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Home > Enzymatic and Bacterial Modifications of Natural Biofibres for Synthesis of Biocomposites

Enzymatic and Bacterial Modifications of Natural Biofibres for Synthesis of Biocomposites

Thesis Info

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Author

Zanib Ahmed

Program

PhD

Institute

University of Agriculture

City

Faisalabad

Province

Punjab

Country

Pakistan

Thesis Completing Year

2016

Thesis Completion Status

Completed

Subject

Biochemistry

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/9601/1/Zanib_Ahmed_Biochemistry_HSR_UAF_2016_10.01.2017.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676726072364

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Environmental concerns have been motivating research in the field of biodegradable materials, especially those from biological sources. Plant fibres are hydrophilic in nature due to interaction with the hydroxyl group of their components and water molecules which results in poor adhesion of these biopolymers to the reinforcing materials due to low compatibility with the hydrophobic polymer matrices that result in inefficient transfer of stress from the matrix to the reinforcing material. Environment friendly methods such as plasma treatment, treatments using fungi, enzymes and bacteria, can be used for the surface modification of plant fibers. In this context, a series of bio-composites e.g. polyvinyl alcohol (PVA) with lignocellulosic substrate (native and delignified) based biocomposites and PVA along with bacterial cellulose modified substrate based biocomposites were successfully synthesized by introducing maleic anhydride as compatibilizer and glycerol as a plasticizer. The lignocellulosic materials (sugarcane bagasse, wheat straw and rice straw) were treated enzymatically and the best delignified substrate was further modified by depositing Acetbacter xylinum. Blends were compression molded and the resulting bio-composites were removed from their respective casting surfaces under ambient environment and characterized using different analytical and imaging techniques. Dynamic mechanical analysis (DMA) was performed to study the mechanical properties of the composites. The structural changes in the composites were analyzed using Fourier transform infra-red spectroscopy (FT-IR), the morphological properties of the bocomposites were studied using Scanning electron microscopy (SEM) and the water absorption behavior of the biocomposites were also determined. The tensile strength, elongation at break point, and Young’s modulus values of the bio-composites reached very high levels in comparison to the composites prepared with pure PVA and pure native straw that were too fragile to be measured for any of the above mentioned characteristics. Morphological analysis of the newly developed biocomposites surfaces through SEM showed a uniform distribution of the PVA and reinforcing substrate. Also there was a marked improvement in the water absorption content of the biocomposite synthesized from 1:3 ratio of wheat straw and PVA. The development of biocomposites by using lignocellulosic biofibres as reinforcement materials will form the basis for the potential use of these biocomposites in various industries.
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التقريظ (2)

التقريظ (2)

بسم الله الرحمن الرحيم

الحمد والثناء لرّبِّ العالمين، والصلاة والسلام على حبيبنا وسيدنا محمد أشرف الأنبياء والمرسلين .........وبعد

من المؤكد أن عملية التوسع الشامل في مجال الأدب في العصر الحديث لم يأت من فراغ بقدر ما جاء نتيجة المقارنة بين الآداب المختلفة وقد ساعدت هذه الفكرة في التواصل بين المجتمعات الحديثة.

ولعله من أهم العوامل الفكرية التي كان لها تأثير على الآداب وتطورها في العصرالحديث هي حركة المقارنة بين الآداب المختلفة.

 الأدب المقارن في العلاقات الثقافية المختلفة له أهمية كبيرة وبالتأكيد دوره عظيم ولا سيما بين ثقافتي العربية والباكستانية .

فعندما لاحظت مهارة تلميذتي في اللغتين الأردية والعربية طرأ على ذهني فكرة المقارنة فلم أرى شخصاً أفضل من الدكتورة مكية نبي بخش بأن يقوم بهذا العمل الرائع لذلك ألقيت عليها فكرة دراسة مقارنة بين أشعار نازك الملائكة الشاعرة العربية العراقية وبين أشعار بروين شاكر الشاعرة الباكستانية الأردية.

لقد أوضح الفكر الإسلامي في أن "التعليم والتعلم" ليس مجرد حرفة ولكن في الأصل هو عبادة وتقرّب إلى الله، وبالفعل هناك بعض الأفاضل الذين أحترموا التعليم والتعلم وأجتهدوا وسهروا من أجل نشر العلم وأحب ان أذكر بالأحرف الذهبية وبكل فخر إسم العالم الجليل الأستاذ الدكتور إبراهيم محمد إبراهيم السيد أستاذ اللغة الأردية وآدابها بجامعة الأزهر الذي يتميز بمهارتهِ في اللغتين العربية والأُردية وسيادته قام بمراجعة هذا الكتاب قبل أن يُنشر وبكل تأكيد وثقة سيادته من العلماء الأفذاذ وأشكر بكل إحترام سيادته على جهوده وتوجيهاته وأنا أثق في خبراته وعلومه أطال الله عمره وأعطاه الصحة والسلامة.

