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Home > Effect of Li2wo4 and Li3po4 Addition on the Sintering Temperature and Dielectric Properties of Batio3-Based Ceramics

Effect of Li2wo4 and Li3po4 Addition on the Sintering Temperature and Dielectric Properties of Batio3-Based Ceramics

Thesis Info

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Author

Uzair, Muhammad

Program

PhD

Institute

University of Peshawar

City

Peshawar

Province

KPK

Country

Pakistan

Thesis Completing Year

2016

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/7325/1/Muhammad_Uzair_Physics_HSR_UoP_Peshawar_2016_10.01.2017.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676725976888

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The growing demand for multi-layer ceramic capacitor (MLCCs) in electronic industry has attracted immense research interest due their high capacitance, small size, reliability and excellent high frequency characteristics. Furthermore, a decrease in the sintering temperature of BaTiO3 (BT) based compounds without too much compromise on the dielectric properties is technologically important in the fabrication of MLCCs. The objective of the present study was to investigate the effect of Li3PO4 and Li2WO4 addition on the sintering temperature and dielectric properties of BT-based ceramics for their possible applications in MLCCs. A number of compositions in the (1-x)BaTiO3–xLi3PO4 (x = 0, 0.01, 0.03, 0.05, 0.10) and (1-x)BaTiO3–xLi2WO4 (x = 0, 0.01, 0.05, 0.10) series were prepared via a solid state reaction route and characterized in terms of phase purity, microstructure and electrical properties. Both the additives were found effective in lowering the sintering temperature of BT from ~1350 ºC to ~1150 ºC. X-ray diffraction analysis revealed the formation of tetragonal BT along with BaLiPO4 at x = 0.01-0.05 and another additional secondary LiPO3 phase at x = 0.10 in the case of (1-x)BaTiO3–xLi3PO4. The Li2WO4 added BT samples revealed the formation of tetragonal BT with an additional phase BaWO4 at x = 0.01-0.10. The dielectric constant for Li3PO4 added samples decreased from ~4288 to ~3600, remnant polarization from 6.70 μC/cm2 to 3 μC/cm2 and coercive field from 3.32 kV/cm to 2.5 kV/cm with an increase in x from 0 to 0.05. In the case of Li2WO4 added samples, the dielectric constant decreased from ~4288 to ~1064. The Curie temperature (Tc) peak of Li2WO4 added samples became more diffused and shifted towards room temperature with an increase in x from 0 to 0.10. The IV remnant polarization of Li2WO4 added samples decreased from ~6.70 μC/cm2 to ~2 μC/cm2 while the coercive field increased from ~3.32 kV/cm to ~7.5 kV/cm, when x was increased from 0 to 0.10. Moreover, for the (1-x)BaTiO3–xLi3PO4 (x = 0, 0.01, 0.03, 0.05, 0.10) compositions, the bulk and grain boundary conductivities decreased as x was increased to 0.05, possibly due to a decrease in the grain size. While the activation energy of the grain boundary increased with an increase in x from 0.01 to 0.05 as a consequence of an increase in grain boundary area. Upon further increase in x to 0.10, the observed decrease in the activation energy (grain boundary) indicated a decrease in the concentration of grain boundaries and an increase in grain size of the secondary phases, for x = 0.10. The bulk and grain boundary conductivities of (1-x)BaTiO3–xLi2WO4 compositions also decreased with increasing x. The activation energy for the bulk decreased due to Li2WO4 addition (x = 0.01) and then increased upon further increase in the concentration of Li2WO4 (up to x = 0.05). On the other hand, activation energy for the grain boundary, initially increased with the addition of Li2WO4 (at x = 0.01) and decreased upon further increase in the concentration of the additive to x = 0.10. This may be due to the consequent increase in the concentration of the secondary phase (BaWO4) as well as a small increase in the grain size. These two electro-active regions (i.e., grain and grain boundary) having different thermal activation energies suggested two different transport mechanisms in the (1-x)BaTiO3–xLi2WO4 (where x = 0, 0.01, 0.05, and 0.10) ceramics investigated in the present study. V In conclusion, these results suggest that Li3PO4 and Li2WO4 were effective in lowering the sintering temperature for BT–based ceramics and may be considered as potential candidate materials for the fabrication of MLCCs.
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حکیم محمد سعید دہلوی

