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Home > Synthesis and Characterization of Graphene Oxide Based Metallic Sulfides Nanostructures for Supercapacitor Applications

Synthesis and Characterization of Graphene Oxide Based Metallic Sulfides Nanostructures for Supercapacitor Applications

Thesis Info

Access Option

External Link

Author

Iqbal, Muhammad Faisal

Program

PhD

Institute

University of the Punjab

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2019

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/11082/1/Final%20Ph.D%20Thesis.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727446480

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The limited available energy sources and their improper use require efficient energy storage devices. Therefore, supercapacitors are more attractive due to light weight, low cost and high specific capacitance. Graphene oxide (GO) based metal sulfides have huge potential for electrochemical applications due to large specific surface area and electrical conductivity. In this study, various GO based metal sulfides were hydrothermally synthesized on nickel foam substrate for supercapacitor applications. The structural phases were observed using X-ray diffraction. The surface morphology of aluminum, strontium, nickel and zinc based sulfides exhibited nanowall, nanorod, nanoplate and nanoweb like structures, respectively. The metal sulfides showed good electrochemical performance, which was depicted using both three and two electrodes systems. The specific capacitance and energy density determined using three electrodes galvanostatic charge discharge for GO based sulfides of aluminum, strontium, nickel and zinc were 2373.51, 1824.14, 2368.833, 2400.30 Fg-1 and 118.68, 91.56, 118.44, 120 WhKg-1, respectively. Similarly, the power densities and specific capacitance retention up to 1000 cycles were measured as 2663.58, 4356.64, 1010.00, 4407.73 WKg-1 and 57, 67, 42.20, 95.90 %, respectively. Furthermore, an excellent two electrodes symmetric behavior was revealed for GO based sulfides of aluminum nanowalls, strontium nanorods, nickel nanoplates and zinc nanoweb, because high energy densities 20.55, 10.55, 15.72, 20.29 WhKg-1 and power densities 585.50, 294.35, 848.50, 485.30 WKg-1, respectively, were observed. Hence, the excellent electrochemical behavior exhibited by the fabricated nanostructures suggested supercapacitor applications.
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80. ‘Abasa/looked indifferently

80. ‘Abasa/looked indifferently

I/We begin by the Blessed Name of Allah

The Immensely Merciful to all, The Infinitely Compassionate to everyone.

80:01
a. He contracted his brows - looked indifferently - and turned his face,

80:02
a. when the blind person came to him.

80:03
a. And what made you think that he, being a believer, may ask you and seek to purify himself,

80:04
a. or you would have guided him and he would have heard words of guidance and thus guidance from you would have benefited him.

80:05
a. Now as for the one who showed through his attitude that he had no need of guidance because of his wealth and social status -

80:06
a. and you were attending to him with full attention,

80:07
a. though you will not be answerable if he would not purify himself from disbelief?

80:08
a. But for the blind one who came to you with full of eagerness to learn,

80:09
a. and he was in awe of Allah,

80:10
a. you did not attend to him - you ignored him.

80:11
a. No, do not be so!
b. Indeed, this is a Reminder -

714 Surah 80 * ‘Abasa

80:12
a. So whoever wills, let him pay attention to it - Reminder.

80:13
a. The Qur’an is inscribed in pages of great esteem,

80:14
a. exalted and perfectly purified of any falsehood,

80:15
a. borne by the hands of scriber - angel envoys -

Spontaneous Abortions and Gestational Diabetes Mellitus- A Study from Pakistan

Background: Gestational diabetes mellitus leads to adverse pregnancy outcomes. Objectives: The objective of the study was to explore the relationship of spontaneous abortions with gestational diabetes mellitus in pregnant women from rural and urban Lahore. Methods: This cross-sectional study was conducted at University of Health Sciences, Lahore in 2019. Among 60 pregnant women sampled, 30 had gestational diabetes mellitus (GDM) and 30 were normal pregnant controls. Pregnant women were sampled from different hospitals of rural and urban areas of Lahore. Independent sample t-test was applied for analyzing the data. Chi- square test was used to analyze the categorical variables. Association of fasting blood glucose (FBG) and abortions was checked. Odd ratio and relative risk were calculated. Results: Mean fasting blood sugar levels were significantly higher in GDM group (105 mg/dL) as compared to non-GDM group (80.50 mg/dL) at p<0.001. The proportions of the women with increased number of abortions had significantly higher blood glucose levels (OR 5.091, 95% CI, RR 1.27). Conclusions: Gestational diabetes mellitus is associated with an increased risk of spontaneous abortions.

