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Home > Synthesis and Characterization of Novel Polyamidoximes, Polyamides, Poly Amide-Imide S and Poly Ester-Amide S and Their Applications for the Removal of Metal Cations from Aqueous Solutions

Synthesis and Characterization of Novel Polyamidoximes, Polyamides, Poly Amide-Imide S and Poly Ester-Amide S and Their Applications for the Removal of Metal Cations from Aqueous Solutions

Thesis Info

Access Option

External Link

Author

Manzar Zahra Awan

Program

PhD

Institute

Quaid-I-Azam University

City

Islamabad

Province

Islamabad.

Country

Pakistan

Thesis Completing Year

2018

Thesis Completion Status

Completed

Subject

Chemistry

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/11290/1/Manzar%20Zahra%20Awan_Chem_2018_QAU_Main%20part.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727457437

Similar


Novel polyamidoximes, poly(amide-imide)s, poly(ester-imide)s along with crosslinked polyamidoximes and polyamides have been reported in this thesis. The foremost goal of the current research endeavor is to design some new adsorbents dealing with adsorption of heavy metal cations, with excellent thermal resistance. The designed monomers (2,6-bis(4-chloroformylphenoxy)benzonitrile, 2,6-bis(4aminophenoxy) benzonitrile, 5-(5-carboxy-1,3-dioxoisoindolin-2-yl) isophthalic acid)bearing pre-formed linkages were synthesized and employed for the novel polymer synthesis.Monomer synthesis was confirmed using FT-IR and NMR spectroscopic analysis while polymer formation confirmed by molecular weight (GPC), XRD and TGA data study. Condensation polymerization was used for the fabrication of polymeric materials. In cross-linked polymers much better crystallinity in addition to boost in thermal resistance was noted. The incorporation of various linkages with more electronegative centers provided polymers with high molecular weights, improved crystalline nature, advanced thermal stability and efficient adsorption capacity. The effect of numerous groups towards adsorption capacity of Cd+2 and Pb+2 was scrutinized following a thorough study of adsorption by batch process. Effects of variable pH, contact time, amount of adsorbent and concentration of adsorbate were deliberately studied with a maximum uptake at pH 6 and 3h of contact time. AAS provided information about the metal ion concentration in the media before and after the adsorption process. The adsorption process was found to be favorable following the Langmuir adsorption isotherm as compared to Freundlich, thus giving an insight to monolayer adsorption over a range of concentration studied. Their ease in formation, high molar mass, heat stability and metal binding ability depict their compliance, rendering them a key material in future polymer science.
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ڈاکٹر عبدالجلیل فریدی

ڈاکٹر عبدالجلیل فریدی
افسوس ہے گذشتہ ماہ ڈاکٹر عبدالجلیل فریدی اکسٹھ برس کی عمر میں ہم سے جُدا ہوگئے۔ مرحوم ایک نہایت بلند مرتبہ اور ماہرِ فن ڈاکٹر کی حیثیت سے ریاست میں ہرجگہ معروف اور مشہور تھے ، لیکن عملی سیاسیات کے میدان میں گامزن ہوئے ابھی انھیں دس بارہ برس ہی ہوئے تھے،اس کے باوجود وہ اس شان اور کروفرکے ساتھ اپنی ریاست کے آسمان ِ سیاست پر نمودار ہوئے کہ پرانے چراغ جھلملا کے رہ گئے۔ ان کی سیاست اگر چہ اتر پردیش تک محدود رہی،لیکن ان کی غیر معمولی شخصیت کاوقار اوروزن پورے ملک کے مسلمانوں میں ہر جگہ محسوس کیا جاتا تھا۔اس کی وجہ یہ ہے کہ مرحوم جذبہ اورعمل دونوں کے انسان تھے، نہایت جری،بے باک اورصاف گوتھے۔ان کی سیاست شترگربگی یامنافقت کے عیب سے پاک وصاف تھی۔اورسب سے بڑھ کریہ کہ سیاست کوجلب منفعت کا ذریعہ بنانے کے بجائے انھوں نے چند در چند مالی نقصانات برداشت کیے اور اپنی کمائی کے لاکھوں روپئے اپنے کازپر بے دریغ خرچ کرڈالے۔اخلاق وعادات کے اعتبارسے بھی وہ بڑی خوبیوں کے مالک تھے ۔عقیدہ اورعمل میں پکے اورسچے مسلمان، ہمدرد ومتواضع، خوش اخلاق وخوش طبع تھے، اس بنا پر مخالفین بھی ان کاادب واحترام کرتے تھے۔ عارضۂ صدر میں مبتلاتھے، روس اور یورپ میں اعلیٰ سے اعلیٰ علاج کرایا مگرمرض نہ گیا۔ایک مرتبہ بڑی حسرت سے بولے : میں نے ڈاکٹر کی حیثیت میں تین لاکھ مریضوں کے ہاتھ دیکھے ہیں،لیکن آج خود اپنا ہاتھ دیکھتا ہوں توحسرت ہوتی ہے ۔آخر یہی مرض جان لیوا ثابت ہوا اوروہ خدا کو پیارے ہوگئے۔ا للّٰھمَّ اغفرلہ وارحمہ۔ [جون ۱۹۷۴ء]

