88. Al-Ghashiyah/The Overpowering Event
I/We begin by the Blessed Name of Allah
The Immensely Merciful to all, The Infinitely Compassionate to everyone.
88:01
a. Has the news of coming of the Overpowering Event reached you?
88:02
a. It will be the Time when some faces will be downcast with fear and shame -
88:03
a. having labored in the world only to weariness - with no payback in the Hereafter.
88:04
a. They will enter the Blazing Fire.
88:05
a. They will be made to drink from a boiling spring of extremely high temperatures.
88:06
a. They will have no food other than bitter dry thorns/cactus -
88:07
a. neither nourishing them nor appeasing their hunger.
88:08
a. While, at the same Time, some faces will be blessed,
88:09
a. pleased with their striving for righteousness during the worldly life,
88:10
a. dwelling in Paradise on high,
88:11
a. wherein they shall never hear any absurdity or frivolous talk,
88:12
a. therein will be flowing spring of fresh sweet water,
732 Surah 88 * Al-Ghashiyah
88:13
a. and couches raised high,
88:14
a. and cups set in place,
88:15
a. and cushions lined up behind them,
88:16
a. and rich carpets spread out beneath them.
88:17
a. Will they - who deny the Resurrection - not observe how the camels are created,
88:18
a. and the celestial realm -
b. how it was formed and raised...
Juristic rules laid the foundation of law, along with such juristic rules, Islām promotes the values of piety (through mystic guidelines). Most of the theologians opine that the real approach to get close the Creator can only be achieved through the mystic guidelines. In the early period of Islām, during the time of the prophet, , caliphate guided rightly the of periods the during and (صلى الله عليه وسلم) Muhammad when people were trained in a very righteous environment, there were no such reservations about the applications of clear jurisprudential injunctions along with the mystic guidelines, but, when Muslims tasted the grandeur of rule, regime and abundance of wealth, they indulged in the worldly affairs and adopted a materialistic approach, not only in their daily life, but, toward their religion, too. The Muslim thinkers have been trying to define and explain whether the typical rituals of mysticism are reconcilable with the larger demands of an Islamic vocabulary. Despite the wide diversity of the critical approaches, a certain pattern has been identified by Muslim responses as mysticism, which is, sometimes found closer to asceticism and sometime as a mediator. Many Muslim mystics have dealt with mysticism, but, perhaps, Manāẓir Aḥsan Gīlānī has displayed, with reference to Ibn ‘Arabī and Shāh Walī Ullāh, the most impressive and knowledgeable applications of such mystic ideas within an Islamic framework. Manāẓir’s applied mysticism is not a typical mysticism; his special focus upon legal injunctions of al-Sharī‘ah goes much further than any of his peers in establishing a strong framework for better understanding of Islām. This study is devoted to examining the effects and implications of mysticism, not only for individuals, but also for the Muslim masses, generally.
Enhanced effectiveness of pharmaceuticals and agrochemicals is the most sought-after attribute in the field of enantioselective synthesis of chiral molecules where single enantiomer (R or S) is required, for which asymmetric catalysis is an attractive way. The synthesis of enantiomerically pure compounds in traditional way is difficult, costly and time-consuming process involving the running of long columns which create a lot of waste that causes water pollution. The selectivity of products are equally depends upon the catalyst and conditions of the reaction which makes the task harder for selecting and finding new catalytic system. Present work deals with the development of six families of chiral ligands libraries for rapid recognition of the best system, by using combinatorial chemistry, during hydrogenation of ketones, a starting material and as intermediate in a number of pharmaceutical processes. The ligands were both generated in situ and in pure form for the comparison of results and were obtained by simple condensation, providing one of the starting materials being chiral. Six families namely; bisimine, diamine, aminal, imine, iminophosphine and oxazoline were synthesized and tested in presence of Zn(II), Rh(I) and Rh(III) by using polymethylhydrosiloxane (PMHS), diphenylsilane and formic acid/sodium formate as hydrogen donor species for transfer hydrogenation during synthesis of selective chiral alcohols from achiral acetophenone. Overall 1566 catalytic systems were developed and subsequently tested and the yield and enantiomeric excesses were found by using 1H NMR and chiral High Performance Liquid Chromatography (HPLC) respectively with more than 90% ee and 99% conversion as the best result for imine and aminal ligands. It has been proven that ligands synthesized in-situ gave comparable and almost same results to purified version with best reproducibility.