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Study of Divalent and Trivalent Cations Substitution on X-Type Hexagonal Ferrites

Thesis Info

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Author

Ejaz, Syeda Rabia

Program

PhD

Institute

The Islamia University of Bahawalpur

City

Bahawalpur

Province

Punjab

Country

Pakistan

Thesis Completing Year

2019

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/12354/1/Syeda%20Rabia%20Ejaz%20physics%202019%20iub%20prr.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727370195

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In the present research work four X-type hexagonal ferrites series with compositions Ba2-xMgxCo2-ySryFe28O46, Sr2-xCaxNi2-yBayFe28O46, SrBaCu2-xCoxCryFe28-yO46 and SrBaZn2-xNixAlyFe28-yO46 where x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and y= 0.0, 0.1, 0.2, 0.3, 0.4, 0.5 have been synthesized by sol gel auto-combustion method. The characterization of the entire compositions has been done by thermo-gravimetric analysis (TGA), x-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), dielectric measurements, vibrating sample magnetometer (VSM) and scanning electron microscopy (SEM). Thermo-gravimetric investigation reveals that hexagonal phase begins to form at a temperature ~1050 ºC and is completed at 1250 ºC for X-type hexagonal phase formation, which is also complimented by the XRD studies. The average crystalline sizes of four compositions were found within the range of 19-40nm. The variations in the lattice constants were in accordance with the dissimilarity in ionic radii of the host and substituted ions. FTIR analysis of entire synthesized compositions was observed in the range of 400-800cm-1 which indicated the existence of two vibrational bands appeared due to the octahedral and tetrahedral stretching vibrations. SEM images showed the hexagonal platelets structure which is best for microwave applications. The dielectric measurements of all synthesized composition were evaluated as the function of frequency and their behavior was described on the basis of Maxwell-Wagner and Koop’s theories. The obtained results revealed that dielectric constants, tan loss and the conductivities were found to be increased with the increased ratio of Mg-Sr, Ca-Ba and Co-Cr substituted synthesized samples. While the decreased trend in the dielectric constant for Ni-Al substituted samples are observed. Electric modulus studies were done to examine the relaxation behavior for all samples. To ensure the influence on magnetic characteristics of different divalent and trivalent cations substitution in synthesized compositions, vibrating sample magnetometer (VSM) was used. The variation in saturation magnetization, coercivity and remanence was observed on the basis of allocated cations in the different hexagonal lattice sites. The linear increase in saturation magnetization, remanence and coercivity in Co-Cr and Ni-Al substituted hexaferrite made them useful as permanent magnets while the decrease in saturation magnetization and coercivity in Mg-Sr and Ca-Ba substituted samples proposed these materials best for magnetic recording media as well as for microwave devices.
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ادارہ (ایم پی ڈی ڈی) لاہور کا آنکھوں دیکھا حال

ادارہ MPDD لاہور کاآنکھوں دیکھا حال
(ڈپٹی ڈسٹرکٹ اٹارنی محمداسلم بھٹی بہاول نگر والے کی فرمائش پر لکھی گئی نظم )
آنکھوں دیکھا حال ہم تم کو سنائیں گے
کیسے گزرے MPDD میں دن منظر عام پرلائیں گے
شروع شروع میں آئے یہاں پر دل ہمارے مسرور تھے
پہلے دن تھی خوش طبیعت خوشی کے نشے میں چور تھے
سوچ میں ڈوبے بنے منصوبے فکروں سے ہم دور تھے
بے فکری پر اتنے کھاتے سوچا دوستوں کو بلوائیں گے
اتنے بہت زیادہ خوش ذائقہ تھے کھانے
عزت نفس مطلوب تھی جس کو ہر کوئی جانے
حاضر رہن دماغ ہمارے جیسے مراقبہ میں درویش سیانے
انگلش میں سوال و جواب وہ کیفیت نہ بتلائیں گے
وقت مقررہ ٹائمنگ ملتی دیر ذرا نہ کرتے تھے
دوستوں کو جب ملتے تو دل ہمارے نہ بھرتے تھے
ایسے ہوئے حالات ہمارے پل پل جیتے مرتے تھے
جیسے ہوں گے حالات ہمارے پھر بھی نہ گھبرائیں گے

حال ہمارا ایسا تھا جتنے چست چالاک بھی تھے
ذہنوں میں کچھ خوف تھا کچھ وہ کرب ناک بھی تھے
کئی ہم میں ایسے تھے جو صاحب خوش پشاک بھی تھے
تہم ہی بتائو کیسے ہم پھر سکھ کی سیج سجائیں گے
تربیت گاہ کے حال میں جب SO تشریف لاتے تھے
انگلش جن کی ویک تھی وہ بہت ہی گھبراتے تھے
سی سی ٹی وی کیمرے سارا حال بتاتے تھے
آئے پسینے دھڑکن سینے سوچا چین سکون نہ پائیں گے
چاولہ سائیں ؔہر مشکل کے بعد ہوتی ہے آسانی
اس دنیا میں اچھا کرجا تیری رہ جائے گی کہانی
مال و دولت دنیا ساری ایک دن ہوجائے گی بیگانی
وہ وقت بھی آئے گا جب ہم بہت...

