حزیں حرف گر (۳)
اے آدم گر!
میں تیرے وصل کی خواہش کا مارا ہوا
ازل سے کاندھوں پہ روشنی کا بوجھ اٹھائے
جو کبھی میرے سامنے جھکی تھی
اب میرے ہر عمل کی گواہ ہے
میں سوچتا ہوں
وصل کیسے ممکن ہو
ہمارے درمیان ایک آتشیں دیوار ہے
وہ آگ جو مانندِ خوں مجھ میں رواں ہے
لمحہ بھر بھی اپنے کارِ...
The patience is the noblest virtue and lays great stress on being patient. Islamic History is full of the examples from the lives of Ṣaḥabah who sacrificed a lot. Islam delineates all the divers and broader aspects of patience in all its form. The need is to follow all these noble personalities called Ṣaḥabah in our lives in this era in order to show tolerance and give respect to others. The Prophetic era is considered as the golden period wherein great students were trained to teach humanity, courage and determination. Although, having low status in society they taught the world how to lead a purposeful life with good morals and distinctive principles. They were the men rightly guided with high and far-seeing vision of the Prophet (r). They were the oceans of knowledge, instilled with spirit of service, thus stood as the exemplary icons of practical life. They chose indigent and destitute life but never extended their hands for help for their highly esteemed self-reliance. Those were men of field who never got afraid of anything in their life. They faced all the challenges with faith and patience, and with the spirit of Jihad, they crushed the infidels and uprooted infidelity from Arabian Peninsula. Owing to their strong faith, they passed through many wild, menacing and brutal stages but never tilted towards the worldly things or people, nor did they compromised on their firm belief and clear stance cultivated by the Holly Prophet (r). This was the reason they got the title weak those about is article This. Allah Almighty from (رضي الله عنهم) of companions of the Prophet (r) who were icons of Patience and determination. Their patience is un-exemplary. They were gifted with excellent qualities of forbearance.
In this thesis, we studied the structural and magnetic properties of uncoated and coateded ferrite nanoparticles (NPs). Cobalt ferrite (CoFe2O4), maghemite (γ-Fe2O3) and manganese ferrite (MnFe2O4) NPs were preferred due to their potential use in wide range of applications including magnetic fluids, catalysis, biotechnology/biomedicine, magnetic resonance imaging, magneto optical devices, data storage, and environmental remediation. To avoid agglomeration and interparticle interactions and study surface effects in these ferrite NPs, different coating materials such as SiO2 (non-magnetic), Co3O4 (antiferromagnetic) and ZrO2 (non-magnetic) were used. The nature of surface coated material can influence the surface magnetization and modify the interparticle interactions. Initially, SiO2 coated and uncoated CoFe2O4 NPs were prepared by using solgel method. X-ray diffraction (XRD) technique revealed the spinel structure of CoFe2O4 NPs. The average crystallite size was found to be 34 and 25 nm for uncoated and 60 % SiO2 coated CoFe2O4 NPs, respectively. The SiO2 remains amorphous at annealing temperature of 900oC. TEM micrographs revealed spherical NPs with less agglomeration. Surface effects were studied by using AC and DC magnetic measurements. Dynamic scaling law fitting on frequency dependent average blocking temperature (TB) of uncoated CoFe2O4 NPs showed weak spin glass behavior with critical exponent value zv = 4. SiO2 coated CoFe2O4 NPs showed two peaks: blocking at high temperature and freezing at low temperature in imaginary part of frequency dependent AC-susceptibility. The dynamic scaling law fitting on frequency dependent freezing peak in coated NPs showed strong spin-glass state with critical exponent zv = 7 due to stiffed frozen surface spins. However, the blocking peak did not follow the thermal activation. DC field in AC-susceptibility shifted the blocking peak and broadened the freezing peak which also confirmed the existence of spin glass in SiO2 coated CoFe2O4 NPs. We have also prepared CoFe2O4 NPs with ZrO2 and TiO2 coating materials and compared their saturation magnetization (MS) values. M-H loops of SiO2, ZrO2 and TiO2 coated CoFe2O4 NPs revealed that ZrO2 coating reduced more magnetization than SiO2, and TiO2 coating materials. ere studied. XRD confirmed the spinel structure of γ-Fe2O3 NPs with phase of ZrO2. Simulated zero field cooled and field cooled (ZFC/FC) curves gave larger Keff = 1.5 ± 1 x 105 erg/cm3 than Kbulk due to enhanced surface effects by ZrO2 coating. Temperature dependent MS was examined by Bloch‘s law. Bloch‘s constant (B) = 2x10-01 K-b for ZrO2 coated γ-Fe2O3 NPs was higher as compared to SiO2 coating due to weak exchange coupling. Coercivity (HC) of SiO2 and ZrO2 coated γ-Fe2O3 NPs showed increasing trend as decrease in temperature due to enhanced surface anisotropy. Uncoated and SiO2 coated γ-Fe2O3 NPs showed slow spin relaxation due to stronger surface disorders as investigated by stretched exponential law. However, ZrO2 coated γ-Fe2O3 NPs showed weak interactions among NPs and reduced surface effects which were examined by frequency dependent AC-susceptibility data. Finally, surface effects in ZrO2 and Co3O4 coated MnFe2O4 NPs were studied. Simulated ZFC/FC measurement showed larger Keff value of Co3O4 coated MnFe2O4 NPs as compared to ZrO2 coated due to strong coupling between ferrimagnetic (FiM) core and antiferromagnetic (AFM) surface. Bloch‘s law fit showed higher value of B = 0.06 K-b for ZrO2 coating due to decreased in exchange coupling caused by ZrO2 coating. DC field and frequency dependent AC-susceptibility data were analyzed by using Arrhenius, Vogel-Fulcher and dynamic scaling laws for these NPs. Co3O4 coated NPs showed a strong spin glass behavior while ZrO2 coating reduced the interactions between NPs as obtained to ZrO2 coated γ-Fe2O3 NPs. In summary, ZrO2 coating reduced the interparticle interactions between MnFe2O4 and γ-Fe2O3 NPs and also reduced surface effects. However, SiO2 and Co3O4 coating enhanced surface spin disorder and interparticle interactions. Different types of coating can tune the magnetic properties of these ferrite NPs tremendously which make them useful for different applications such as for data storage, hyperthermia cancer treatment, microwave absorber etc.