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Home > Comparative Study of Various Decolorization Processes for Treatment of Synthetic Dyes

Comparative Study of Various Decolorization Processes for Treatment of Synthetic Dyes

Thesis Info

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Author

Kiran, Shumaila

Program

PhD

Institute

University of Agriculture

City

Faisalabad

Province

Punjab

Country

Pakistan

Thesis Completing Year

2012

Thesis Completion Status

Completed

Subject

Chemistry

Language

English

Link

http://prr.hec.gov.pk/jspui/handle/123456789/2126

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676725768872

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Azo dyes constitute the largest and most diverse group of dyes used in commercial applications. These dyes are carcinogenic and mutagenic in nature, as well as also create an aesthetic problem, so these must be removed before their disposal into water bodies. Various methods are in use for the decolorization of azo dyes. Every method has its own shortcomings and drawbacks. In this study, a comparative study was conducted to get the maximum decolorization of synthetic azo dyes and industrial effluents. Photo-Fenton’s process, biological and sequential methods were utilized for the decolorization of synthetic and real wastewater having azo dyes. In biological method, experiments was performed with five locally isolated indigenous white rot species, for the selection of two white rot fungal cultures based on their maximal decolorization potential. Different fermentation conditions (dye level, pH, inoculums size, temperature, mediators and metal ions) and nutritional factors (carbon and nitrogen sources) were optimized to enhance the efficiency of white rot fungal cultures for dye decolorization. In Photo-Fenton,s treatment method, the optimization of different experimental parameters (pH, FeSO4, H2O2, temperature and effects of salts) was done to get maximum decolorization (90%) of dye under study. Sequential methods were also studied) to investigate their effectiveness in the present study. The effectiveness of all treatment technologies was evaluated by water quality assurance parameters such as COD, BOD, TOC, TSS, phenolic contents ant toxicity assey, by following the standard methods of treatments. All treatments under study showed a good potential towards decolorization as well as mineralization, however, Sequential treatments showed best potential towards decolorization (up to 97%) as well as mineralization (up to 90%) of synthetic azo dyes. The uv-visible and FTIR spectral studies have shown decolorization as well as mineralization of dyes under study. An economic analysis has shown as the cost in the chemical treatment (Photo-Fenton treatment is considered mainly due to the chemicals, thus at lower doses (it is applied as a pre-treatment step), operating cost of the treatment can be saved. It was also found, that as the sequential carried out at lower dose of chemicals, so sludge production was almost negligible and the dye wastewater after sequential treatments fall within the safer limits, hence dispose off such treated water not be hazardous. Thus the overall treatment chain of Photo-Fenton oxidation followed by aerobic biological treatment could be quite effective and economical option for the treatment recalcitrant compounds like azo dyes in pilot plant scale.
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سخنان چند

سخنانِ چند
عصرِ حاضرمیں محبت کی ندرت اور مشاہدے کی گہرائی کے ساتھ اپنے خارج و باطن میں جھانک کر اور حرف ومعانی سے اپنے والہانہ لگائو سے فن شعر سے وابستگی رکھنے کی روایت کس مقام پہ ہے اس کو نقدو نظر کی دنیا کے امام ہی بہتر جانتے ہیں لیکن اس گئے گزرے دور اور عہد ناپُرساں میں قلم و قرطاس سے اپنا رشتہ مضبوطی سے قائم رکھنے والوں میں جو اہلِ قلم میں اپنے ہونے کا یقین کامل دلاتے ہیں ان میں تائب نظامی کا نام اپنی منفرد شناخت رکھتا ہے۔
ان کے اشعار میں ہمارے تہذیبی معاشرتی اورفکری رویوں کی بازگشت بڑی نمایاں ملتی ہے۔ گردوپیش کی زندگی اور اس کا منظرنامہ ان کے ہاں ایک فکری رنگ میں یوں سامنے آتا ہے کہ ہم خود شاعر کے فی بطنہہٖ موجود احساسات کے ساتھ خود کو ہم آمیز پاتے ہیں۔ فنی وفکری التزامات ہوں یا سہلِ ممتنع کے انداز میں شعرگوئی تائب نظامی اس کائنات میں اپنی ریاضت فن کے جوہر دکھلاتے نظرآتے ہیں انسانوں کی زندگی پر انسانوں ہی کے ستم ، بے رُخی اور اجارہ داریوں کے زخموں کا بیاں ہو، محبتوں کی ناسپاسی اور بے قدری کا ذکر ہو یا معاشرتی رویوں کے ہاتھوں انسانوں کے آنسوئوں کا تذکرہ ہو، یہ سب ان کی شاعری کا حسن بیاں ہے۔ سیاست کے مکروہ جہاں کے اندھیروں میں لوٹ کھسوٹ کا عالم ہو یا گئے زمانوں کی محبتوں کے مزار پہ اپنے اشکوں کا نذرانہ عقیدت ہو تائب نظامی کے ہاں ایک سلجھی ہوئی علمی روایت کے دیپ روشن نظر آتے ہیں۔
ان کے ’’صبحِ قفس ‘‘ میں حمد و نعت کے پھول ہوں یا منقبت اہلِ بیت و صحابہ کرامؓ کے روشن دیپ ہوں ان کی ارادت و عقیدت ’’قربان جائیے‘‘ کا رُوپ لیے اپنا اظہار کرتی ہے۔ اُن کی غزل...