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کس قدر ظالم ہاتھ تھے اور کس قدر درندہ صفت دل کا وہ انسان نہیں حیوان رہا ہوگا جس نے فرشتہ صفت ہستی، غریب انسانوں کامسیحا، ملک وملت کاخیرخواہ ،پوری انسانیت کی فلاح وبہبود گی چاہنے والا،شرافت کاپیکر مجسم، حکیم محمدسعید دہلوی پر گولیاں چلا کر آن کی آن میں ان کو شہید کردیا۔اناﷲ وانا الیہ راجعون۔
جیسے ہی یہ خبر عوام الناس تک پہنچی کہ کراچی پاکستان میں ہمدرد دواخانہ کے مطب سے فراغت کے بعد جب حکیم محمد سعید دہلوی اپنی کار میں بیٹھنے لگے تو کچھ نامعلوم درندوں نے ان پر اندھا دھند گولیاں چلانی شروع کردیں جس سے وہ ان کاڈرائیور اورتین ان کے ہمراہ اصحاب موقع پر جاں بحق ہوگئے ۔غم وصدمہ میں ڈوب گئے۔ اوران سب کے منہ سے ایک چیخ نکل پڑی کہ ہائیں یہ کیا ہوگیا، کیاشرافت وانسانیت کابھی قتل ہونا شروع ہوگیا ہے۔ حکیم محمدسعید دہلوی شرافت انسانیت کی جیتی جاگتی تصویر تھے، وہ بڑے وضعدار انسان تھے انہوں نے دوسروں کے آرام کے لیے اپناآرام چھوڑدیا تھا۔ان کامقصدِحیات صرف اور صرف بنی نوع آدم کی خدمت کرناتھا اٹھتے بیٹھتے سوتے جاگتے وہ انسانیت کی فلاح وبہبودگی کے کاموں ہی میں اپنے کولگائے ہوئے تھے۔
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Islam and Mysticism or tasawuf have coexisted. Sufism has flourished in all Muslim dominated regions. Sufism is a mode of spirituality within Islam. Sufi schools teach three parts: Shariah, Tariqah and Haqiqh. In this article, traditional thoughts in Sufism and its impacts on the world especially in the region of Indo-Pak have been discussed. The shrines of Pakistani Sufis are the centers of inspiration for mysticism and spirituality that influence cultures and civilizations.

Molecular Characterization and Genetic Diversity of Snails in Agroecosystem of Faisalabad

This is a first attempt towards a detailed understanding of malacofaunna of Faisalabad Pakistan. The present study has been carried out on the morphometric and molecular characterization and genetic diversity of snails in the agroecosystem of Faisalabad City from March 2011 through August 2011. During this period 19290 snails were randomly collected from four agroecosystems (sugarcane, wheat, fodder, vegetables fields) and ditches from villages linked with Rakh branch, Jhang branch and Ghogera branch. The snails were isolated from the soil samples through sifting through screen of mesh size less than 1 mm. The snail specimens were studied under the microscope. The snail species were identified by using recent identification keys i.e., Blandford and Godwin (1908), Bouchet and Rocroi (2005), Sturm et al., (2005), Anderson, (2008), Watson and Dallwitz (2005) and diagrammatic description provided in them. The identification of the specimens was made on the basis of number of whorls, coiling of the shell, umbilicus, shape, colour, shape of the aperture, presence or absence of operculum, height (mm), diameter (mm), and the diameter of the aperture (mm) using vernier caliper. The snails were found belonging to two suborders, seven families, nine genera, fifteen species out of which six species have been reported first time in this region. Molecular characterization of snails has been done with the help of randomly amplified polymorphic DNA-polymerase chain reaction (RAPD-PCR) technique for understanding the biodiversity in this region. Genetic characterization of 15 snail species was done by using 23 RAPD primers and out of which 15 RAPD primers produced polymorphic amplification. On the basis of Analysis of Molecular Variance there was found 11% variation among populations of the five habitats and 89% variation within populations in species population found in all the habitats. Genetic similarity among snail species was estimated by Nei’s genetic similarity indices showing a range of 0.5 to 0.74. Maximum genetic similarity was found between Ariophanta belangeri bombayana and Ariophanta bristrialis taprobanensis as well as Ariophanta belangeri bombayana and Ariophanta solata. Minimum genetic similarity based on Nei’s genetic indices was observed among Cernuella virgata and Ariophanta bistrialis cyix. Considering the Zooctecus insularis and Juvenile Zooctecus insularis they are quite distant from each other in the cluster due to which it is expected that might belong to some new species, which need further investigations. The data of distribution and abundance was subject to different statistical tools i.e., shannon and wienerdiversity index, index of overall association, two way analysis of variance, multiple regression, cluster analysis shows that as we progress towards south, the diversity of the snail species in Faisalabad is highly reduced. However the species diversity in all the villages linked to R.B., G.B. and J.B. was highly significant with a strong positive relationship between species diversity and species evenness (97.03%). The diversity indices in all the habitats of the agroecosystem were highly significant while in ditches the results were non-significant with a strong negative correlation between species diversity and evenness in the crops that clearly shows that when diversity is low the evenness was high and viceversa in the distribution of snails in the different crops. There is 95.3% relationship between species diversity and species evenness in different crops of Faisalabad. The species diversity is highly significant in all the months except in April.Regression analysis between species diversity and species evenness shows that there is 57.36% relationship between them in different months in agroecosystem of Faisalabad. There is a significant effect of maximum and minimum temperatature on the number of snails while other abiotic factors i.e., humidity, rainfall, sunshine, soil cadmium concentration, soil lead concentration, soil pH, soil electrical conductivity has a non-significant effect on them. The soil parameters have been found much less than National envoirnmental quality standards Pakistan. However the association between the species and months and between species and agroecosystem has been found highly significant. Interspecific association indices suggests an overall positive association however no association has been found during different months while a strong association has been found with different habitats.This study has given us a baseline data of the malacofaunna in Faisalabad which will help us to identify the indicator species, develop ecological models, and conservation strategies by the policy makers.