oleracea (D23-E) dye resulted in best absorption at ICT band with λmax = 662 nm having absorbance A= 0.33. Cyclic voltammetry of the dyes D1-D25 was carried out which revealed the distinct oxidation and reduction peaks. The peaks can be seen more prominently among S. oleracea (D23-E), R. tinctorum (D21-D) and H. rosa-sinensis (D1-A) dyes while rest of the dyes exhibited less prominent peaks. The photovoltaic performances of the individual dyes D1-D25 (A-F) were evaluated by fabricating the sandwich-type DSSCs with the extracted natural dyes. TiO2 coated FTO glass slides were prepared for dye adsorption. The J-V profiles showed open circuit voltage values and short circuit current density. The most promising results of photovoltaic parameters were found for solar cell fabricated with D23-E dye with Jsc= 5.38 mA/cm2 and Voc= 0.47 V followed by D21-D (Jsc=4.14; Voc= 0.36 V) and D1-A (Jsc= 5.48; Voc= 0.36 V) respectively The best sunlight to energy conversion efficiency was obtained from D23-E (η= 1.4%) dye which has better UV absorption and oxidation properties. The respective dye gave high short circuit current density and hence high photon to current efficiency was achieved. Other dyes gave the efficiency in the following order D21-D (R. tinctorum) = 1.1% > D22-D (A. tinctoria)= 1.05% > D1-A (H. rosa sinensis)= 1.02% > D17-B (S. anacardium)= 0.92 > D2-A (B. oleracea var. capitata) & D11-B (P. granatum) = 0.9% > D6-A (R. macdub)= 0.8% > D19-C (B. vulgaris) = 0.7%. Other natural dyes also showed satisfactory results. These natural dyes can easily replace conventional harmful, persistent and expensive metallic and synthetic dyes. Natural dye can be regarded as a promising candidate for low cost DSSCs fabrication with no environmental damage.
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۶۔ نکلنا خلد سے آدم کا

نکلنا خلد سے آدم کا۔۔۔

آس کی خوشبو یاس کی بد بو پرہمیشہ غالب آتی ہے

یوں محسوس ہو رہا تھا

 جیسے دل میں اِ ک آگ سی لگی ہو

اور سب کچھ اس بھٹی میں جھونک رہا ہوں

 اس بھٹی کو صرف آنسو ہی ٹھنڈا کر سکتے تھے 

لیکن !وہ بھی لب ِ مژگاں تک آتے آتے مر گئے

 کتنی مشکل سے محبت کے تارو پود سے سنہری خواب بنے تھے

مگرایک تار کے نکل جانے سے

سب خواب نیند کی وادیوں میں کہیں کھو گئے ہیں

حیف!میرے دھندلے خواب

 جو میں کسی کی آنکھوں سے دیکھ رہا تھا

 یوں لگتا ہے جیسے

میرا بھی شمار اُن سوختہ سروںمیں ہوتا ہے

جو بحرِ محبت میں بنا کشتی اور پتوار کے اتر گئے تھے

مجھے اپنی عادتوں پردکھ ہے

 جو پھر سے خراب ہو جائیں گی 

جنہیں اک عرصہ بدلنے میں لگا تھا

یہ آدم اور آدم زاد کے نصیب میں لکھا جا چکا ہے

کہ اس کا کبھی ایک ٹھکانہ ہو ہی نہیں سکتا

کبھی یہ بہشت سے نکالا جاتا ہے 

کبھی اپنے گھر سے دربدر ہوتا ہے تو کبھی شہر سے

کبھی کسی کی زندگی سے توکبھی کسی کے دل سے

یزداں نے بھی انسان کے ساتھ کیاخوب کھیل کھیلا ہے 

 اسے فاصلوں میںالجھائے رکھتا ہے

اسلامی تصوف کے مصادر اور مستشرقین كى آراء کا ایک تجزیاتی مطالعہ

The issue of the source and origin of Sufism in Islam is a complex one. A number of scholars, since the latter half of the nineteenth century have put forward conflicting claims. Earlier Orientalists thought that a Sufism developed from a single source while the latter scholars think a number of different sources should be considered as origin of Sufism. Both groups agree, however, in maintaining that Sufism is an addition to Islam and did not originally belong to Islam.  Different opinions have been presented regarding the true source of Sufism, for example, Persian, Indian, Christian, Jewish and Neo-Platonic philosophies. The present paper intends to refute these charges of external influences on Islamic Sufism and attempts to show that the real origin of Islamic Sufism lies nowhere but in the teachings of the Holy Qur’an, Sunnah of the Prophet (peace be upon him) and lives of the blessed companions of the Prophet (peace be upon him).

Effects of New Physics on Neutrino Interactions

Effects of New Physics on Neutrino Interactions We explore the effects of neutrino interactions due to new physics with the standard Lorentz structure, but with the nonstandard flavor structure in the reactor electron- antineutrino disappearance short- and medium-baseline oscillation and in the very- short-baseline scattering experiments. In both types of experiments, we explore the nonstandard interactions of neutrinos produced in the charged current neutron beta decays and, later on, when detected through inverse beta decay and through purely leptonic elastic scattering processes. In oscillation experiments, there is degeneracy between oscillations and the new interactions, whereas the scattering experiments are free from the degeneracy because of their baseline short enough to ignore the standard oscillation phenomenon. In oscillation experiments, we draw on the short-baseline Daya Bay and its future upgrade JUNO for the spectral event rate and the statistical analyses and in the scattering experiments TEXONO and its future upgrade version with improved statistical sensitivities for confidence level boundary regions of the nonstandard neutrino interaction parameters. In the oscillation experiments, we find that the average spectrum of observed events at a baseline of 50 km, in the middle of the currently favored region, provides improvement in sensitivity to new physics if combined with improved precision of input mixing parameters in independent experiments, despite of the ambiguity due to the degeneracy between new physics and oscillations in medium-baseline data. Moreover, the nonstandard interactions can enhance or suppress the sensitivity of experiments to the mass hierarchy, depending on the combination of nonstandard and the standard CP-violating phases. In the scattering experiments, we confirm that the current data of TEXONO experiment allows for new physics constraints at the detector of the same order as those currently published. The new physics phase effects are at the 5% level, noticeable in the 90% contour plots but not significantly affecting the conclusions. Based on the projected statistical sensitivities with an upgraded version of TEXONO experiment, we estimate sensitivity of new physics at both source and detector. We find that bounds on source nonstandard interaction parameters improve by an order of magnitude, but do not reach parameter space beyond current limits. On the other hand, the detector new physics sensitivity would push current limits by maximum of an order of magnitude.