اسلام میں تبدیلی مذہب کا مطالعہ: ایک تنقیدی تجزیہ

Muslim scholars have produced various writings in which the process of conversion to Islam has been presented in the form of narratives. However, less consideration has been given to the understanding of nature of this process. Furthermore, the elements which originate and shape this process have also been ignored in the previous studies. After analyzing the sources concerning the study of conversion to Islam, the current article argues that the previous studies, especially by the Muslim scholars, were mostly written for Daʻwah purposes. They did not encourage the analytical dimension of the conversion studies. For a grasp of the complex elements and the strategies underlying this process, the Western scholars divide religious conversion into its diverse types while providing different motifs. However, a critical analysis of their works points out that some of these types and motifs are not applicable to Islam. The current article points out the elements helpful in explaining the process of conversion to Islam keeping in line with the Holy Qur’ān and Sunnah. Moreover, this paper also purports that the study of Ḥadīth, spiritual experiences of converts, and the opinions of the scholars supports the concept of fiṭrah to be used as a framework for a thorough understanding of this process.

Isolation, Identification, Characterization and Toxicity Evaluation of Indigenous Strains and Preparation of Indigenous Bacillus Thuringiensis-Based Biopesticide Against Chickpea Pod-Borer, Helicoverpa Armigera

Bacillus thuringiensis Berliner is being used successfully as biological control agent throughout the world as a substitute of hazardous chemical insecticide in agriculture and forestry for the elimination of pests, and in human health sector for the elimination of disease vectors. In Pakistan, being an agricultural country, commercial scale production and application of biological insecticide is essential. The main objective of this study was to explore potential B. thuringiensis isolates from local environments and to produce effective and low cost biopesticides by a simple and effective process (shake flask technique/fermentation) for the control of chickpea pod-borer, Helicoverpa armigera Hübner of lepidoptera group. To achieve this objective 150 soil samples collected from different regions of Pakistan were screened and eighty one B. thuringiensis isolates were obtained from 33 (22%) soil samples, identified as B. thuringiensis by using phase contrast microscope and standard tests. These B. thuringiensis isolates contained crystal of different shapes but majority contained typical bipyramidal with cuboidal or irregular crystal. Polymerase chain reaction results indicated that 85.19% isolates was positive for cry1 gene (Lepidoptera specific) showing that cry1 gene occur frequently in our B. thuringiensis isolates. The SDS-PAGE results indicated that variations exist in the protein profile of spore-crystal of B. thuringiensis isolates but the protein profile of the majority was similar to reference standard strain. Results of preliminary screening bioassay at 500 μg toxin/mL diet indicated that toxic B. thuringiensis isolates and reference strain caused 96.55-100% whereas non-toxic caused - 7.33-45.33% mortality against 1 st instar larvae of H. armigera. Non-toxic B. thuringiensis isolates did not contain typical bipyramidal crystal. These results indicated that correlation exist between crystal morphology and toxicity to H. armigera. Bioassay results of toxic B. thuringiensis isolates indicated that LC 50 and potency of the most toxic B. thuringiensis isolate, PA-Sb-46.3 were 4.54 μg/mL, 1177515 IU/mg and relative potency 73.6. Relative potency showed that it was 73.6 times toxic than reference strain. B. thuringiensis var. kurstaki (HD-I-S-1980) viiiThe biopesticide was prepared from locally available low cost ingredients: dried beef blood, molasses and mineral salts (ZnCl 2, MgCl 2, MnCl 2, CaCl 2 and FeCl 3 ) which were used as medium for the laboratory scale production of B. thuringiensis biopesticide by shake flask technique. Indigenous B. thuringiensis isolate PA-Sb-46.3 which produced two crystals: bi-pyramidal and cuboidal was found 73.6 times toxic against H. armigera than reference strain B. thuringiensis var. kurstaki (HD-I-S-1980) was used. Medium was fermented for 72 hours at 30 ± 2 o C and 160 rpm. After 72 h fermented medium showed 95-99 % sporulation, with spore yield of 3.97 X 10 9 spore/mL and LC 50 value to 1 st instar larvae of H. armigera was 0.53 μg/mL diet. Preservatives and diluents used in the biopesticide were found to be effective when stored it at room temperature over a period of 30 months. The three years field results of biopesticide with exotic and chemical insecticides indicated that biopesticide was effective against H. armigera. These observations suggested that the biopesticide produced was effective and highly economical for the industrial scale production to manage H. armigera in Pakistan.