Arrhythmias after Implantation of the Left Ventricular Assisted Device Arrhythmias after Implantation of the Left Ventricular Assisted Device

Cardiac arrhythmias has been frequently reported after left ventricular assist devices implantation but currently literature shows no sufficient information on cardiac arrhythmias. Objective: The aim of this study was to assess the frequency and other features of ventricular and supra ventricular ectopic beats ((SVEB), atrial fibrillation (AF)/flutter (AFL) post device implantation. Methods: This is a retrospective study conducted in Department of Cardiac-Surgery, University of Verona Medical School, Verona, Italy from June 2014-September 2016. Rhythm monitoring and registration were collected from 16 patients (13 males; 45±13years) during the first five (05) days after implantation. To assess late post-operative rhythm, patient’s hospital electronic records were used as well asfunctional hemodynamic parameters including mean arterial pressure(MAP), right atrial pressure(RAP), heart rate(HR) and ST-deviation(d-ST). Results: Ventricular arrhythmia (n=9), atrial fibrillation (n=5) or atrial flutter (n=2) episodes were preoperatively present in 11 patients. Postoperatively, 5 patients developed either VT (n=2), AF (n=1) or both VT/AF (n=2) during a follow-up of 18±14 months. Prior to postoperative VT (POVT) episodes (n=123), MAP decreased, HR, d-ST increased and RAP remained unaltered. POVT were initiated either by single VEBS (28%), V-couplets (15%), V-run (46%) or occurred suddenly (11%). Conclusions: Ventricular and supraventricular arrhythmias are common after device implantation. The frequency of sustained VTA was less at early phase as compared to late postoperative phase.

Linear and Nonlinear Dynamics of Space and Laboratory Plasma

Linear and non-linear dynamics of di erent electrostatic modes is studied in inhomoge- neous, magnetized and non-Maxwellian plasmas. A linear dispersion relation is obtained for the Ion Temperature Gradient (ITG) mode and numerically analyzed in the presence of dust charge uctuations and Kappa distributed electrons. It is found that these nonthermal pop- ulations reduce the growth rate ITG. It is also noticed that the characteristics of ITG driven vortices change with the value of spectral index, inhomogeneities, scale lengths and dust charge uctuations. Electron Temperature Gradient (ETG) mode is investigated in a collisionless plasma with Kappa distributed ions. Di erent aspects of the ETG-mode are discussed and noticed that these are modi ed with the superthermality e ect of ions e.g., the phase velocity of the ETG- mode. In the nonlinear regime, we found the ETG mode driven vortex structures, where we noticed that the vortex speed and the amplitude changes with the Kappa value and the ion to electron temperature ratio. Further, the ETG mode is discussed by including the parallel electron dynamics. It is noticed that the parallel motion of electrons stabilizes the ETG instability. Thus the possibility of the formation of nonlinear vortex structures increase. These investigations are discussed both for circular and elliptic type dipolar vortices. In this model an eigen mode dispersion relation is also obtained in the ballooning limit. This relation is also modi ed in the presence of non- Maxwellian ions. Electron AcousticWaves (EAW) are studied with non-Maxwellian hot electrons and stationary/non- stationary ions. In this investigation, both the linear and nonlinear propagation of EAW with stationary and non-stationary ions are discussed. It is noticed that the behavior of EAW is di erent for Kappa distributed hot electrons and Cairn''s distributed hot electrons. Superthermality e ect of electrons and ions on the dust charge uctuations and on the low frequency dust drift/acoustic waves is investigated in an inhomogeneous dusty plasma. It is noticed that this superthermality e ect of ions and electrons reduces the growth rate of the instability due to dust charge uctuations. It is found that dust charge and the superthermalty e ect of ion and electrons reduce the growth rate of instability. In the nonlinear regime, the condition for the existence of dust drift/ acoustic wave driven vortices modi es due to spectral index Kappa. Further, we have investigated the ITG driven solitons and shocks for the electron-ion plasmas for thest time. In this case, it is noticed that the amplitude of the soliton decreases and width of the soliton increases with the increase in ion temperature. In the case of dissipated electron- ion plasmas, the amplitude of the shock increases for with an increase in thei value.