مولوی عبدالحمید ندوی
یہ سطور ابھی پریس نہیں گئی تھیں کہ مولوی عبدالحمید ندوی کے انتقال کی خبر ملی، وہ بارہ بنکی کے ایک گاؤں جیسکھ پور کے رہنے والے تھے، بڑے مخلص، حق پسند اور بہی خواہ خلق تھے، ۱۹۱۹ء میں ندوہ میں داخل ہوئے، تحریک خلافت شباب پر تھی، حمید صاحب بھی اس سے متاثر ہوئے، اس کی وجہ سے سادگی طبیعت ثانیہ بن گئی، مولانا عبدالرحمن نگرامی کی صحبت نے ان کے اندر ندوہ کی محبت اور خاموش خدمت کا جذبہ پیدا کیا، تعلیم سے فراغت کے بعد قیام زیادہ تر وطن ہی میں رہا، لیکن ندوہ برابر آتے جاتے رہتے تھے، دوستوں کے اصرار کئی برس تک بھٹکل میں تعلیمی خدمت انجام دی، ان کے مخلص شاگردوں نے اس کام کو آگے بڑھایا اور ایک بڑا تعلیمی مرکز قائم ہوگیا، عرصہ سے دل کے مریض تھے، رمضان میں ندوہ آئے، مولانا ابوالحسن علی سے ملنے رائے بریلی جانے کا ارادہ تھا، دفعتہ دل کا دورہ پڑا اور تھوڑی دیر میں جان جان آفریں کے سپرد کردی، اﷲ تعالیٰ ان کی مغفرت فرمائے اور ان کے صاحبزادہ مولوی عبدالرشید ندوی اور دوسرے متعلقین کو صبر جمیل عطا فرمائے۔ (عبد السلام قدوائی، ستمبر ۱۹۷۸ء)
Sheikh Molana saleem ullah khan was born in Muzaffer Nagar in India. He belongs to hasan pur. He get degree of dura-e-nizami from Dar-ul-Uloom Deoband. In Deoband he received Education of Quran, Hadith and other related sciences through learned scholars of the time which includes Molana Hussain Ahmed Madani, Molana Izaz Ali, Molana Idrees kandahalvi and other religious personalities. After his education he start teaching and served as a teacher in many madaris. He was a prominent and renowned scholar.1n 1967 He laid the foundation of Jamia Farooqia Karachi. His entire services have been so much blessed by Almighty Allah that since its foundation, till now the Jamia has advanced a long way in Islamic Education and related fields which seems almost unbelievable. He left many books which based on his writing and narration of Hadith during different session of dura-e-Hadith. In this Article, I have tried my level best to elaborate sheikh saleem Ullah khan’s services as Author for Islamic literature and specially for Hadith Nabvi(s.w).
The present dissertation entitled “Synthesis of Novel Heterocyclic Compounds” is comprised of two parts. Part A describes the synthesis of Azaborines. In Part A the synthesis of Azaborines is classified into two classes. (a) 1, 3, 2 benzodiazaborininones (carbonyl containing, boron-based heterocyclic scaffolds) (68-89). In the synthesis of 1, 3, 2 benzodiazaborininones, anthranilamide reacted with different commonly available potassium organitriflouroborates using a fluorophile (BF3NH2Et) with efficient methodology. NH B NH O 68 F NH B NH O MeO OMe 69 NH B NH O O 70 NH B NH O 71 NH B NH O Br 72 NH B NH O F F 73 NH B NH O COOMe 74 NH B NH O CN 75 NH B NH O 76 NH B NH O O 77 NH B N H O CH3 78 Abstract ix NH B N H O CF3 79 NH B N H O S 80 NH B NH O NO2 81 NH B NH O 82 NH B NH O 83 84 NH B NH NH2 O NH B NH Cl O 85 NH B NH O CO2Me 86 CH2CO2Me NH B NH O 87 NH B NH O 88 N H B NH N O 89 The second class of azaborines prepared were 1,2-dihydroazaborinines, including 1-benzenyl-2-quinolinyl/isoquinolinyl-1,2-dihydroazaborinines (91-95, b1). These were obtained by reacting N-benzyl-2-vinylaniline with potassium organotrifouroborates in the presence of SiCl4 and Et3N. 2-Ethynyl-1,2-dihydroazaborinines (96-97, b2) were synthesized by using the same methodology where 2-vinylaniline was used with different commercially available potassium organotriflouroborates. All the products synthesized were charecterzied by FT-IR, 1H-NMR, 13C-NMR, 11B-NMR, HRMS. The results obtained confirmed the formation of desired product. Abstract x B N N B N N B N N B N N B N N 91 92 93 94 95 B HN TMS B HN F 96 97 Part B. Part B consists of the synthesis of 2,4 di-substituted quinolines. The 2, 4- disubstituted quinolines were synthesized using a Povarov related reaction using indium chloride as a catalyst. Two classes of 2,4 di-substituted quinolines were prepared. (c) Quinoline isoindolindiones (187-193) products were synthesized in two steps.The First step involved Schiff base synthesis while second step involved condensation of Schiff bases with N-propargylphthalimide. N Cl OMe N O O N Br OMe N O O N OMe N O O MeO 187 188 189 Abstract xi N OMe N O O N OMe N O O N Cl N O O MeO N N O O 190 191 192 193 Second class is (d) benzoquinoline isoindolindiones (194,195). These compounds were prepared by reacting aldehydes, 1-naphthyl amine with N-propargylphthalimide in presence of indium chloride catalyst. All these compounds were characterized through FT-IR, 1H-NMR and 13C-NMR. Along with N-propargylphthalimide, another alkyne, 1- nitro-4-(prop-2-ynyloxy)benzene was used under the same conditions. A reaction was attempted where 1-nitro-4-(prop-2-ynyloxy)benzene was reacted with benzo[c][1,2,5]thiadiazol-5-amine and different aldehydes, but the product isolated was not the desired one. N N O O N N O O 194 195