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Kinetic Study and Reactor Simulation of Methycyclohexane Dehydrogenation Reaction for a Mobile Power Plant

Thesis Info

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Author

Muhamamd Sarfraz Akram

Program

PhD

Institute

University of the Punjab

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2018

Thesis Completion Status

Completed

Subject

Chemical Engineering

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/12836/1/Muhammad%20Sarfraz%20Akram_Chemical%20Engg_2018_UoPunjab_PRR.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676726568457

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Fossil fuels are a major contributor to the today’s world energy demand as well as greenhouse gases causing global warming. The idea to reduce the dependence on fossil fuels for a green future needs a stepwise transition from fossil fuels to renewable sources. Among the various renewable sources hydrogen is probably the most promising alternative due to its availability, high heating value per unit weight, and zero emissions. The only challenge associated with hydrogen is its safe and feasible storage. The methylcyclohexane-toluene-hydrogen (MTH) system is the one that is considered safe and economical option for hydrogen production, storage and transportation, and utilization. The dehydrogenation reaction of the MTH system is highly endothermic and requires considerable amount of heat energy at a fast rate to have high equilibrium conversions. The successful utilization of hydrogen economy based on the MTH system therefore requires a highly active, selective, and stable dehydrogenation catalyst with its associated reaction kinetics. An intensified dehydrogenation reactor design that supplies high rates of heat transfer to the catalyst bed is also desired. A comprehensive review of the literature regarding kinetics of the methylcyclohexane (MCH) dehydrogenation over Pt containing catalysts has revealed that there is no consensus among the researchers on describing the reaction mechanism, rate-determining step, and inhibition offered by a product. Different researchers have suggested different reaction chemistry and developed different kinetic rate equation. There is hardly a study on the design and simulation of an intensified dehydrogenation reactor that is capable of being used on commercial scale applications. In the present study, an attempt is made to address the discrepancies in the kinetics of the MCH dehydrogenation that exist in the literature. The experimental data of 5 different Pt containing catalysts over a wide range of operating conditions is used to conduct a detailed kinetic study of the dehydrogenation reaction. Various kinetic models are developed based on the power law, Langmuir-Hinshelwood-Hougen-Watson (LHHW), and Horiuti-Polanyi reaction mechanism. The developed kinetic model equations are analyzed both kinetically and statistically and the best fitted kinetic model for each of the catalysts is worked out. The kinetic model based on single-site LHHW kinetics where loss of first hydrogen is the rate limiting step is found appropriate in representing the data of all the catalysts. This leads to report a unified kinetic model for the methylcyclohexane dehydrogenation reaction over any Pt containing catalyst. In addition to that, a new reaction mechanism called associative adsorption of methylcyclohexane is proposed and a kinetic model equation developed based on this mechanism is found successful in representing the relevant experimental data. A 2.0 MW power plant, working on the methylcyclohexane dehydrogenation reaction to yield hydrogen gas as fuel for the power production, is proposed and simulated in Aspen Hysys. The operating conditions such as stream flowrates, temperatures, pressures, and thermal efficiency are worked out. It is found that 17.4148 kmol/h methylcyclohexane are required to produce 2.0 MW net power output. Also, it is found that there is enough energy in the exhaust gases of the turbine that can carry out the dehydrogenation reaction. Using the best-fit kinetic model and the simulation data obtained for 2.0 MW power plant, a novel reactor-heat exchanger design is mathematically modeled and simulated. The proposed reactor configuration is found highly appropriate in carrying out the dehydrogenation reaction.
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محققِ نعت: ڈاکٹر شہزاد احمد

محقق ِنعت: ڈاکٹر شہزاد احمد
بہت خوش نصیب ہیں وہ لوگ جن کے شب و روز سید الانبیاء والمرسلین صلی اللہ علیہ و آلہٖ وسلم کی تعریف و توصیف کے بیان میں گزرتے ہیں۔ ایسے ہی خوش نصیب افراد میں ایک نام ڈاکٹر شہزاد احمد خان کا ہے۔ڈاکٹر صاحب کی نعت سے وابستگی نصف صدی پر محیط ہے۔جس پر بجا طور پر انھیں فخر بھی ہے ۔
شہزادؔ! میں بھی عاشقِ خیرالانام ہوں
ہاتھوں میں میرے دیکھیے دامانِ نعت ہے
فروغِ نعت کے حوالے سے ڈاکٹر صاحب کی خدمات کسی تعارف کی محتاج نہیں ہیں۔ آپ ۱۹۷۲ء سے ثناخوانی کررہے ہیں۔ مولانا اختر الحامدیؒ، علامہ سید محمد ہاشم فاضل شمسیؒ، مولانا عبدالقدوس قادریؒ، علامہ شمس بریلویؒ اور بابا سید رفیق عزیزی یوسفی تاجی ؒ جیسے بزرگوںکے آپ صحبت یافتہ ہیں۔ ایک اچھے نعت خواں اور نعت گو ہونے کے ساتھ ساتھ نعتیہ کتابوں کے مصنف و مرتب،تذکرہ نگار، نعتیہ رسائل کے مدیر، نعتیہ ادب کے محقق ، فروغِ نعت کے لیے قائم متعدد تنظیموں کے بانی اور نعتیہ کانفرنسوں اور جلسوں کے منتظم بھی ہیں۔
ڈاکٹر صاحب کا ایک بڑا کام ـ’’اردو نعت پاکستان میں‘‘ (نعتیہ شاعری کا تحقیقی جائزہ پاکستان کے خصوصی حوالے سے) کے عنوان سے وہ تحقیقی مقالہ ہے جس پر جامعہ کراچی نے انھیں پی ایچ۔ڈی۔ کی سند عطا کی ہے۔ اس سے نعتیہ ادب کے فروغ میں آپ کی محنت، تحقیق ، جستجو اور لگن کا اندازہ کیا جاسکتا ہے۔
عصر ِ حاضر میں نہ صرف حمدیہ و نعتیہ موضوعات پر ملکی و غیر ملکی جامعات میں ایم۔فل۔اور پی ایچ۔ڈی کی سطح پر تحقیقی مقالات لکھے جارہے ہیں بلکہ حمدو نعت سے وابستہ شخصیات بھی تحقیقی مقالات کا موضوع بن رہی ہیں۔ فروغِ نعت کے حوالے سے ڈاکٹر شہزاد صاحب کی خدمات یقینا اس لائق ہیں کہ انھیں...

