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Home > Removal of Selected Metal Ions from Aqueous Media by Agricultural Wastes: Kinetic and Thermodynamic Studies

Removal of Selected Metal Ions from Aqueous Media by Agricultural Wastes: Kinetic and Thermodynamic Studies

Thesis Info

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Author

Kausar, Abida

Program

PhD

Institute

University of Agriculture

City

Faisalabad

Province

Punjab

Country

Pakistan

Thesis Completing Year

2014

Thesis Completion Status

Completed

Subject

Chemistry

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/2379/1/2833S.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727081815

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In the present research study, biosorption efficacy of agro-wastes (rice husk, bagasse, peanut husk, cotton sticks and wheat bran) for U, Zr and Sr removal from aqueous media was investigated. Rice husk, bagasse and peanut husk were selected as most efficient biosorbent for the removal of U, Zr and Sr ions respectively. These selected biomasses were subjected to different pre-treatments (Physical and chemical) and modifications (immobilization). Batch biosorption affecting parameters like pH, sorbent dose, initial metal ion concentration and temperature were optimized for native, pre-treated and immobilized biomasses to get maximum removal. Maximum biosorption capacity values were found at pH (4-5), (3-4) and (7-9) for U, Zr and Sr ions respectively for native, pre- treated and immobilized biomasses. The amount of metal ions sorbed (mg/g) decreased with increasing biosorbent dose and increased at higher initial metal ion concentration. Linear and non-linear regression forms of pseudo-first and second-order were studied and value of R2 and six non-linear regression error functions namely hybrid fractional error function (HYBRID), Marquardt’s percent standard deviation (MPSD), average relative error (ARE), sum of the errors squared (ERRSQ/SSE), sum of the absolute errors (EABS) and Chi-square test (χ2) were used to predict the most optimum kinetic model. Sorbent- sorbate reaction nature was estimated by fitting equilibrium data by non-linear and transformed linear forms of the Langmuir, Freundlich and Redlich-Peterson isotherms and most optimum isothermal model was optimized by comparing linear and non-linear R2 value and non-linear regression error functions. Calculated values of thermodynamic parameters i.e. ΔG ̊, ΔH ̊ and ΔS ̊ showed that studied processes are feasible and spontaneous. Response surface methodology using face-cantered central composite design was used to design experiments for biosorption of U(VI), Zr(IV) and Sr(II) ions onto biomasses. Significance of main, interaction and square effects of quadratic model was determined by ANOVA, F-test and p value. Adsorption/desorption studies showed that biosorbents can be reused successfully. Effect of interfering ions (cations & anions) on the removal efficiencies was studied. The column biosorption was also done and effect of bed height, flow rate and initial metal ion concentration was also studied by breakthrough curves and applying Bed Depth Service (BDST) and Thomas model. BET, SEM-EDX, TGA, XRD and FTIR analysis were carried out to characterize the biomasses. The whole study proved that selected agro-wastes have good removal potential for U(VI), Zr(IV) and Sr(II) ions containing wastewater.
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نواب حمیداﷲ خاں

نواب حمیداﷲ خاں
گزشتہ مہینے نواب حمید اﷲ خاں مرحوم کے انتقال کی خبر اس وقت ملی جب شذرات کی کاپی جم چکی تھی، اس لیے معارف اس حادثہ پر اپنے تاثرات کا اظہار نہ کرسکا، نواب صاحب مرحوم اپنے اوصاف و خصوصیات میں دوسرے والیان ریاست سے بہت مختلف تھے، ان میں دین و دنیا کی بہت سی خوبیاں جمع تھی، فہم و فراست اور تدبیر و سیاست میں وہ ہندوستان کے ممتاز مدبروں میں تھے، اور ہر طبقہ میں بڑی، عزت و وقعت کی نظر سے دیکھے جاتے تھے، مذہبی اعتبار سے عملاً دیندار تھے، والیان ملک میں اس زمانہ میں وہ تنہا حافظ قرآن تھے، حج و زیارت کے شرف سے مشرف ہوئے تھے، ان کی تعلیم و تربیت عام شہزادوں کے برعکس بڑی سادگی سے ہوئی تھی اور انھوں نے بغیر کسی امتیاز کے علی گڑھ کالج میں عام طلبہ کی طرح تعلیم پائی تھی، جس کا اثر بعد میں ان کی زندگی پر رہا چنانچہ ان کے یہاں درباری آداب و تکلفات نہ تھے اور ہر شخص سے عام انسانوں کی طرح ملتے جلتے تھے۔
نواب صدیق حسن خاں مرحوم کے اثر سے ریاست بھوپال میں اس زمانہ میں بھی مذہب کے بڑے اثرات تھے جس سے دین و ملت کو بڑا فائدہ پہنچا مسلمانوں کا کوئی دینی و تعلیمی ادارہ اس ریاست کے فیض سے محروم نہ تھا، یہ وراثت نواب حمید اﷲ خاں کے حصہ میں بھی آئی تھی بلکہ ان کی صحیح تعلیم و تربیت نے ان خیالات میں اور زیادہ جلا پیدا کردی تھی، اور انھوں نے اپنے دور حکومت میں بہت سی اصلاحات کیں، وہ ایک عرصہ تک مسلم یونیورسٹی کے چانسلر بھی رہے تھے، دارالمصنفین بھی ریاست بھوپال کے ابرکرم کا ممنون تھا، بلکہ اس کا قیام ہی نواب سلطان جہاں بیگم مرحومہ کی فیاضی...

