Present work describes the optimization of reaction parameters for biodiesel production using chemical and enzymatic transesterification of conventional as well as nonconventional feedstocks. Response Surface Methodology based upon central composite response surface design was used to optimize reaction parameters for biodiesel production. Different reaction parameters including catalyst/enzyme type, catalyst/enzyme concentration, reaction temperature, reaction time and methanol to oil molar ratio were optimized and comprehensive protocols were developed to achieve highest biodiesel yields using both chemical and enzymatic transesterification. During chemical transesterification, NaOCH3 catalyzed transesterification was depicted to give highest biodiesel yields comparative to KOH, NaOH catalyzed transesterification whereas, during enzymatic transesterification, NOVOZYME-435 catalyzed transesterification resulted into higher biodiesel yields comparative to A.n.Lipase catalyzed transesterification reactions. Among different feedstocks studied, linseed oil exhibited highest biodiesel yield (96.5%) during chemical transesterification, while during enzymatic transesterification Eruca sativa oil exhibited best biodiesel yield (98.3%). For optimized chemical transesterification, 0.5 to 0.75% catalyst concentrations, 6:1 to 7.5:1 methanol to oil molar ratio, 45 to 52.5oC and 60 min reaction time, whereas, for enzymatic transesterification 1.0 to 1.25% enzyme concentrations, 6:1 to 9:1 methanol to oil molar ratio, 30 to 32.5oC reaction temperature and 60 to 96 hrs were depicted to be optimized reaction parameters to obtain highest product yields. Monitoring of transesterification reactions was carried out using FTIR spectroscopy and High Performance Liquid Chromatography (HPLC), while compositional analysis of synthesized biodiesels was performed with Gas Chromatography equipped with Mass Spectrometric detector (GC-MS). Fuel characteristics including flash point, fire point, pour point, cloud point, density, ash content, kinematic viscosity, cetane number, higher heating value and oxidative stability were evaluated and found technically compatible and comparable with EN 14214 and ASTM D 6751 specifications. Furthermore, exhaust emission levels of CO, NOx and PM from the engine exhaust operated on biodiesel and its blends (B-5, B-20, B-40, B-50, B-80 and B-100) were also estimated. Prominent reduction in both CO and PM whereas, irregular trends in NOx emissions were depicted from engine exhaust operated on biodiesel and its blends comparative to engine exhaust emissions based on petro diesel. Based upon the above described results, it can be depicted that biodiesel is an environment friendly alternative to the conventional petrodiesel.
شفیق الرحمن قدوائی شفیق الرحمن مرحوم اگر چہ شہرت و ناموری کے عام معیار سے کو ئی بڑے آدمی نہ تھے مگر اپنے ایثار و قربانی، اخلاق وکردار، اخلاص و عمل اور خاموش اور بے لوث خدمات کے لحاظ سے بہت سے بڑے بڑے لیڈروں پر فائق تھے، جامعہ ملیہ کے لئے تو انھوں نے اپنی زندگی وقف کردی تھی اور سرد و گرم دور میں بھی اس سے جدا نہ ہو ئے، اور یہ کہنا غلط نہ ہوگا کہ جامعہ انہی کی محنت و جانفشانی کی بدولت زندہ رہ گیا، ظاہر وباطن دونوں میں مسلمان اور اپنے اوصاف کی بنا پر ہر جماعت میں مقبول تھے، کا نگریس اور حکومت دونوں کے سنجیدہ طبقہ میں ان کا بڑا وقار و وزن اور اخلاقی اثر تھا، مگر وہ اتنے بے لوث تھے کہ کبھی اس اثر سے فائدہ اٹھانے کی کوشش نہیں کی، ان کو بنیادی تعلیم کا عملی تجربہ تھا، اس کے وہ ماہر تھے، اس لئے یو این او کی جانب سے اس کام کے لئے انڈونیشیا بھیجے گئے تھے، ابھی وہ وہیں تھے کہ گذشتہ الیکشن میں کانگریس نے ان کو دہلی اسمبلی کے لئے مقرر ہو ئے، مگر اس سے بھی ان کا فائدہ اٹھانے کا موقع نہ مل سکا، تھوڑے ہی دنوں کے بعد بیمار پڑگئے، اور چند مہینے بیمار رہ کر ۳؍ اپریل کو انتقال کیا، انتقال کے وقت کل ۵۳ سال کی عمر تھی جو سیاست کی دنیا میں عین شباب کی عمرہے، مسلمانوں میں اب ایسے مخلص اور باعمل آدمی مشکل سے پیدا ہوں گے، اﷲ تعالیٰ اس پیکر اخلاص کو اپنی رحمت و مغفرت سے سرفراز فرمائے۔ (شاہ معین الدین ندوی، اپریل ۱۹۵۳ء)
Background and Aim: Sacroiliac joint pain is localized in the region of sacroiliac joint which can be increased by stress and provocation tests of the joint. Aim of this study was to compare two interventions for reduction of sacroiliac joint pain.
