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Home > Synthesis of Titanium Based Nitride Thin Films by Plasma Focus System

Synthesis of Titanium Based Nitride Thin Films by Plasma Focus System

Thesis Info

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Author

Hussain, Tousif

Program

PhD

Institute

Government College University Lahore

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2011

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/handle/123456789/762

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727499295

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The present research is motivated by the remarkable mechanical, thermal and electronic properties of titanium based nitride thin films that have many applications ranging from coatings on cutting tools to diffusion barrier microelectronic applications. This work reports the first successful attempt to grow titanium based nitride thin films, specifically TiAlN, nc- TiN/ a-Si 3 N 4 , nc- (Ti, Al) N/ a-Si 3 N 4 and Ti-Si-N using plasma focus device. The synthesize of these films using different deposition techniques have been reported earlier but the use of plasma focus technique is one of the prospective hybrid deposition method which is not only economical, simple, efficient but also provide high deposition rate and good adhesion SS in less time compared to other available thin film synthesize techniques. The results of these experiments show the successful growth of titanium based nitride thin films using plasma focus device of energy 2.3 kJ. The following four types of different experiments were performed: In the first experiment, the sputtered titanium ions and energetic nitrogen ions emitted from Mather-Type plasma focus device were used to synthesize nanocrystalline TiN/amorphous-Si 3 N 4 thin films. The crystallite size analysis showed strong dependence on the number of focus shots. The crystallinity of TiN thin films wasfound to increase with increasing the number of focus shots. SEM results showed net like structure ofthe film deposited for 15 numbers of shots, which are in the form of elongated grains of Si 3 N 4 embedded in TiN crystals. The average surface roughness calculated from AFM images indicated that the average surface roughness increased for films deposited with increased number of focus shots. In the second experiment, a plasma focus device was used to prepare thin films of nc-(Ti,Al)N/a-Si 3 N 4 at room temperature. The plasma focus device, fitted with copper anode encapsulated with Ti 0.5 Al 0.5 anode, operated with nitrogen as the filling gas was used. Films were deposited with various number of focus shots, at 90 mm from top of the anode and at zero angular position with respect to anode axis. XRD patterns showed the growth of polycrystalline (Ti, Al) N thin films with orientations in the (111), (200), (220) and (311) crystallographic planes. Behavior of lattice constant, grain size and film roughness of xvideposited film as a function of variation in number of focus shots was discussed. SEM micrographs of film deposited with 15 number of focus shots exhibited well-developed net like structure of nc-(Ti,Al)N/a-Si 3 N 4 and possibly nc-(Ti,Al)N/a-Si 3 N 4 /a-AlN or nc-TiN/a- Si 3 N 4 /a-AlN. Surface Roughness ranging 64 nm to 89 nm was also observed. In the third experiment, TiAlN coatings were synthesized by a dense plasma focus deposition system. The effect of focus shots on the crystallography, microstructure, surface morphology, roughness and hardness was investigated. The X-ray diffraction (XRD) data showed TiAlN coatings crystallized in the cubic NaCl B1 structure with orientations in the (111), (200), (220) and (311) crystallographic planes.SEM micrographs showed dense and SS uniformly spread film with fine-grained morphology with hardly any void. Grain size and roughness were found to decrease, whereas thickness and hardness were found to increase, with increasing focus shots. In the fourth and the last experiment, a plasma focus device was used to prepare thin films of Ti-Si-N. XRD patterns showed the growth of polycrystalline TiN thin films. The results revealed that the grain size was correlated to the amount of silicon added. SEM results showed Ti–Si–N film exhibited a denser and amorphous compact structure almost without obvious defects due to addition of Si content in TiN structure. The surface roughness of synthesized thin films was much smoother compared to Plasma focus deposited thin films reported previously, the average surface roughness ranged from 0.23 nm to 9.39 nm.
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المبحث الثالث: ثقافتها