The Impact of SMEs on the Economic Development of Pakistan

Pakistan is a country where the expansion of the industrial sector is necessary, and in this process, the relative significance of the Small and Medium Enterprises (SMEs) sector cannot be overstated. SMEs comprise approximately 90% of total businesses in Pakistan; nearly 80% of the workforce other than the agriculture sector is employed by the SMEs; and approximately 40% of GDP is contributed by the SMEs.1 Though, the growth of SMEs is constrained by financial and other resources that is not faced by Large Scale Manufacturing (LSM) sector. From the facts and figures presented in this paper, it can be concluded that SMEs perform a dynamic role in the growth of all the related sectors of the economy. This study empirically analyzes the effect of innovation and activities of SMEs on economic growth of Pakistan over the span of 19732017. The study concludes that the activities of SMEs do influence the economic development of Pakistan.

Assessment of Selected Persistent Organic Pollutants in River Ravi and its Northern Tributaries, Pakistan

The persistent organic pollutants (POPs), particularly organochlorines are of key global concern due to their persistence and toxicity in the environment. The present study investigated the occurrence levels, spatio-temporal distribution, risks to both, ecological integrity and human health through dermal and oral exposure to the organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) across River Ravi and its three northern tributaries (Nullah Bein, Nullah Basantarand Nullah Deg) that provides the baseline data for the occurrence of POPs from the study area. The present study is a pioneer investigation from Pakistan to assess the bioavailable level of POPs using mussels as bioindicator species. The water (n=54) and sediments (n=54) samples from twenty-seven sampling sites and freshwater mussels (n=30) samples from fifteen sampling stations were collected across the four aforementioned streams in two alternate seasons (pre-monsoon and post-monsoon). The ∑23OCPs concentrations were ranged from 13.61 to 1992.18 ng/g dry weight (dw), 189.66 to 2049.40 ng/g, and 12.89 to 128.16 ng/L in sediment, freshwater mussels and water matrices, respectively. The ∑35PCBs concentrations were ranged from 1.06 to 95.76 ng/g (dw) in sediments, 1.94 to 11.66 ng/L in water, and 25.81 to 135.38 ng/g in freshwater mussel samples. Among the OCPs, the dominance of ΣDDTs, ΣHCHs and Σendosulfan were observed in all three studied environmental matrices. The PCBs homologs analysis indicated that penta-CBs and hexaCBs in sediments and mussels, and tetra-CBs and tri-CBs in water were predominant homologs. Based on the POPs contamination levels, the tributaries of River Ravi followed the contamination order as; Nullah Deg> Nullah Basantar > Nullah Bein and fresh addition of lindane, technical DDTs and chlordane were identified in the study area. The OCs levels in the environment were found to be higher than previous studies from Pakistan and other parts of the world. The ecological risk assessment indicates considerable potential ecological risk (= 95.17) associated with PCBs contaminations. The ecological risk assessment of OCPs elucidates high risks for endosulfan (αendosulfan) and endrin. The human health risk assessment indicated absence of hazardous (non-carcinogenic) risk through dermal exposure in studied streams; while, the considerable carcinogenic risks associated to aldrin, dieldrin, p,p’-DDT, β-endosulfan and PCBs was found at certain studied sites. The oral exposure to OCs through mussels consumption revealed existence of substantial carcinogenic risk (Hazard Ratio > 1) for OCPs and PCB at both, 50th and 95th percentile concentration in mussel tissues. Therefore, the high levels of ecological risk and carcinogenic human health risk had emphasized an immediate elimination of ongoing OCPs usage and PCBs release in the studied area. Moreover, in Pakistan, comprehensive ecological and human health risk studies, and firm statutory initiatives are needed to be taken in debt to the Stockholm Convention, 2001 to cope up with the OCs contamination in various environmental matrices of the country.