وبالفعل تلميذتي الدكتورة مكية نبي بخش تحب العلم وهي إنسانة طموحة ومجتهدة جداً فقد عانت الكثير من التحديات ولكنها لم تستسلم وقد ساعد جهودها إلى رفع مستواها العلمي والثقافي، فقد حصلت على درجة الدكتوراه في اللغة العربية من...

STUDENT'S READINESS TO CARRY OUT FACE-TO-FACE LEARNING AT KENDARI VOCATIONAL HIGH SCHOOL

The slowing spread of Covid-19 infections has brought positive changes in the education sector. The issue of implementing limited face to face learning begins to excite students in gaining knowledge. Online learning effects for approximately two years was relatively difficult to keep students away from themselves. This study time to determine how the level of student learning readiness in facing offline learning. This was quantitative research with a survey type. The population were State vocatoonal high school 2 Kendari students, totaling 558 students. The sample was drawn randomly with a magnitude estimated using the Slovin formula at a significance of 5% so that the total sample size was 233 students. Data were collected by learning readiness scale. Data were analyzed descriptively and comparative statistics. The results showed that the learning readiness of State vocatoonal high school Negeri 2 Kendari students was in the high category and female students had a higher level of learning readiness than male students.

Effect of Organic and Inorganic K Sources and System of Rice Intensification on Growth and Yield of Genotypically Varying Rice Cultivars

A series of trials, including hydroponics and soil experiments, were conducted to document the phenotypic variation among rice genotypes and the response of selected genotypes to inorganic and/ or organic sources of K under standard rice management (SRM) and system of rice intensification (SRI). In a solution culture study, changes in growth attributes under both deficient and adequate K levels indicated differential adaptation of 26 rice genotypes. Three of 26 genotypes, namely, IR-6, Super basmati and 99509, were selected for subsequent studies on the basis of their differential responses for K use efficiency (KUE), shoot biomass, and K uptake at deficient and adequate K levels. The categorization of rice genotypes was made using the index scoring technique. Accordingly, 99509 was categorized as highly efficient-medium responsive, Super basmati as medium efficient-medium responsive, while IR-6 as low efficient-low responsive. Correlation among various growth parameters was calculated, and a strong correlation was found among shoot biomass, KUE, and total K uptake. The growth and yield responses of these selected genotypes were subsequently studied with exogenously applied K (K 2 SO 4 ) in pot trials. On overall basis, the KUE determined the responses of various growth and yield parameters against varying levels of K application. Again, the order of genotypes with respect to KUE was found to be the same as that observed in the hydroponic study, i.e., 99509 was found to be highly efficient, Super basmati was medium efficient, and IR-6 was non-efficient in term of growth and yield attribute formation. A dose of 60 kg K ha -1 was found optimum for increasing most of the growth and yield attributes of the three rice genotypes, which was very close to that calculated amounts obtained using the quadratic model. Keeping in view the cumulative effects, a dose of 60 kg K ha -1 was selected for subsequent field trials. Thereafter, the genotypes were tested under the conventional SRM (continuously flooded) and SRI (intermittently flooded) systems. The growth, yield and quality of the three genotypes were studied under single and integrated use of inorganic and organic K fertilizer. Most of the growth and yield attributes gave maximum response with integrated application of 30 kg K ha -1 as K 2 SO 4 + 30 kg K ha -1 as K-enriched compost under SRM, while 15 kg K ha -1 as K 2 SO 4 + 15 kg K ha -1 as K-enriched compost proved best under SRI. Super basmati gave the maximum grain yield under SRM, while under SRI 99509 was best, both with integrated application of 15 kg K ha -1 as K 2 SO 4 + 15 kg K ha -1 as K-enriched compost. However, maximum straw yield was produced by 99509 with integrated application 1of 15 kg K ha -1 as K 2 SO 4 + 15 kg K ha -1 as K-enriched compost under SRM, while integrated application of 30 kg K ha -1 as K 2 SO 4 + 30 kg K ha -1 as K-enriched compost resulted in maximum straw yield in Super basmati under SRI. IR-6 remained relatively poor in performance in most of the growth and yield parameters. It was note worthy that the genotype 99509, which was rated highly efficient in K use in hydroponic trial changed its response as medium efficient in K use in field trials (both in SRI and SRM), while exactly reverse trend with respect to KUE was observed in case of Super basmati. IR-6 remained relatively poor in growth, yield and KUE under both the systems of management. Total K uptake and KUE of the genotypes varied with K doses and sources under SRM and SRI, affecting the growth and yield parameters of the three rice genotypes tested. Most of the quality parameters under SRI and SRM gave almost similar values, implying that SRI had no negative effect on yield and quality of both coarse and fine varieties of rice. Moreover, SRI was seen to be a viable approach to save water without compromising the yield and quality of the produce, thus it may be adopted as a low-input technology system.