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Structural and Superconducting Properties of Cutl-12 N-1 N N = 3, 4/Nanostructures Composites

Thesis Info

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External Link

Author

Qasim, Irfan

Program

PhD

Institute

International Islamic University

City

Islamabad

Province

Islamabad.

Country

Pakistan

Thesis Completing Year

2016

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/2792/1/Irfan_Qasim_Physics_2016_HEC_Scholar_Pd7-052_HSR_IIU_21.10.2016.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727245354

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Nanostructures/(CuTl) 0.5 Ba 2 Ca n-1 Cu n O (2n+4)–δ , {CuTl-12(n-1)n}; n = 3, 4} superconducting composites were synthesized by solid-state reaction (SSR) technique and their superconducting behavior was examined by different available experimental techniques. Anti-ferromagnetic chromium (Cr) nanoparticles (NPs), ferromagnetic cobalt (Co) and nickel (Ni) NPs, non-magnetic zinc (Zn) NPs and carbon nanotubes (CNTs) of different wt. % have been inserted in CuTl-12(n-1)n; n = 3, 4 superconducting matrices and their effects on the structure, morphology and composition was carried out by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy. The transport properties and magnetic field response were explored by restivity versus temperature (RT) measurements with the help of four point probe method and ac-susceptibility (χ ac ) measurements, respectively. The experimental data was further analyzed theoretically by different models such as Aslamazov-larkin (AL), Lawrence-Donaich (LD) and Maki-Thompson(MT) models. It has been observed that the inclusion of different nanostructures (NS) in polycrystalline CuTl-12(n-1)n; n= 3, 4 superconducting matrices do not change their tetragonal structure and stichoimetry. Increasing concentrations of magnetic NPs (Cr, Co,Ni) additions in host CuTl-12(n-1)n}; n= 3, 4 superconducting matrices reduce the diamagnetic strength and superconducting volume fraction and cause suppression in characteristic superconducting parameters. The suppression of superconducting parameters after addition of these magnetic NPs can be accredited to spin scattering of carriers due to net magnetic moment, which tend to remain align in particular blocked state and oxygen disorder in superconducting regions. Non-magnetic Zn and CNTs also diminish superconductivity because of enhanced carrier scattering cross section at inter- crystallite sites. Theoretical fluctuation induced conductivity (FIC) analysis confirm the suppression of superconducting characteristic parameters by these NS inclusions in CuTl- 12(n-1)n}; n= 3, 4 superconducting matrices. Decrease in coherence length (ξ), increase in penetration depth (λ p.d ) and shifting of 3D regions towards lower temperature values illustrate the increased insulation at grain-boundaries and decrease in optimum charge carriesr density after addition of these NS in CuTl-12(n-1)n}; n= 3, 4 superconducting matrices
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رشید آفریںؔ

رشید آفریںؔ(۱۹۳۸ء۔پ) کا اصل نام محمد رشید ہے۔ آپ محلہ مجید پورہ سیالکوٹ میں پیدا ہوئے۔ایم۔اے اردو پنجاب یونیورسٹی سے کیا۔ آپ بچپن سے ہی شعر و شاعری کر رہے ہیں۔ اکبر لاہوری سے شاعری میں اصلا ح لیتے تھے(۹۳۳) آپ کا شعری کلام ماہنامہ’’حور‘‘ لاہور ماہنامہ’’شمع‘‘،لاہور ماہنامہ ’’ماہِ نو‘‘ لاہور ماہنامہ’’اقدار‘‘ کراچی ماہنامہ’’رابطہ‘‘ کراچی ماہنامہ ’’نئی قدریں ‘‘ حمید آباد ،ماہنامہ’’ادبِ لطیف‘‘ لاہور ،ماہنامہ ’’ادبی دنیا‘‘ لاہور ،ہفت روزہ’’برمنگھم‘‘ برطانیہ، ماہنامہ ’’اوراق‘‘ لاہور اور دیگر ملکی اور بین الاقوامی رسائل و جرائد میں شائع ہوتا رہا۔ ’’وجہ آفریں‘‘ آپ کا پہلا شعری مجموعہ ہے جسے مکتبہ فردوس سیالکوٹ نے ۱۹۷۲ء میں شائع کیا۔ دستِ ساحل‘‘ آفریںؔ کا دوسرا شعری مجموعہ ہے جسے الحمد پبلی کیشنز نے ۱۹۹۵ء کو طبع کیا۔ ’’دامن احساس‘‘آپ کا تیسرا شعری مجموعہ ہے جسے الرزاق پبلی کیشنز نے ۲۰۰۲ء میں شائع کیا۔ ’’فخر دو عالم‘‘ رشید آفریں کا چوتھا شعری مجموعہ ہے جو نعتیہ شاعری پر مشتمل ہے۔

رشید آفریں غزل کے شاعرہیں لیکن غزل کے ساتھ ساتھ انھوں نے نظم ،حمد ،منقبت،سلام ،نعت اور قطعات بھی لکھے ہیں۔ کشمیریات کے حوالے سے خصوصاً ان کی نظمیں دردو غم میں ڈوبی ہوئی ہیں۔ اور کشمیر سے ان کی محبت کی عکاسی کرتی ہیں۔اس کے علاوہ قومی ترانے ،قومی و ملی نظمیں اور بانیانِ پاکستان کے حوالے سے لکھی نظموں میں وطنیت اور قومیت کا واضح اظہار ملتا ہے۔

رشید آفریں ادب میں مقصدیت کے قائل ہیں ان کے ہاں غیر مقصدی ادب کی کوئی اہمیت نہیں ہے۔ ان کی شاعری میں روایت اور جدت کا امتزاج پایا جاتا ہے۔ ان کا لہجہ پر درد اور موثر ہے۔ انھوں نے اپنی شاعری کو پورے سماج کا ترجمان بنایا ہے۔ ان کی نظموں میں روانی و برجستگی اور خلوص فن کی صداقت کی جیتی جاگتی تصویریں...

