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Home > Fabrication and Characterization of Nanostructured Materials of Metal Sulfides and Oxides

Fabrication and Characterization of Nanostructured Materials of Metal Sulfides and Oxides

Thesis Info

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Author

Nafees, Muhammad

Program

PhD

Institute

Government College University

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2019

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/11375/1/Muhammad%20Nafees%20Physics%202019.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676726184704

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The motivation behind the focused and intense research in the field of nanomaterial is owing to promising and established properties that can be plagued into applications. Metal sulfides (MS) and oxide (MO) nanomaterial epitomize a fairly new class of materials and under intensive investigations since few decades for potential application in various fields like photo-catalysis, thermal stability, bio-mineralization, drug delivery, and optoelectronic applications. In this work, metal sulfide (CuS, PbS) nanomaterial was synthesized by a hassle-free aqueous route under microwave irradiation with different morphologies as spherical, tubular, leaf-like and strip type shape without assistance of any surfactant/template. Whereas metal oxide (PbO, Mn3O4) were prepared by thermal decomposition of oxalate precursor of relative metal synthesized using the soft chemical method. Various techniques were employed to characterized the synthesized nanomaterial such asX-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), fourier transform infrared spectroscopy (FTIR), ultraviolet–visible (UV–Vis) spectrophotometry, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Mn3O4 were examined as adsorbent material for anti-cancer drugs doxorubicin-DOX, daunorubicin-DNR and cisplatin-CPN from aqueous solution. Kinetics study was conducted to investigate the phenomenon and mechanism of adsorption of drugs onto Mn3O4
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نواب شوکت خاں

نواب شوکت خاں
دوسرا حادثہ باغپت کے نوجوان رئیس نواب شوکت خاں کی وفات ہے ان کو اﷲ تعالیٰ نے امتیازی و جاہت کے ساتھ دینداری کی دولت سے بھی نوازا تھا، چنانچہ حاجی اور حافظ بھی تھے جس کی مثال جدید تعلیم یافتہ نوجوان رئیسوں میں مشکل سے ملے گی، اسمبلی کے ممبر بھی رہ چکے تھے، سٹی سنٹرل وقف بورڈ کے صدر تھے، اس تعلق سے کئی سال ان سے سابقہ رہا، طبعاً نہایت شریف اور مہذب و متین تھے، عمر چالیس بیالیس سال سے زیادہ نہ تھی، اﷲ تعالیٰ اس نوجوان اور دیندار رئیس کی مغفرت فرمائے۔
(شاہ معین الدین ندوی، فروری ۱۹۶۹ء)

Pandemic Impact on the Travels and Tourism Sector of Nepal

The travel and tours enterprise were badly affected due to pandemics. In the aftermath of high restrictions on human movement, travel-based entrepreneurs were highly impacted due to lockdown. Due to pandemic, highly impacted into earning-saving, lack of supportive working conditions, lower self-capacity, and lack of recovery budget and policies, the travel and tours-based entrepreneurs were highly impacted. The study reflected the impact of pandemics on travel and tours, major constraints, and a possible way forward to sustaining. The research explores what are the major existing practices of sustaining travel and tours entrepreneurs during pandemics, what factors can contribute to building bounce-back capacities of travel and tours entrepreneurs’ sustainability. Above forty-four, snowball-based sampling was done from major travel and tours entrepreneurs, Pokhara-Nepal. A structure-based open-ended questionnaire, key informant interviews, and in-person-based discussion were applied in the method of study. Used the content analysis along with a recap of the research question, undertake bracketing to identify biases, operationalize variables with develop a coding, and code the data with undertaking analysis while qualitative analysis, and multiple regression facilitated on quantitative analysis to finalize the discussion. The study reflects that self-saving, social support, state and financial institutions recovery support, social behavior and change communication, full vaccination practices, and self-accountable tourist behavior are highly expectable conditions to the sustainability of travel and torus entrepreneurship in the learning area. The study concludes that self-saving capacity can contribute to bounce-back capacity for every entrepreneur. Social support and socioeconomic recovery packages were also contributing to sustaining travel and tours in the study area. Self-saving condition and capacity is higher bounce back capacity compared to non-saved entrepreneurs in the study area. Social support, socioeconomic recovery practices, and recovery packages from state and financial institutions were not at the higher level as expected.

