Low cost oxidized and un-oxidized activated carbon samples were prepared from saw dust and seed shells of Ziziphus jujube by chemical activation with phosphoric acid (H3PO4), followed by carbonization at 450 oC. The prepared carbon samples were characterized and utilized for the adsorptive removal of toxic heavy metals from aqueous solutions such as chromium (VI), cadmium (II) and lead (II) ions. All samples were found to be microporous in nature with low ash content, sufficient BET surface area and pore volumes. The effect of various parameters like solution pH, contact time, initial concentration, temperature, carbon dosage and shaking speed, on adsorption of metal ions was investigated. The adsorption of Cr (VI) decreased while that of Cd (II) and Pb (II) increased by increasing pH. Maximum adsorption of Cr (VI) was observed in the pH range of 2–4 at equilibrium time of 300-420 min. Equilibrium time for Cd (II) and Pb (II) adsorption was found to be 420-480 min at all temperatures. Batch experiments revealed that the adsorption of all the metal ions increased with increase in contact time, initial concentration, temperature and carbon dosage, etc. Thermodynamic studies indicated the feasibility, spontaneity and endothermic nature of the adsorption process. Among different isotherm and kinetic equations, Langmuir’s model and pseudo - second order equation were found to better describe the experimental data. The adsorption capacity of oxidized samples was found to be higher than that of un-oxidized samples for Cr (VI) but lower for Cd (II) and Pb (II). In comparison to Cd (II) ions, the removal of Pb (II) ions was higher. The results suggested that the prepared activated carbon samples could be used effectively as eco-environment friendly adsorbents for removal of Cr (VI), Cd (II) and Pb (II) ions from aqueous solutions. Keywords: Activated carbon; Ziziphus jujube; Adsorption; Heavy metals; Chromium; Cadmium; Lead; Thermodynamic; Kinetic
آہ ذاکر صاحب ! ڈاکٹر ذاکر حسین صاحب کی ناگہانی وفات ہندوستان کا بہت بڑا قومی حادثہ ہے، وہ اسکا گوہر بے بہا تھے، ان کی موت سے وہ ایسی دولت سے محروم ہوگیا جس کی تلافی نہیں ہوسکتی، کم سے کم مسلمانوں میں ان کا بدل پیدا ہونا بہت دشوار ہے اور اب وہ اس نقصان کو محسوس کریں گے، وہ اپنے علمی کمالات ، فہم و فراست، قومی و تعلیمی خدمات، ایثار و قربانی اور اخلاق و سیرت کے لحاظ سے بہت بڑے انسان تھے، انھوں نے سیاست کے میدان میں کبھی قدم نہیں رکھا، لیکن اپنی بصیرت سے بڑی بڑی سیاسی گتھیوں کو آسانی سے سلجھا دیتے تھے، پنڈت جواہرلال نہرو کے بعد بین الاقوامی دنیا میں ہندستان کا وقار اُن ہی نے قائم رکھا۔ ان میں ابتدا سے غیر معمولی صلاحیتیں تھیں، ان کا آغاز ہی ان کے روشن مستقبل کا پتہ دیتا تھا طالب علمی ہی کے زمانہ سے ان کا قومی خدمت کا ولولہ اور ایثار و قربانی کا جذبہ تعلیم یافتہ نوجوانوں اور قومی کارکنوں کے لیے نمونہ تھا، اس زمانہ اور اس عمر میں جب ہونہار نوجوانوں کا منتہائے نظر اور ترقی کی سب سے بڑی معراج سرکاری عہدے اور تعیش کی زندگی تھی، انھوں نے ان کی طرف آنکھ اٹھا کر بھی نہ دیکھا، اور ان کے مقابلہ میں قومی خدمت اور غربت کی زندگی کو ترجیح دی اور اس راہ میں عمر کا بہترین حصہ صرف کردیا، ان کا زندہ کارنامہ ہندوستان کی پہلی آزاد قومی درسگاہ جامعہ ملیہ ہے، گو اس کے بانی حضرت شیخ الہند حکیم اجمل خاں اور مولانا محمد علی وغیرہ تھے۔ لیکن اس کے اصلی معمار وہی تھے، اور ان ہی نے جامعہ کو جامعہ بنایا اور اپنی زندگی میں اپنے لگائے ہوئے پودے کو ایک تناور درخت بنا گئے، اور آج...
The advancement in science and technology has made the world peace and prosperity very important at this time in the human history. We find in the human history, since it was recorded, that almost all the civilizations were very intolerant, brutal to their opponents, especially, to the believers of other religions. On the other hand, the Islamic states were the most tolerant and accommodating to other religions. This fact is proved from the early history of Islām during the period of the Prophet Muḥammad (r) and his immediate successors. Similar is the case in the later history of the Muslims, during the period of the Abbasid, the Umayyids in Spain, the Turks, the Mughal era and in the Far East. Human and economic losses in wars were very huge during the first, the second world wars, and the current wars being fought in Iraq and Afghanistan. The human and material losses are horrible. The author believes that the Prophet Muḥammad (r) ’s teachings and traditions of moderation, tolerance, human respect, freedom of religious practice are the only ways to peace and prosperity in the world.
This thesis is concerned with the expansion of diagnostic methods in parametric regression models with some biased estimators. Of which, the Liu estimator, modified ridge estimator, improved Liu estimator and ridge estimator have been developed as an alternative to the ordinary least squares estimator in the presence of multicollinearity in linear regression models. Firstly, we introduce a type of Pena’s statistic for each point in Liu regression. Using the forecast change property, we simplify the Pena’s statistic in a numerical sense. It is found that the simplified Pena’s statistic behaves quite well as far as detection of influential observations is concerned. We express Pena’s statistic in terms of the Liu leverages and residuals. For numerical evaluation, simulated studies are given and a real data set has been analyzed for illustration. Secondly, we formulated Pena’s statistic for each point while considering the modified ridge regression estimator. Using this statistic, we showed that when modified ridge regression was used to mitigate the effects of multicollinearity, the influence of some observations could be significantly changed. The normality of this statistic was also discussed and it was proved that it could detect a subset of high modified ridge leverage outliers. The Monte Carlo simulations were used for empirical results and an example of real data was presented for illustration. Next, we introduce a type of Pena’s statistic for each point in the improved Liu estimator. Using this statistic, we showed that when the improved Liu estimator was used to mitigate the effects of multicollinearity, the influence of some observations could be significantly changed. The Monte Carlo simulations were used for empirical results and an example of real data was presented for illustration. The ridge estimator having growing and wider applications in statistical data analysis as an alternative technique to the ordinary least squares estimator to combat multicollinearity in linear regression models. In regression diagnostics, a large number of influence diagnostic methods based on numerous statistical tools have been discussed. Finally, we focus on ridge version of Nurunnabi et al. (2011) method for identification of multiple influential observation in linear regression. The efficiency of the proposed method is presented through several well-known data sets, an artificial large data with high-dimension and heterogeneous sample and a Monte Carlo simulation study.