Art and Architecture as A Space for Kalash Identity (A Case Study of Bumburet Valley in District Chitral Pakistan)

The present study was conducted in Bumburet valley of Kalash, District Chitral, Pakistan. The key technique used for data collection was participant observation in which the researcher lived in the community, observed and documented their cultural patterns as an indicator of their traditional culture which includes religious songs, folklore, dress, art and crafts, as a basis for identity. The basic purpose of the study was to understand the role and significance of arts and architecture as a prime tool for establishing identity for the conventional people of Kalash. The people of Kalash have managed to maintain their identity through their unique arts and crafts. Tradition resists change and most often remains unaltered in a static spatial arrangement. The changes which incorporate in Kalash traditions may find their way through peripheral adjustments. The traditions in art and crafts are scanty to find and the present artifacts does not throw any light on their origin. The art and architecture available signify their unique ways, and tradition which is definitely different from the other ethnic tribes in the shared geographical arrangement. The Kalash ethnic identity has faced several challenges like colonization in the past and modernization and technological advancement and conversion to Islam in the present. The Kalash insist on keeping their self-identity as well as participating in modernity. They have maintained their centuries old traditional culture, despite the fact of current globalization, and modernization.

Crop Yield, Soil Properties and No3-N Distribution in Soil Profile in Response to Tillage, Irrigation and Fertilizer Practices

Over and ill-timed application of nitrogen (N), intensive tillage and heavy irrigation could lead to build up of residual nitrate in surface as well as subsurface soil layers, low fertilizer use efficiency and contamination of ground and surface water with nitrates. This is particularly true in wheat-maize crop rotation where high rates both of N and irrigation and intensive tillage are practiced to get higher yields. However, limited literature is available on the fate of applied N in wheat–maize cropping system in response to tillage, irrigation and fertilizer practices in Pakistan. Hence two experiments were conducted in the Research Area, Institute of Soil and Environmental Sciences, University of Agriculture, Faisalabad to assess the effect of irrigation, nitrogen and fertilizer practices on soil properties, crop yield, carbon sequestration and NO3-N under wheat-maize cropping sequence for two consecutive years from 2011-2013. In the first study, treatments comprised of three levels of irrigation and four levels of N in split plot design. Three levels of irrigation were 0.7, 1.0 and 1.3 of the estimated evapo-transpiration (ETc). The four N levels were 0, 110, 160 and 210 kg N ha-1 for wheat and 0, 200, 250 and 300 kg N ha-1 for maize, the recommended rate N for wheat (Triticum aestivum L.) and maize (Zea mays L) in this area is 110 and 200 kg ha-1, respectively. The N was applied either in two splits (50% at sowing + 50% at maximum tillering for wheat, 50% at sowing + 50% at knee height for maize) or three splits (50% at sowing + 25% at maximum tillering + 25% at spike initiation for wheat, 50% at sowing + 25% at knee height + 25% at tasseling for maize), therefore making a total of seven N treatments. In the second experiment, same cropping system was followed, however recommended rate of N (110 and 200 kg N ha-1 for wheat and maize, respectively) was sourced from either urea or combination of urea and farm manure (FM). Thus, there were three fertilizer treatments F1 (100% N from urea), F2 (75% N from urea and 25% N from FM) and F3 (50% N from urea and 50% from FM) at three tillage systems namely MT (minimum tillage), CT (conventional tillage) and DT (deep tillage). The treatments were replicated three times in split plot design using tillage in main plots and fertilizer practices in sub plots. The data on growth and yield parameters were recorded for both the crops at harvest. Before sowing the first crop and after harvesting fourth crop, soil samples were collected and characterized for physical (bulk density, soil saturated hydraulic xx conductivity and total porosity) and chemical (soil organic carbon and nitrate-N) properties following standard procedures. The results from the first study indicated that N at 110 and 250 kg ha-1 for wheat and maize crops, respectively not only increased growth, yield and water use efficiency of both the crops during both the years but also decreased buildup of NO3-N in soil. Application of N in 3 unequal splits (50%+25%+25%) proved better than application of N in 2 equal splits (50%+50%) in terms of improved crop yield, crop N recovery, water use efficiency and less accumulation of NO3-N in soil profile. Application of irrigation water according to crop water requirement was the best treatment in terms of better yield, crop N recovery and water use efficiency along with lower leaching of NO3-N into sub-soil. Deficit irrigation resulted in lower crop yield and higher buildup of residual NO3-N in soil. In contrast, excessive irrigation did not have any additional benefits in terms of crop yield, however resulted in lower water use efficiency and crop N recovery and greater concentration NO3-N in lower depths of soil. Results from the second field study revealed that deep tillage and conventional tillage along with combined application of inorganic and organic N sources (half N from urea + half N from FM) resulted in lower bulk density, higher saturated hydraulic conductivity and root length density (RLD) compared that with the minimum tillage. The results indicated that MT resulted in significantly higher SOC pools in surface soil (0-10 cm), conversely DT and CT caused high SOC pools in 10-40 cm soil depths. Therefore, averaged across 0-40 cm, DT and CT proved better in terms of SOC pools. The DT and CT caused greater RLD and stocks of total N and available P in soil with DT and CT compared to that with MT caused significantly higher crop yield. The DT and CT also resulted in significantly greater accumulation of NO3-N in soil compared to that with MT treatment.