Comparative Study of Enriched Compost, Inorganic Fertilizer and Pgpr on Soil Fertility Status and Physiology of Wheat Triticum Aestivum L.

Present investigation was aimed to formulate an efficient phosphatic bio-fertilizer to supplement or substitute chemical fertilizers and to evaluate its effect on the availability of P for growth and yield of wheat. For this purpose rock phosphate enriched compost (RPEC) was prepared and the effect of plant growth promoting rhizobacteria (PGPR) was evaluated for phosphorus availability through composting. Impact of PGPR alone or in combination with different (organic and inorganic) fertilizers were studied on wheat crop grown under natural conditions of field and axenic condition of pots. In the first experiment, poultry litter alone and in combination with rock phosphate was composted with and without PGPR (Pseudomonas sp. and Proteus sp.) inoculation in pits for 120 days (d) and shuffled with 10 d interval for proper aeration. The RPEC prepared by the combination of poultry litter, rock phosphate (RP) and Pseudomonas sp. inoculation showed maximum total phosphorus, available (Mehlic-3 extracted) phosphorus, microbial biomass (carbon and phosphorus), but lower total organic carbon, total nitrogen and carbon/nitrogen ratio over poultry litter without inoculation and addition of RP. Pseudomonas sp. enhanced P solubilization from rock phosphate (RP) and showed 79% higher P availability from RP added poultry litter over un-inoculated treatment on 120th day of composting. Experiments under natural condition of field as well as under axenic condition in pots were conducted for two consecutive years. The residual impact of the treatments were also studied on soil chemical and biological properties. The wheat seeds were surface sterilized and inoculated with Pseudomonas sp. (Accession No. KF307201) and Proteus sp. (Accession No. KF307202) at the rate 106cells ml- 1 prior to sowing. Seven treatments; simple poultry litter (SPLC), Rock phosphate enriched compost (RPEC1, inoculated with Pseudomonas sp. during composting), RPEC2 (solubilized with Proteus sp. during composting), Rock phosphate, Half recommended dose of inorganic P fertilizer (HDP) and Full recommended dose of inorganic P fertilizer (FDP) were applied with and without seed inoculation of PGPR (Pseudomonas sp. and Proteus sp.). Average of two year data on field and pot experiments showed increase in plant height, number of tillers, grain yield, dry matter yield, seed phosphorus and plant P-uptake with application of Pseudomonas sp. solubilized rock phosphate enriched compost compared to recommended dose of inorganic (single super phosphate) fertilizer. The chlorophyll content and phytohormones (Indole Acetic Acid and Gibberellic Acid) in flag leaves were also enhanced with application of rock phosphate enriched vii compost. Post-harvest soil phosphorus availability, nitrate nitrogen content, extractable potassium, alkaline phosphatase activity and microbial biomass increased with the application of rock phosphate enriched compost over full recommended dose of inorganic fertilizer. Moreover, seed inoculation with PGPR (Pseudomonas sp.) also significantly increased yield and yield parameters of wheat and post-harvest soil properties over un-inoculated treatments. Economic analysis in terms of value cost ratio showed 3.23:1 from the treatment where RPEC in combination with Pseudomonas sp. seed inoculation was applied. Thus rock phosphate enriched compost can be used as an alternate to inorganic phosphatic fertilizers and seed inoculation with Pseudomonas sp. can enhance wheat growth and yield applied in combination with enriched compost. In another experiment, wheat (AGS2060) root phosphatase activity was also determined in presence of different P sources; compost (C), rock phosphate (RP), single super phosphate (SSP), C + RP, C + SSP, RP + SSP, C +RP + SSP and results showed maximum (447%) increase in P mineralization with compost (C) grown roots over SSP. It was inferred that compost is the best source to mineralize organic P for better crop production.