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Synthesis and Fragmentation of Carbon Clusters and Nanotubes

Thesis Info

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Author

Javeed, Sumera

Program

PhD

Institute

Pakistan Institute of Engineering and Applied Sciences

City

Islamabad

Province

Islamabad

Country

Pakistan

Thesis Completing Year

2014

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/2189/1/2753S.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727470943

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A detailed study of the formation and fragmentation patterns of sp2 bonded carbon nano and micro structures has been carried out. Nanotubes and graphite are the extended and composite structures formed by the curved and flat sheets of graphene. Their structural stabilities and subtle differences have shown to be responsible for their characteristic fragmentation patterns under different forms of irradiations. Various techniques were employed for imparting energy to these structures. These include arc discharge, magnetron sputtering, energetic ion induced sputtering, and ablation with electronic and ionic pulses. Emission spectroscopy as well as the velocity and momentum analyzers was employed for the identification of the fragments. Arc discharge and magnetron sputtering of graphite delivered C1, C2, C3 and higher clusters which subsequently coalesced to form two types of thin films. Raman, Fourier transform infra red spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses relates the sp2 character of these two types of films to the relative ratios of C2 versus all these clusters used in their respective formation. C2 is shown to be the essential component of formation as well as fragmentation of the sp2-bonded structures. Detailed mass spectrometric investigations were performed on Cs+ irradiated SWCNTs, MWCNTs and graphite as a function of Cs+ energy (E(Cs+)) ranging from few tens of eV to 5000 eV. C2, C3 and C4 emission are shown to be the main fragmentation channels for irradiated and pristine single and MWCNTs while C1 shows a linearly increasing relative number density as a function of E(Cs+) thus indicating C1 to be the by-product of the dissociation of C2 and C3. Relative stability of C2 and C3 in energetic collisions with N2 demonstrates that C2 and C2+ dissociate at relatively small collision energies as compared with C3 which has superior survival probabilities even at much higher energies. Sputtering of C2, C3 and C1 under broad energy ranges and doses of Cs+ has been modeled to visualize the breaking of multiple bonds in direct and secondary recoils. The prevalence of C2 among the sputtered species from the irradiated SWCNTs, MWCNTs and graphite targets identify the dominant role that recoil sputtering plays, where a double bonded pair of carbon breaks its four single bonds with four C2 neighbors on sp2– bonded surface.
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Chapter 2: Qur’ānic Services of Dr. Isrār Aḥmad

Introduction of Anjuman Khuddām Al-Qur’ān

            Anjuman Khuddām al-Qur’ān was established by Dr. Isrār Aḥmad in March 1972A. D. It was registered in November 1972A. D and Dr. Isrār Aḥmad was declared as lifetime president.[1]

            The Memorandum of the Anjuman has the following contents:

Naḥmaduhū wa Nuṣallī ‘alā Rasūlehil karīm

Bismillāh al- Raḥmān al-Raḥīm

            It is strongly felt that the dream of the renaissance of Islām and the second tenure for supremacy of righteous Dīn cannot be fulfilled without initiating a general movement to invoke faith in Muslim Ummah. To achieve this, it is mandatory that the source of faith and belief, i. e, the doctrine of intellect and wisdom by the Qur’ān should be publicized on a wide scale. Since we are in harmony with the thoughts of Dr. Isrār Aḥmad by overviewing his matchless task performed by him for the last four and half years, we, the few servants of The Divine Book hereby decide to set up “Central Anjuman Khuddām al-Qur’ān” which under the guidance of Dr. Isrār Aḥmad will keep striving the following objectives:

1.         Learning and customization of the Arabic Language.

2.         General persuasion and an invitation to study the Qur’ān.

3.         Transmitting and publishing the Qur’ānic disciplines.

4.         Adequate grooming and training of the youth who can make teaching and learning of the Qur’ān the life-mission, and

5.         Setting up of aQur’ān Academy which may present across philosophy and wisdom of the Qur’ān at the highest academic level.

            May Allāh enable us to achieve these objectives by putting in maximum effort and sacrifice! (Āmīn)

             We are:...