Methodology: Study design was randomized clinical trial. Study was conducted in bajwah hospital and children polyclinic Lahore. Duration of study was six months. The total sample size was 64 patients. Females of 20-50 years old with diagnosed sacroiliac joint pain were included in this study. Compression and distraction objective tests were performed for further confirmation of sacroiliac joint pain. Purposive sampling technique was used. Numeric pain rating scale (NPRS) and Oswestry low back disability questionnaire (ODI) were used to collect the data. Exclusion criteria was females with fractures and other abnormalities of spine.
Results: Results showed that both groups were equal when assessed on baseline by normality test colmogorov-smirnova. Independent t test was applied to compare the mean value of NPRS. Pretreatment mean of NPRS scale for both the regional treatment and standard treatment groups was 7.After 4 weeks NPRS of regional treatment group was 4 and of standard treatment group was 7. The mean value of pretreatment ODI for regional treatment group was 33 and for standard treatment group was 34.After 4 weeks ODI of regional treatment group was 24 and mean of standard treatment group was 27.
Conclusion: It is concluded that after giving equal sessions to both groups when results were assessed regional treatment is more effective than standard treatment.
Regionalism emerged in international politics after the World War II, but the end of Cold War has significantly impacted on global politics and regionalism. It is a new phenomenon and nowadays it is difficult to find a country that is not a member of at least one regional organization. Even some of them are the members of more than one regional organizations and international organizations. Economic Cooperation Organization (ECO) as a regional organization established by Pakistan, Iran and Turkey in1985, but after the Cold War Central Asian countries also joined the Organization and ECO expanded with a new situation. In this study to better explain and analyze regionalism in ECO, nefunctionalism, interdependence and liberal intergovernmentalism theories are examined and used together in the context of globalization. It seems that non of theory alone can explain the perfect situation of the region. The advance of technology and information revolution have considerably accelerated globalization and vice versa. Consequently interdependence amongst nations also has been increasing. Such conditions have affected to rise regionalism as a requirement of nations to promote their interests through regionalism particularly after the Cold War. Thus globalization is a main driver of regionalism, however there is interaction between globalization, regionalism and nation-states. The nation-states can manage to take the best advantages of globalization age and remain as an important actor. In globalization age, economic interdependence between the members on the one hand and interdependence between the regions and countries on the another hand have considerably affected on the shape and progress of ECO. Common historical heritage, culture, social and many other factors also have impacted on ECO. Geo-economic and geostrategic locations of ECO also have had important role in the establishment of the organization. The region is very rich in oil and gas which are the main factors of development. Globalization, growth of technology and economic development of EU, China and India''s have impacted on the requirement of energy. These countries have been suffering from shortage of energy and ECO can help them out their energy crisis. Moreover ECO members are also dependent on manufacturing and technology of advance countries like EU, China and other countries. Thus although the process of regionalism in ECO is not fast like EU, interdependence in energy, trade and many other factors within the region and outside the region can drive an push integration not only in the region but also with the other regions and countries.