قرآن و حدیث کی روشنی میں تعمیر کردار و شخصیت اور نصاب اسلامیات: ایک تنقیدی مطالعہ

Islam gives the idea of collective life and tries for human development. The basic idea of the teaching of Islam is that the individual must be true and active worker of society. He must have moral values and principles clearly. In addition, he tries constantly that a Muslim should perform saying of Allah and human rights properly. In this way, Islam tries to work on the behavior, morality, and habits of people and tries his best to properly enhance the different aspects of personality.  For this, the life of Prophet Muhammad? Is a complete code of life. The good characteristics of Muslims are considered praiseworthy that are truth, brotherhood, justice, forgiveness, the oneness of Allah and keepings. In the same way, the things which are condemned by Islam are bride, misery, theft, backbiting, telling lies, blaming others, self-centeredness, close vision, dishonesty, garrulous, greediness, showiness manners, jealousy,  un-obligation, clashes, hatred and etc. The philosophy of character building and personality development in Islam is the Muslims should avoid all bad works and develops good qualities in him as discussed before so that a Muslim should be a very useful and pious citizen of society. And we all know that education especially we can say that Islamic Education is a tool of change. So education is worthless if it does not create change in the minds of people and society. It is useless if it does not build the moral character regarding the personality development of the students. Islam tells us all about the values which are fruitful for humanity and are beneficial to human beings. For this purpose, it is necessary that we should give awareness of Islamic values to the people through Islamic education. It is only possible if the textbooks are designed according to the Islamic concept and values as well as teachers and parents play their effective role in the development of the personality of their children. Pakistan is a Muslim country and has its own religious, moral, political and social values and being a Muslim through an effective Islamic educational system, we can transfer these values to our new generation. Our curriculum is playing key role in the personality development and character building of the students or not is the main question so that this article is being written. In this article keeping in view the aims and objectives of the curriculum of Islamic Studies and following the Quranic verses and Hadith, we will try to analyze whether it is building the personality or character of students or not. After that, the conclusion and recommendations will be given keeping in view the analysis.

Electro-Deposition & Dissolution Behavior of Zinc-Based Alloys in Additive-Free Chloride Baths and Formation of Doped Zno Nanostructures by Their Hydrothermal Oxidation

Zn-Ni and Zn-Co alloy coatings with 5-18 at% Ni and 8-25 at% Co have been prepared by DC plating in additive free chloride baths. Effects of bath composition on the alloy composition, texture, grain size, morphology and hardness were investigated. Potentiodynamic anodic stripping, reverse chronopotentiometry were employed in combination with XRD and EDS to correctly determine the electro-dissolution (dezincification) behavior of alloy electrodeposits. Potentiodynamic cyclic stripping was also performed to prepare compact Zn-Co electrodeposits. Zn-rich alloy deposits are predominantly formed by DC plating in these baths due to anomalous codeposition. With the help of careful cyclic voltammetry, chronopotentiometry, chronoamperometry, and (potentiodynamic) cyclic voltammetry, it has been established for the first time in this work that it is primarily the electrochemical potential that determines the deposition mode. Between the window of normal codeposition where nickel or cobalt rich phases are deposited and anomalous codeposition where zinc-rich phases are formed, a range on electrochemical potential exists where the formation of zinc hydroxide hinders the electrodeposition and cathodic current mostly becomes insignificant. A shift from this region to the cathodic direction allows anomalous codeposition of zinc and nobler alloy constituent. A shift in the anodic direction may again allow cathodic deposition of nobler constituent with under-potential deposition of zinc. The transition potentials depend on bath composition and temperature. Hydrothermal oxidation of Zn, Zn-Ni and Zn-Co electrodeposited on conducting substrates resulted in wide variety of nanostructures depending on the oxidation temperature and alloy content. In case of pure electrodeposited zinc, nanorods with diameter ranging from 300-800nm are seen at oxidation temperature of 100oC. The size of nanorods becomes coarser with rise in oxidation temperature. Hydrothermal oxidation of Zn-Ni alloys resulted in the doped ZnO nanostructures with quantity of dopant ranging from 2 at% to 11 at%. Not only nanorods and nanowires are synthesized by this technique, but also novel structures like nanotulips, hollow nanocones, faceted nanotubes and electronically translucent nanosheets arranged are obtained. Hydrothermal oxidation of Zn-Co alloys resulted in hollow and tubular ZnO nanostructures with doping of cobalt around 2at%. The doped ZnO nanostructures become finer with a rise in synthesis temperature. Hence, dopant and temperature exhibit synergistic effects in determining the morphology of the ZnO nanostructures grown by hydrothermal oxidation of electrodeposited nanocrystalline alloys.