تقارب عقائد کے لئے علمائے اہل سنت کی کاوشیں (ایک تحقیقی و تجزیاتی مطالعہ) The Efforts of Ahl al-Sunnah Scholars for Convergence of Beliefs (An Exploratory and Analytical Study)

There are many beliefs in the sects that are common, while the differences are very small and minor. The differences are usually of a sectarian, ijtihad and preferential nature. But the false powers are using these sectarian differences to spread extremist thinking, which is a poison for the Muslim Ummah. Closeness is essential for the survival of the Muslim faith. This unity should not be temporary but should be a message of intellectual and spiritual, material well-being, spiritual maturity and evolution of mental development and unity should be universal. No matter how much the two groups disagree, there are many commonalities. It is important for convergent beliefs to cultivate commonalities rather than divisive ones. So that the atmosphere of hatred is reduced and an atmosphere of unity is created. The history of Islam bears witness to the fact that the Imams, jurists, narrators and commentators have differed on a number of issues. Despite this difference, love, goodwill, brotherhood and unity prevailed. For such interfaith tolerance and harmony, mutual respect is also necessary. Key words: Convergence of beliefs,  Unity and solidarity,   Interdisciplinary, Shared, Sub-differences, Universal

Modeling and Characterization of Cellular Mobile Channels for 3-D Radio Propagation Environments

In order to meet the increasing demands of capacity in land mobile radio cellular communication systems, the use of directional antennas has become an integral part of future communication systems. With purpose to gauge the capabilities of systems with directional antennas, it is essential to have a precise knowledge of angular and temporal representation of the dispersion of multipath waves in 3-D propagation environments. Such representation of propagating waves can only be achieved with the use of spatial channel models. Therefore, this thesis focuses on modeling and characterization of cellular mobile channels for 3-D radio propagation environments. The research work in this thesis consists of three parts. Part-I aims at the physical modeling of cellular mobile channels in 3-D radio propagation environments. Part- II characterizes the impact of mobility on the Doppler spectrum; while, part-III provides a geometrically based performance analysis of handovers in land mobile radio cellular systems. The thesis begins with an overview of the basics of spatial channel models in different cellular environments and then proceeds towards a detailed and compre- hensive survey of spatial channel models. Further, a generalized 3-D scattering model is proposed for macro-cellular land mobile radio cellular systems with a Mobile Station (MS) located at the center of a 3-D scattering semi-spheroid and a Base Station (BS) employing a directional antenna located outside of the semi- spheroid. The effect of directional antenna is thoroughly observed on spatial and temporal characteristics of the proposed model. Closed-form expressions for joint and marginal Probability Density Functions (PDFs) of Angle of Arrival (AoA) seen at MS and BS in correspondence with azimuth and elevation angles are derived. Furthermore, closed-form expressions for propagation path delays and trivariate joint PDFs of Time of Arrival (ToA) seen at MS and BS in correspondence with azimuth and elevation angles are derived. Moreover, the theoretical results along with observations illustrate the effect of directional antenna on the spatio-temporal statistics of the proposed 3-D spatial model. All the statistics are derived for both uniform and Gaussian scatter densities. The proposed 3-D scattering model for the case of uniform scatter density, is shown to deduce all previously-proposed 2-D and 3-D models that assume uniform distri- bution of scatters with directional or omnidirectional antennas, found in literature for macro-cell environment. The theoretical results obtained are compared with some notable 2-D and 3-D scattering models to validate the generalization of the proposed model. Obtained theoretical results (for the case of Gaussian scatter density) for spatial statistics at BS are compared with an empirical set of mea- sured data (found in literature), which also demonstrates the validity of proposed model. vi In the second part of thesis, the effect of mobile motion on the statistical character- istics of Doppler spectrum is presented. An analytical model to quantify the effect of directivity of the radiated waves from the BS antenna on the Doppler spectrum in 3-D radio propagation environment is proposed. Closed-form expressions for trivariate PDFs of propagation path distance, power, and Doppler shift are de- rived. Furthermore, general expressions for joint and marginal PDFs of elevation AoA, power, and Doppler shift are established. The obtained theoretical results along with the observations are presented that illustrate the effect of directivity of the antenna beam-width and the direction of MS’s motion on the distribution characteristics of power Doppler spectrum. It is established that for motion of the MS in all directions, the spread in distribution of the Doppler shift observed is reduced significantly due to the use of directional antenna at the BS with a nar- row beam directed towards the desired user. It is also observed that, for a sharp azimuthal beam of directional antenna, the multipath components corresponding to the scatterers in elevation plane result in the reduction of Doppler shift with an increase in their vertical distance from MS. In part-III, an analysis for the impact of various channel parameters on the per- formance of handover in mobile radio cellular systems is presented. Using the proposed analytical model, a mathematical relation for the handover margin with velocity of MS, direction of mobile motion, and propagation environment is derived on the basis of path loss propagation model. Relationship for the ratio between the radius of coverage area and the length of overlapped region between adjacent cells is derived, which guarantees to satisfy the required handover margin. The impact of velocity and direction of MS’s motion on the handover margin is com- prehensively analyzed. The impact of propagation environment on the handover margin is also analyzed, where it has been observed that, the handover margin decreases significantly with an increase in the path loss exponent. For dense urban areas with higher propagation path loss exponent, the time margin available to perform the handover is less; therefore, quicker decision of handover is required to be made.