المبحث الثالث: ثقافتها

 تقول نازك الملائکۃ: بأنھا اتجھت اتجاھًا شدیداً مبالغاً إلی دراسۃ الأدب القدیم، وخاصۃ النحو، وأنھا قرأت من کتب النحو ’’شذور الذھب لابن ھشام‘‘[1]، وأیضاً ’’حاشیۃ الشیخ عبادۃ علی شذور الذھب‘‘ وقرأت نازك في حقل الأدب واللغۃ ’’عمدۃ ابن رشیق‘‘[2] والمثل السائر وأدب الکاتب و ’’خزانۃ الأدب للبغدادي‘‘ وقرأت أیضاً، ’’البیان والتبیین‘‘[3] في ثمانیۃ أیام ولم یکن ھذا ھیناً علیھا، فقد کانت أیام محنۃ انتھت بمرض عینیھا حتی اضطرت إلی ترك المطالعۃ وقرأت أیضاً ’’رسالۃ الغفران‘‘[4]۔

 وتحکي نازك عن نفسھا في حیاتھا المدرسیۃ عندما کانت تلمیذۃ في ’’فرع البنات‘‘ وفي تلك الفترۃ ھذا الفرع کان بین العلمي والأدبي فنازک کانت تکرہ الریاضیات والفیزیاء وعلم النبات، وکانت تتمنی أن تتخرج من الثانویۃ وتلتحق بالفرع الأدبي في دار المعلمین العالیۃ، وفي ھذہ الفترۃ کانت تحب دروس اللغۃ العربیۃ، فقد جاء ت في السنۃ الأخیرۃ من الثانویۃ مَدرِّسۃ راعت مواھبھا ومدحت ثقافتھا الواسعۃ، وکانت کثیرۃ النقاش مع والدھا وحفظت الکثیر من الشواھد والأھم من ذلك أنھا کانت توفق بین دراستھا الخارجیۃ والمدرسیۃ۔



[1] ابن ھشام: ابن ھشام الانصاري ھو ابو محمد عبداﷲ جمال الدین بن یوسف بن أحمد بن عبداﷲ بن ھشام الانصاري المصري من أئمۃ النحو العربي

[2] ابن رشیق: ھو ابو علی الحسن بن رشیق المعروف بالقیرواني أحد الأفاضل البلغاء۔ لہ کتب عدۃ منھا، کتاب العمدۃ في معرفۃ صناعۃ الشعر ونقدہ وعیوبہ، وکتاب الأنموذج والرسائل الفائقۃ

[3] البیان والتبیین: البیان والتبیین للجاحظ، وھي موسوعۃ أدبیۃ تمثل ثقافۃ الجاحظ وھو من أصخم مؤلفات الجاحظ۔

[4] رسالۃ الغفران عمل...

دور جدید میں کرائے کی ماں (Surrogate Mothering) کا تصور اور اسلامی نقطہ نظر

Artificial insemination is a means of attaining pregnancy not involving sexual intercourse. A couple having trouble getting pregnant can benefit from the exact timing and placement of the sperm. It can overcome instances where a woman's immune system can reject her partner's sperm as invading molecules. In the case of an impotent male, donor sperm may be used. It is also a means for a woman to conceive when two women wish to parent a child, or a single woman does not have a male partner, when she does not want a male partner, or when a male partner's physical limitation impedes his ability to impregnate her by sexual intercourse. A relationship in which one woman bears and gives birth to a child for a person or a couple who then adopts or takes legal custody of the child; called Surrogate Motherhood. In surrogate motherhood, one woman acts as a surrogate, or replacement, mother for another woman, sometimes called the intended mother, who either cannot produce fertile eggs or cannot carry a pregnancy through to birth, or term. Surrogate mothering phenomena is prevailing all over the world now days especially in America and European countries. The first recognized surrogate mother arrangement was made in 1976. Surrogate mothering is also introducing in Islam in some extend but Islam has its own laws regarding each and every problem of life. This Article is a summary of all positive and negative aspects of said issue and a critical analysis of its implications according to the Islamic injunctions in modern era.

