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Kinetics of Photochemical Reactions of Thionine

Thesis Info

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Author

Uddin, Fahim

Program

PhD

Institute

University of Karachi

City

Karachi

Province

Sindh

Country

Pakistan

Thesis Completing Year

1985

Thesis Completion Status

Completed

Subject

Chemistry

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/3001/1/617.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676726570716

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Hie photochemical reduction of thionine by N-phenyl glycine, N-allylurea, N -phonylurea and thiourea in absolute me¬ thanol ms investigated. An apparatus for the irradiation of air free solutions, with known intensities of monochromatic light was constructed. Double walled glass reaction cell was deviced in which nitrogen inlet/outlet, water inlet/outlet ar¬ rangements were made. Acidities of the reaction solutions were controlled using buffer solutions. Acidities determined spec- trophotometrically using basic indicator were expressed in terms of a Hamnett acidity function. Variations of quantum ef¬ ficiencies in absolute methanol have been determined at various concentrations of thionine, reductants, and acidities. The oxy¬ gen free reaction solutions were irradiated and the react ions were followed by measuring the intensity of light transmitted. The quantum efficiency, in yellow light, for the dis¬ appearance of thionine, was found to be a function of reductant concentration, acidity and temperature. The quantum efficiency was found to be independent of the concentration of thionine. The results have been interpreted in terms of a reaction mechanism Ratios of the certain rate constants for the proposed mec banian have been evaluated. It was found that the quantum efficiency is controlled by two equilibriums between: i) triplet state of thionine with proton, and protonated triplet state of thionine, and ii) protonated triplet state of thionine with reductant, and associated complex of thionine with reductant.
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چل پڑے حجاج کیوں کر صحنِ کعبہ چھوڑ کر


چل پڑے حجّاج کیونکر صحنِ کعبہ چھوڑ کر
منزلِ حق مل نہ پائی راہِ طیبہ چھوڑ کر

صورتِ ابرِ گریزاں رحمتِ کُلؐ کی گھٹا
جا نہیں سکتی کسی صحرا کو پیاسا چھوڑ کر

عاصیوں کو مل گئی اُنؐ سے نویدِ مغفرت
زاہدوں نے کچھ نہ پایا یہ وسیلہ چھوڑ کر

فتنہ پرور دور میں پکڑو صراطِ مستقیم
سنّتیں اپناتے جاؤ رسمِ دنیا چھوڑ کر

جائیں گی خاتونِ ؑجنّت سوئے جنّت شان سے
ایک جانب خلق ہو جائے گی رستہ چھوڑ کر

نغمۂ توحید کی ہو گی صدا کیسے بلند
یا رسولؐ اللہ کا عرفانؔ نعرہ چھوڑ کر

Tribute Dr Ghulam Mustafa Khan

Dr Ghulam Mustafa Khan [d. 2005] can truly be said to be a teacher of teachers [ustadh al-asatadha]. In his long and distinguished academic career spanning over six decades, he brought into existence literally hundreds of teachers in his subject Urdu and also created in many of them a taste for critical research that resulted in the existence of a whole corpus of standard critical material. This will endure in academic circles for a long time. It was his common habit to encourage his students, especially those of an academic bent of mind, to enrol for a Ph.D. In the course of which he would proffer them all kinds of assistance even if he were not their research supervisor. As such, the names of Dr Najmul Islam, who succeeded him as Chairman, Department of Urdu, University of Sindh, stands out. Dr Najmul Islam was the editor of a scholarly research journal, Tehqiq, which appeared in over 20 volumes in his own lifetime. Each issue contained scores of critical essays of a very high academic standard including his own [Dr N. Islam’s]. There is also the name of Dr Hasrat Kasganjvi, who emerged as a creative artist and critic of merit later on authoring dozens of books of high academic standard. The list is long and distinguished and contains the names of the major teachers of Urdu language and literature at the main Pakistani universities. Apart from Urdu teachers, the thousands of persons who had the benefit of attending his lectures and courses are also evidence of his intellectual wide-ranging scholarship. Then there is the select circle of his murids who formed his circle of spiritual knowledge and who had proffered their religious devotion at his hands. To these he gave the benefit of his spiritual counsel and advice as well as the vast knowledge he possessed of the Islamic sciences in his table-talk. Among these persons, the name of ex-President Ziaul Haq is most prominent.

