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Home > Synthesis, Spectroscopic and Biological Studies of 3D Transition Metal Complexes With Various Aniline Based Schiff Bases

Synthesis, Spectroscopic and Biological Studies of 3D Transition Metal Complexes With Various Aniline Based Schiff Bases

Thesis Info

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Author

Hussain, Habib

Program

PhD

Institute

University of Engineering and Technology

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2015

Thesis Completion Status

Completed

Subject

Chemistry

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/10005/1/Habib_Hussain_Chemistry_2015_UET_Lahore_31.05.2016.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727526517

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A variety of Schiff bases and their metal complexes have been synthesized from 3 – acetyl – 2 H – chromen – 2 - one and anils. 2-hydroxybenzaldehyde was reacted with ethyl acetoacetate (acacs) in the presence of piperidine to give 3 – acetyl – 2 H - chromen – 2 - one which was further reacted with different anils namely p-toluidine, p-chloroaniline and 2-nitroanilie to obtain Schiff bases. These Schiff bases were used as ligands in the current study. Schiff base metal complexes were then synthesized by reacting Schiff base ligands with 3d-transition metals nickel( II), cobalt( II), copper( II) and zinc( II). Both ligands and metal complexes were then characterized by various spectroscopic techniques which include UV-visible spectroscopy, 1H NMR, 13C NMR spectroscopy and powder X-ray diffraction (PXRD). Stability of complexes was estimated in solid and solutions form. Amounts of metals in complexes and metals’ to ligands ratios were estimated by Atomic Absorption Spectroscopy (AAS). These metal complexes were found diamagnetic by vibrating sample magnetometry. Schiff base complexes were found to have immense applications in biological fields. So all Schiff base ligands and their metal complexes were scanned against gram positive and gram negative bacterial strains and it was found that they show promising activities against selected bacterial strains.
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7 ۔حدِارتداد

ردد کامعنی ہے کسی شےکالوٹنا ، مسلمان کا کفر کی طرف لوٹ جانا۔ اس حوالے سے ابن فارس لکھتے ہیں
الراء والدال أصلٌ واحدٌ مطّردٌ منقاس، وهو رَجْع الشَّيء. تقول: ردَدْتُ الشَّيءَ أرُدُّه ردّاً. وسمِّي المرتدُّ لأنّه ردّ نفسَه إلى كُفْره.143
"مادہ " رَدَدَ " ہے اور اس معنی ہے کسی شے کا لوٹنا جیسے تو کہے ردَدْتُ الشَّيءَ أرُدُّه ردّاً میں نے فلان چیز کو لوٹا دیا اور مرتد کو مرتد اس لیے کہتے ہیں کہ وہ اپنے آپ کو کفر کی طرف لوٹا دیتا ہے ۔ "
اسلام سے پھر جانے کوارتداد کہتے ہیں، جیسا کہ ابن منظور کے نزدیک ارتداد
"وفي التنزيل من يرتدد منكم عن دينه والاسم الرِّدّة ومنه الردَّة عن الإِسلام أَي الرجوع عنه وارتدَّ فلان عن دينه إِذا كفر بعد إِسلامه۔"144
"اور قرآن مجید میں ہےمن يرتدد منكم عن دينه۔ ۔ ۔ الیٰ آ خرہ ۔ اور اسی سے ہے الردۃ عن الاسلام یعنی اسلام سے پھر جانا جیسے کہا جاتا ہے فلاں شخص مرتد ہو گیا جب کہ وہ اسلام سے کفر کی طرف پھر جائے ۔ "
ارتداد کے معنی اسلام قبول کر لینے کے بعد اسلام کو چھوڑ دینے اور اس کے خلاف بغاوت کرنے کے ہیں، جیسے امام راغب اصفہانی نے ارتداد سے متعلق تحریر کیا ہے
"والردۃ الرجوع فی الطریق الزی جاء منہ لکن الردۃتختص بالکفر والارتداد یستعمل فیہ وفی غیرہ۔" 145
"اس راستے پر پلٹنے کو کہتے ہیں جس سے کوئی آیا ہو لیکن ردۃ کا لفظ کفر کی طرف ہی لوٹنا خاص ہے اور ارتداد عام ہے جو حالت کفر اور غیر دونوں کی طرف لوٹنے پر بولا جاتا ہے۔ "
اصطلاحی مفہوم :علاؤالدین کاسانی ؒ شرعی اصطلاح میں ارتداد کے بارے میں لکھتے ہیں
"فَالرُّجُوعُ عن الْإِيمَانِ يُسَمَّى رِدَّةً في عُرْفِ الشَّرْعِ۔ "146
"پس ایمان سے پلٹ جانے کو...

