جج پر ضمان: فقہی قواعد اور پاکستانی قانون میں تطبیق

A judge should be honest,  transparent, free and fair. He should always respect law. The question arises that if a judge who disrespects law and makes unbalanced decisions: as a result of which people get affected then will he or she be penalized? The Ḥanafi Scholars opine that if a judge passes a wrong decision intentionally, he should be penalized from his own property. Because in Islamic jurisprudence, judiciary owns a supremacy over the masses and everyone irrespective of the position is equal and has to obey law. Whether he is a judge or a commoner, he has to follow the rules and regulations as prescribed by law. In practice, Pakistani judges are not held responsible for making a wrong verdict. Our judges make judgments on the basis of already manipulated evidence. A judge bars himself from the responsibility of collecting evidence. Similarly, if a judge has developed personal grudges with the criminal then the criminal reserves right of appealing the higher court where the decision is reviewed and rectified. In such situation, there is a compulsion between the legal maxim "وَالْأَصْلُ عَدَمُ الضَّمَان" and the Pakistani laws. However, Ḥanafi jurisprudence and Pakistani Laws are not in accordance with each other. This study concentrates upon the nature of punishment and tort to be applied on judges in case of making a decision based on falsehood. It is suggested that Pakistan’s Judiciary should be reread as that the already in-practice system does not comply with the standards of Islamic teachings.

Synthesis, Electrochemical and Flourescent Studies of Metal Complexes and Nanomaterials

The research work has been divided into three parts, Part I, Part II, and Part III. Part I A Series of di-and tri-organotin(IV) complexes (23) have been synthesized by the reaction of tri- and diorganotin(IV) chlorides/oxides with 3(3-Indolyl)-propionic acid and 4,5-diphenyl 2-imidazole thiol ligand in dry toluene under reflux condition for 6-8 hrs. The coordination behaviour of ligands and geometry of synthesized complexes were studied by employing different analytical techniques such as FTIR, multinuclear NMR (1H, 13C, 119Sn). Based on these results, the ligand appeared to coordinate the Sn atom via COO- & -SH moiety. The triorganotin(IV) derivatives reveal a monomeric tetrahedral structure in solution. While diorganotin(IV) dicarboxylates have shown an octahedral geometry, however, the coordination around Sn change from six to five in solution, in most cases. The appearance of new peaks for Sn-O and Sn-S in the IR spectra indicated the formation of organotin(IV) carboxylates and values point to the bidentate nature of ligands in solid state. Multinuclear NMR (1H, 13C and 119Sn) data revealed that the coordination number of Sn changed from five to four in triorganotin (IV) derivatives and from six to five in diorganotin(IV) compounds. Part II For the first time, we have studied Electrogenerated chemiluminescence of Ru(phen)32+ /Dibutylamino)ethanol system. ECL of Ru(phen)32+ /DBAE was compared with ECL of Ru(bpy)32+ /DBAE at both Au and GC electrodes. ECL intensities of Ru(phen)32+ /DBAE were found several times of ECL of Ru(bpy)32+ /DBAE. In addition, Ru(phen)32+ is sensitively detected using very low concentration of DBAE. ECL behavior of Ru(bpy)32+ /DBAE and Ru(phen)32+ /DBAE was vigilantly studied under cyclic voltametry and amperometry conditions at Au and GC electrode.Therefore, Ru(phen)32+ / DBAE system is promising for the sensitive detection of biologically important compounds. Part III We have presented a new, easy and environment friendly method for the facile aqueous preparation of silver nanoparticles well defined in size and shape by exploiting EG as mild reductant. No additives, such as surfactant is needed in the procedure. The size and shape of the silver nanoparticles are sensitive to the reactant temperatures and the concentration of the precursor. A denser concentration of precursor facilitates the formation of large and highly crystalline nano-Ag particles. The other metal nanoparticles, such as gold, can be successfully fabricated as well by this technique. It is important to note that the reducing reactivity of EG was rapidly increased with the increase in reaction time, concentration of the precursor and temperature, which offers the possibility of preparation of metal nanoparticles with a shift of particle size range from ca. 10 to 30 nm. In addition, Quantum dots (QDs) are reported as promising fluorescent probes for biomedical imaging. We have tried to fabricate CdTe QDs using SFSD as reducing agent under isothermal method.