Export-Led Growth and its Supply Determinants in Pakistan: A Disaggregated Empirical Analysis

This study is an attempt to investigate the export-growth nexus and the impact of supply-side factors on the export performance of Pakistan at a disaggregated level. It has identified major export categories of Pakistan and constructed a novel time series data set of each of these categories from 1971 to 2014. The principal objective of the study is to examine the impact of disaggregated exports on economic growth and determine how much of the variance in economic growth can be explained by various export categories in Pakistan. It allows us to classify exports in terms of their contribution to the long-term economic growth of Pakistan. In addition, the study also discovers the role of prices, cost, production capacity and domestic demand pressure in determining Pakistan’s exports. Using autoregressive distributed lag (ARDL) model, the empirical results show that there is a significant long-term equilibrium relationship between output growth and aggregate, and disaggregated export categories. Moreover, the long-run dynamics indicate that aggregate, manufactured and services exports have significant positive effects on the long-term output growth while primary and semi-manufactured exports showed insignificant effects on non-export GDP in the long-run. However, with further decomposition, the analyses of primary export categories show an individual impact on non-exports GDP which is positive and significant. The long run growth impact of food exports such as rice, fruits, fish and fish preparation is stronger compared to raw materials exports. In addition, the estimation results also indicate that all sub-categories of manufactured exports have a significant positive influence on the non-export GDP in the long-run though with few qualifications. However, the value-added manufactured goods exports have the potential to contribute more to the long-term aggregate output in Pakistan’s case. The results of the Granger causality test based on vector error correction model also confirmed that aggregate, manufactured, and services exports Granger causes the non-export GDP, while no causal link is found from primary and semi-manufactured exports to non-export GDP in both the short- and the long-run. In the case of sub-categories of primary and manufactured exports, the findings showed a causal link from only food items and value-added manufactured exports to non-export GDP in both the short- and the long-run. Similarly, the variance decomposition analysis also confirmed that manufactured and services exports have significant effects on non-export GDP, while shock in primary and semi-manufactured exports are found to be insignificant in explaining variation in non-export GDP. However, when primary and manufactured exports divided into sub-categories, then the shocks in value-added exports and food items exports are found to be significant in explaining movement in non-export GDP. To sum up, the results of all three tests suggest that export-led growth hypothesis cannot be rejected for Pakistan in most cases in both the short- and the long-run. However, the services, food items, and value-added manufactured exports are much more important for the output growth in the case of Pakistan. With respect to the determinants of export supply, the empirical results based on ARDL model show a cointegrating relationship between aggregate exports, disaggregated export categories and other important variables under study. In addition, long-run estimates indicate that aggregate exports are highly elastic to changes in prices and production capacity while inelastic to changes in the cost of production and domestic demand. When aggregate exports are disaggregated into several primary and manufactured export categories, however, major export categories respond differently to changes in various factors of export supply. For instance, the relative prices have a larger impact on the export performance of raw materials and value-added manufactured products. Similarly, the cost of production has higher effects on the growth of value added manufactured and cotton waste exports. On the contrary, production capacity and domestic demand pressures have significantly influenced the export supply almost all manufactured and primary export categories in the long-run. In the short-run, the relative price, cost of production and production capacity showed mixed effects on the export supply of majority primary and manufactured export categories, while the domestic demand pressure hypothesis is valid almost in all cases of primary and manufactured export categories in the short-run. This implies that the export supply almost of all primary and manufactured export categories significantly depends on the domestic demand pressure in the short-run in Pakistan’s case. Apart from this, the study also empirical verified that that domestic demand pressure has a negative and significant effect on export supply at both aggregate and disaggregated levels, implying that along with traditional factors, domestic demand pressures are also relevant for modeling the export supply for Pakistan at both aggregated and disaggregated levels. Finally, the study concludes that export-led growth hypothesis is relevant to Pakistan. However, there are large differences in the effects of exports on non-export GDP across various export categories. Services, food items, and value-added manufactured exports can contribute more to the aggregate output in the long-run in Pakistan’s case. Therefore, it is suggested that Pakistan should pursue the export promotion policy with a greater emphasis on services, food items, and value-added manufactured exports to contribute sufficiently to the economic growth of the country in the long run.In addition, the disaggregated analysis also clarifies that the factors determining the export supply have changed over time and across the various categories of exports.Hence, the government must revisit the export policy and make the new policy in line with new sectoral realities in order to expand the export sector of the country as well as to ensure the economic prosperity of the country on a sustainable basis.