ان سب رگوں سے پھوٹتے جنوں کا مسئلہ
لاحق ہمیں ہے ہر گھڑی سکوں کا مسئلہ
اب لاؤ کوئی پیر میرا سینہ دم کرو
ٹلتا نہیں ہے ہجر کے فسوں کا مسئلہ
دن ہو بھلے سے عید کا ہمیں خوشی نہیں
اب لا دوا سا ہے دلِ زبوں کا مسئلہ
اپنے بھی اب تو خیر سے اپنے ہیںکب رہے
یوں بڑھ گیا ہے یہ سفید خوں کا مسئلہ
چھینا ہے تیری ضد نے مجھ سے اُس کو اے خدا
معلوم تھا جسے مرے ’’لوںلوں‘‘ کا مسئلہ
Different scholars have compiled the books which contain a large numbers of authentic Ahadith (Ahadith Sahiha), to achieve this purpose, they introduced different hadith sciences to distinguish between the true and the fabricated hadith. The authentic Sunnah is contained within the vast body of Hadith literature. One of them is Imam Zia ul Maqdasi. Imam Zia Uddin Muhammad bin Abdul Wahid Maqdasi’s book “Al Ahadith al Makhtara” is one of the best books of its kind. Many Islamic scholars have declared it better than Imam Hakim’s book Al Mustadrak. Allama Iraqi, one of his contemporaries said that the Ahadith given in his book Al Ahadith al Makhtara were not ascertained to be authentic before. Only those Ahadith have been given in this book whose asaneed are correct but they have not been reported by Imam Bukhari and Imam Muslim. Also, one of the strengths of this book is that it reflects the glimpses of Muajam. Imam Maqdasi wrote this book in the manner of Masaneed that is to say that he mentioned the name of the companion of the Holy Prophet (SAW) and then reported his traditions. Sometimes he also indicates the factors responsible for the interruption in the authenticity of Ahadith. But, sadly, Imam Maqdasi passed away and could not complete this great book. In this article I will discuss the Imam Zia ul Maqdasi approach towards “Ahadith Sahiha” in his book Al Ahadith ul Mukhtara.
Several 5-arylfuran-2-carbaldehydes were prepared from furfural by a Meerwein arylation. These were then reacted with a few arylhydrazides to provide respective arylhydrazones which acted as the starting ligands. On reaction with copper, nickel and cobalt (d block elements) salts provided corresponding metal complexes. (Scheme). NH2 R + O CHO R O CHO O CH R N NH O C R'' H2N NH C O R'' (Hydrazide) M= Cu(II), Ni(II), Co(II) O C N H N C R'' O M O C N H N C R'' O R R M O C N H N C R'' O R Cl (A) (B) O N C H N C O M O (C) R (Hydrazone) (5-arylfuran-2-carbaldehydes ) Both the conventional heating and microwave irradiation were employed for the formation of the hydrazides, hydrazones and the metal complexes. Microwave methods were time and yield efficient and presented as eco-friendly, neater and higher yields processes as viii compared to the conventional methods. All the new compounds were characterized through their elemental analyses and spectra (FTIR, 1H NMR, 13C NMR and EIMS). The metal complexes were further analyzed for their metal contents (ICP-OES) and chloride ions (Metrohm potentiometric autotitrator). Mass spectral fragmentation of the hydrazone ligands was also suggested. Further studies showed that the complexes formed in the ligand to metal ratios were 2:1 and 1:1 which helped identify them as Octahedron (A), Tetrahedron (B) and Square planar (C) in their geometry. Chloride ions when present are perhaps in the bridging position in the complexes. Biological screening of the ligands as well as their complexes was carried out to test for their antibacterial (three Gram Positive (Staphylococcus aureus, Bacillus subtilis and Actinobaculumschaalii) and six Gram Negative (Pseudomonas aerugenosa, Escherichia coli, Salmonella typhimurium, Bordetellabronchiseptica, Shigella and Salmonella) bacterial strains were tested) and antioxidant activity (three: in vitro methods used DPPH method, NO method and Phosphomolybdenum method). These products did not show any pronounced activities however.