 

Khula Between Family Code Modified by Order 05-02 and Islamic Jurisprudence

Just as a man can resort to divorce when he does not love his wife, the Islamic Law (Sharīa„h) gives the woman the right to end her marriage, if she does not love her husband. However, she will have to repay her the dowry paid to her unless there are circumstances in which a judge could force his husband to pronounce Ṭalaq without compensation from his wife. The Family Code puts an end to an abuse of the rule by judges who demanded the consent of the husband. She asserted that the demand for Khula„ was no longer conditional on the husband's acceptance. As a result, the expression "without the consent of the husband" was introduced in 2005, in Article 54 of the Family Code.

Numerical Simulations, Nonlinear Analysis and Control of Bio-Inspired Flows: A Step Towards Autonomous Vehicles

To propose e cient and better designs for small swimming and ying unmanned vehicles, understanding of the unsteady mechanisms to generate lift and thrust forces at low Reynolds numbers is of key importance. Fluid owing over these vehicles interact nonlinearly with the structure and carries great complexities. Recently, due to interest in biomimicking ying (micro-air vehicles) and swimming robots (underwater vehicles), industry has shown keen interest in production of these vehicles. To design e ective control of these vehicles, thorough understanding of its unsteady aerodynamics and underlying phenomena is required. In this study, we focus upon coupling the numerical simulations with the tools of nonlinear dynamics. We decompose this whole study into two parts; aerodynamics and hydrodynamics. In therst part, we investigate the bifurcations occurring in the ows over oscillating airfoils at low Reynolds numbers. Investigation of mechanism responsible for the generation of unsteady forces pose challenges due to wide spectrum of parameters that are involved in its dynamics. Both experimental and currently available numerical techniques require costly resources in terms of time and money. Considering this fact, we also develop nonlinear reduced-order models for unsteady aerodynamic forces produced by plunging, pitching, and apping airfoils. Observing similarity in the character of unsteady forces generated by pitching, and plunging airfoils, we propose an equivalence criteria to obtain the aerodynamic forces of same magnitude or order. We also demonstrate that de ection of the wake for large Strouhal numbers is a result of strong quadratic nonlinearity. With the lessons learnt from the nonlinear analysis/interaction of apping airfoils, we investigate the hydrodynamics ofsh swimming in the second part of this dissertation. We consider a singlesh and twosh in tandem performing traveling-wave like motion, known as undulation. In case of tandem con guration, we numerically simulate the ow while both sh undulate asynchronously. We quantify the drafting and inverse-drafting e ects using time-averaged drag coe cients. We also explain physical mechanisms which are responsible for hydrodynamic advantage/disadvantage to upstream and downstreamsh. To further enhance our understanding related to the instability mechanisms in the wakes of undulating bodies, we compute the symmetry/asymmetry of parent and combined modes. We apply the symmetry principles, already established for drag-producing wakes of blubodies, to the thrust-producing wakes of undulatingsh. We conclude that thrust producing wakes also follow the same symmetry principles. This research addresses the coupling of techniques/tools of nonlinear mechanics with computational uid dynamics to explore important features of complex ows around oscillating and undualating bodies.