Comparative Study of Enriched Compost, Inorganic Fertilizer and Pgpr on Soil Fertility Status and Physiology of Wheat Triticum Aestivum L.

Present investigation was aimed to formulate an efficient phosphatic bio-fertilizer to supplement or substitute chemical fertilizers and to evaluate its effect on the availability of P for growth and yield of wheat. For this purpose rock phosphate enriched compost (RPEC) was prepared and the effect of plant growth promoting rhizobacteria (PGPR) was evaluated for phosphorus availability through composting. Impact of PGPR alone or in combination with different (organic and inorganic) fertilizers were studied on wheat crop grown under natural conditions of field and axenic condition of pots. In the first experiment, poultry litter alone and in combination with rock phosphate was composted with and without PGPR (Pseudomonas sp. and Proteus sp.) inoculation in pits for 120 days (d) and shuffled with 10 d interval for proper aeration. The RPEC prepared by the combination of poultry litter, rock phosphate (RP) and Pseudomonas sp. inoculation showed maximum total phosphorus, available (Mehlic-3 extracted) phosphorus, microbial biomass (carbon and phosphorus), but lower total organic carbon, total nitrogen and carbon/nitrogen ratio over poultry litter without inoculation and addition of RP. Pseudomonas sp. enhanced P solubilization from rock phosphate (RP) and showed 79% higher P availability from RP added poultry litter over un-inoculated treatment on 120th day of composting. Experiments under natural condition of field as well as under axenic condition in pots were conducted for two consecutive years. The residual impact of the treatments were also studied on soil chemical and biological properties. The wheat seeds were surface sterilized and inoculated with Pseudomonas sp. (Accession No. KF307201) and Proteus sp. (Accession No. KF307202) at the rate 106cells ml- 1 prior to sowing. Seven treatments; simple poultry litter (SPLC), Rock phosphate enriched compost (RPEC1, inoculated with Pseudomonas sp. during composting), RPEC2 (solubilized with Proteus sp. during composting), Rock phosphate, Half recommended dose of inorganic P fertilizer (HDP) and Full recommended dose of inorganic P fertilizer (FDP) were applied with and without seed inoculation of PGPR (Pseudomonas sp. and Proteus sp.). Average of two year data on field and pot experiments showed increase in plant height, number of tillers, grain yield, dry matter yield, seed phosphorus and plant P-uptake with application of Pseudomonas sp. solubilized rock phosphate enriched compost compared to recommended dose of inorganic (single super phosphate) fertilizer. The chlorophyll content and phytohormones (Indole Acetic Acid and Gibberellic Acid) in flag leaves were also enhanced with application of rock phosphate enriched vii compost. Post-harvest soil phosphorus availability, nitrate nitrogen content, extractable potassium, alkaline phosphatase activity and microbial biomass increased with the application of rock phosphate enriched compost over full recommended dose of inorganic fertilizer. Moreover, seed inoculation with PGPR (Pseudomonas sp.) also significantly increased yield and yield parameters of wheat and post-harvest soil properties over un-inoculated treatments. Economic analysis in terms of value cost ratio showed 3.23:1 from the treatment where RPEC in combination with Pseudomonas sp. seed inoculation was applied. Thus rock phosphate enriched compost can be used as an alternate to inorganic phosphatic fertilizers and seed inoculation with Pseudomonas sp. can enhance wheat growth and yield applied in combination with enriched compost. In another experiment, wheat (AGS2060) root phosphatase activity was also determined in presence of different P sources; compost (C), rock phosphate (RP), single super phosphate (SSP), C + RP, C + SSP, RP + SSP, C +RP + SSP and results showed maximum (447%) increase in P mineralization with compost (C) grown roots over SSP. It was inferred that compost is the best source to mineralize organic P for better crop production.