Synthesis and Characterization of Nanocomposites As Slow Release Environment Friendly Fertilizers

Agriculture is the back bone of economic development of any agricultural country and it has been transformed into a vast industry fulfilling the primary needs of the masses. Sustainability in agriculture sector is a serious concern specifically in the perspective of environmental conservation as well as maintaining rather improving the crop productivity. This research work was designed to prepare environmentally friendly slow release nano-fertilizer as a substitute for conventional chemical fertilizers that could protect the environment from deleterious effects of conventional chemical fertilizers without compromising agricultural productivity. Two types of nano-composites, based on zeolite (ZNC) and biochar (BNC), with a particle size of 6.05 and 55.6nm, were synthesized by adopting two-step approach and compared with conventional chemical fertilizers. In the first step support materials i.e. nano zeolite (NZ) and biochar of corncob (CB) were synthesized and in the second step support materials were impregnated/ doped with micro and macro nutrients. Physiochemical properties of both the support materials (NZ & CB) and their nanocomposites (ZNC & BNC) were determined using standard methods. While the structure, morphological features, chemical composition, size and thermal stability were determined by fourier transmission infrared spectroscopy (FT-IR), powder x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDX), atomic force microscopy (AFM) and thermogravimetric analysis (TGA). Slow release properties of ZNC & BNC carried out in water as well as in soil for 7 and 14 days, respectively, that confirmed the gradual release and long time availability of all the doped nutrients (N, P, K, Ca, Mg, Fe, Zn). Concurrently, the synthesized nano-composites showed excellent water absorbance, salt index and water retention capacities that is good to enhance the soil condition without imparting negative impacts to the crops. The nano-composites’ capability to enhance crop production in comparison to conventional fertilizers was accessed primarily by performing greenhouse experiments on wheat – a major cash crop of Pakistan that is widely grown and serving the purpose of staple food in Pakistan. The completely randomized design with five treatments (control, urea, NPK, ZNC and BNC) was laid ii down, to study the germination parameters; time for 50% germination (T50), mean germination time (days), final germination percentage (%) and germination index. The results indicated early sprouting and germination in ZNC followed by BNC than conventional fertilizers (i.e. urea and NPK). After positive germination results of greenhouse experiment, the field trials were carried on using the same approach i.e. RCBD with three replicates of each treatment to examine the effect of nano-composites on growth and yield parameters for two consecutive years (2014 - 2016). The results were statistically analyzed using one- way ANOVA (LSD at 0.5%) and means were separated by standard errors. The results of field trials demonstrated that nano-composites (ZNC & BNC) positively influenced growth and yield of wheat crop as compared to conventional fertilizers (urea and NPK) and control. In the first year, the highest grain yield was found for ZNC followed by BNC, NPK, urea and lowest for control treatment. While in the second year the scenario was slightly changed and the highest yield was observed in BNC followed by ZNC; the rest of the pattern is same as previous i.e. NPK > urea >control. The proximate, antioxidant and nutritional analysis of wheat grain were performed to determine the comparative effect of nano-composites (ZNC & BNC) with conventional fertilizers. The results demonstrated that nano-composites had marked influence on nutritional quality, antioxidant activity and proximate analysis of wheat grain as compared to urea and NPK. Similarly, comparison of pre and post-cropharvest analysis of soil confirmed that use of nano-composites improve the quality of the soil. Finally, the viability of these nano-composites was quantified through economic analysis for the feasibility of this new approach in field application. The results showed that nano-composites significantly enhanced the gross benefit as compared to conventional fertilizers. Hence, it can be safely concluded that use of these nanocomposites will not only protect the environment but also enhance the yield, nutritional quality of crops and income of farmers by reducing the fertilizer input cost thereby ensuring sustainable agriculture development.