Fazle Haq Khayrabadi: An Extraordinary Personality

This is an account of the life and works of Fazle Haq Khayrabadi, a great but forgotten Indian Muslim religious scholar and thinker of the 19th century is presented. Coming from a family of great distinction, Fazle Haq Khayrabadi was an author, poet and philosopher who expressed himself in Arabic, Persian and Urdu. Especially relevant is the dedication and fervor with which Khayrabadi participated in all stages of the First Indian War of Independence of 1857 [also termed the Great Mutiny], for which he was exiled to the Andaman Islands by the British rulers of India, where he died in 1862. The remarkable personality of Fazle Haq Khayrabadi [17871862] has been forgotten by an ungrateful nation that does not honour its heroes but instead buries them under the debris of history. A great scholar, familiar with the diverse disciplines in the Islamic sciences, and the Imam of the Khayrabadi school of logic and philosophy, he, also a son the great Fazle Imam Khayrabadi, distinguished himself early for his intellectual prowess and strength of genius. Amazingly, such a scholar, devoted to academics, was also a fighter and participant in the War of Independence of 1857, and a member of the revolutionary council that directed its strategy. For this, he suffered imprisonment at the hands of the vengeful British, who sentenced him to hard labour in the distant Andaman Islands – where he died ‘across the black water’.

Photonic Generation of Width Tunable Uwb Pulses

Ultra-wideband (UWB) is a cutting edge, short range and huge bit rate wireless communication technique which provides communication services at Gbps data rates per user. The developing attraction for UWB is primarily due to its various interesting characteristics, such as reduced power emission, resilience to fading, little probability of interception, conformance with other wireless technologies and potential of supporting cost-efficient Gbps transmission to user ends. Owing to low power spectral density (PSD), the transmission distance is restricted from few meters to tens of meters. UWB over fiber (UWBoF) is a recent technique used to extend the range of UWB wireless transmission and also integrates the UWB services with fixed wired or wireless communication networks. Generally, this dissertation proposes various simple, efficient and novel all-optical techniques of UWB signal generation and transmission over single mode fiber (SMF), multimode fiber (MMF) and free space optics (FSO) link in order to effectively utilize the imposed Federal Communication Commission (FCC) mask. The proposed schemes are cost efficient and promising the seamless delivery of high data rate signals to user ends. In addition to UWB signal generation, a novel all-optical 2R (re-shaping and re-amplification) regeneration and continuous wave (CW) to pulsed signal wavelength conversion scheme is also presented which can be used to extend the range of UWBoF access network apart from its core function of optical signal re-shaping and reamplification. In particular, all-optical regenerative technique of width tunable UWB signal generation operating at 5 Gbps has been proposed and simulated where UWB mono-cycle pulses are generated by employing the nonlinearity of highly nonlinear fiber (HNLF) and semiconductor optical amplifier (SOA) based nonlinear mediums. Width tuning of generated UWB mono-cycle pulses is achieved with all-optical means. The regeneraix tive property of the proposed technique is verified by comparing with optical delay line (ODL) based UWB signal generation scheme. A simple and cost efficient scheme of UWB signal generation in optical domain has been proposed where UWB mono-cycle pulses are generated by exercising the nonlinearity between two linearly polarized (LP) modes in a SOA. The proposed bi-directional architecture promises the delivery of 2 Gbps data over MMF for down-link (DL) and up-link (UL) transmissions. Cost efficiency is achieved by employing direct modulation and carrier re-use techniques. This dissertation also explores the possibility of all-optical generation and transmission of UWB signals over FSO link. Therefore, a cost efficient architecture for generation and transmission of multiple UWB signals using all-optical technique over FSO link has also been presented based on Gamma-Gamma (GG) channel model which is employed between central unit (CU) and remotely distributed multiple radio access units (RAUs). The cost efficiency with added advantage of data transmission at higher data rates have been achieved by reducing the deployment cost by using FSO link instead of optical fiber and generating multiple coherent optical carriers by direct modulation of a single CW laser for data transmission. Finally, a novel all-optical 2R regenerator and CW to pulsed signal wavelength converter operating at 10 Gbps has been proposed which performs re-shaping and reamplification functions as well as wavelength conversion by inducing nonlinear chirp over CW probe by data modulated optical pulsed signal in HNLF and offset filtering. After inclusion of this 2R regenerator, the range of UWBoF access network can be extended beyond 40 km.