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Efg and Magnetic Studies of Actinide-Post Transition Metals

Thesis Info

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Author

Khan, Sajid

Program

PhD

Institute

University of Malakand

City

Malakand

Province

KPK

Country

Pakistan

Thesis Completing Year

2018

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/11165/1/Sajid%20Khan_Phy_2018_Malakand_PRR.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676726041137

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In this thesis, we explore the structural and magnetic properties as well as electric field gradient (EFG), hyperfine field (HFF) and quadrupole coupling constant in actinide digallides AcGa2 (Ac=U, Np, Pu), NpPx3 (Px =Al, In, Ga) and UX3 (X =In, Tl, Pb) by using local density approximation (LDA), generalized gradient approximation (GGA) with onsite Hubbard potentials LDA+U and GGA+U and Hybrid Wu-Cohen GGA (HF-WC). The hexagonal AB2 type AcGa2 and cubic AuCu3 type NpPx3 as well as UX3 compounds are optimized. The lattice constants, bulk moduli, optimized volumes and ground state energies of these compounds are evaluated from the optimized structures. Our results show that the calculated values of these structural parameters are consistent with the available experimental results. The magnetic structures of the materials under study are investigated by calculating the ferromagnetic, antiferromagnetic and non magnetic phase energies. The UGa2, NpGa2 and NpPx3 have lowest energies in ferromagnetic phase while PuGa2 and UX3 prefer in antiferromagnetic phase, which is in agreement with the experimental results. Due to the 5f- electronic states in these compounds spin orbit coupling (SOC) effect has been considered to include. The spin, orbital and total magnetic moment at U, Np and Pu sites have been calculated computationally with the presence and absence of SOC. Our calculated magnetic moments at uranium, neptunium and plutonium sites are consistent with the experimental values. The orbital, dipolar, Fermi contact as well as total hyperfine and its origin in actinide as well as post transition atomic sites have been investigated for the first time in these compounds. The EFG and quadrupole coupling constant of uranium, neptunium and plutonium atom have been calculated and discussed in detail. These properties are mainly originated from f- states at uranium sites while p- states at post transition sites.
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پنڈت کشن پرشاد کول

پنڈت کشن پرشاد کول
پنڈت کشن پرشادکول لکھنؤ کے رہنے والے اور لکھنؤ کی پُرانی تہذیب اور روایات کی بڑی حسین یادگار تھے، اُردو زبان کے نکتہ سنج ونکتہ شناس، بلند پایہ ادیب اور بڑے صحیح الخیال اورنیک دل بزرگ تھے۔اُردو زبان اوراس کے ساتھ وابستہ کلچر اورتہذیب کے ساتھ اُن کوعشق تھا۔ یوپی میں اُردو کو علاقائی زبان بنانے کے لیے دستخطی مہم کی کامیابی زیادہ ترانھیں کی کوششوں کانتیجہ تھی۔اُردو سے متعلق ہرتحریک میں وہ سرگرمی سے حصّہ لیتے تھے۔ چنانچہ وفات سے کچھ دن پہلے ہی انھوں نے بہار میں اردو کانفرنس کی صدارت کی تھی اوراس میں بڑا اچھا خطبہ پڑھا تھا۔ اگرچہ وہ اب خود دنیا میں نہیں ہیں لیکن اپنے کردار وعمل اوراپنے اخلاق کاایک ایسا نقش چھوڑگئے ہیں کہ نئی نسلیں اُن سے بہت کچھ سبق حاصل کرسکتی ہیں۔ [ فروری ۱۹۵۵ء]

 

The Influence of Theory of Planned Behavior and Technology Acceptance Models on Behavioral Intentions in Online Grocery Shopping in Pekanbaru City

This study was carried out to investigate the impact of integrating two theories on consumer behavior, namely the Theory of Planned Behavior (TPB) and Technology Acceptance Models (TAM), on the consumer behavior intention in online food shopping in the city of Pekanbaru. A descriptive quantitative method was employed in this research, utilizing purposive sampling techniques. The study involved 174 female respondents aged 18 and above, residing in the city of Pekanbaru, who had previously engaged in online food shopping. The analysis of data was performed utilizing the Structural Equation Modeling-Partial Least Squares (SEM-PLS) approach. The results indicated that both the perceived usefulness (PU) and perceived ease of use have a notable impact on attitude (ATT). Furthermore, behavioral intention was significantly influenced by attitude (ATT), subjective norm (SN), and perceived behavioral control (PBC). The originality of this study resides in combining the Theory of Planned Behavior (TPB) and Technology Acceptance Models (TAM) within the specific context of online food shopping in the city of Pekanbaru. This study is expected to contribute to the field of consumer behavior, especially the behavior of consumers in Pekanbaru regarding online food shopping.

Development of Tomato Breeding Material Through Mutagenesis and its Evaluation for Thermotolerance.

Tomato (Solanum lycopersicum L.) belongs to the family Solanaceae. It is consumed in differing ways, including crude, a fixing in numerous dishes, sauces and beverages. It thrives well in temperature 10 °C to 30 °C. The mean temperatures below 16 °C and above 35 °C are not desirable. In summer season temperature rises in most regions of province Punjab (Pakistan) up to 45 °C that affects the germination, pollination, fruit setting and development that ultimately lowers the yield and quality. There are different techniques used to select stress tolerant lines of tomato Viz. mutagenesis is one of a major technique to create variants of tomato which can be more stress tolerant. The present study was conducted on tomato cultivar "Rio Grande". Research experiments conducted were: 1) Development of mutant population through physical and chemical mutagens. 2) Screening of mutated M1 population for thermotolernace. 3) Raising of M2 population and its screening. 4) Assessment of genetic diversity/similarity among screened thermotolerant variants by using heat specific SSRs. EMS and Gamma irradiations were used to induce mutations. Germination percentage was observed in first experiment and concluded that only two doses of gamma irradiation 5 kr and 10 kr and EMS i.e. 4 mM, 8 mM, 16 mM, 24 mM and 32 mM showed germination and all remaining doses/concentration proved lethality in tomato seed germination. This mutated population was transferred into the field for development of M1 population and screening for thermotolerence was done by using different traits (membrane stability Index%, Cell viability, RWC, proline 2 contents, morphological, reproductive and fruit related traits). On the basis of all studied traits populations developed through gamma irradiation 5 kr and EMS 4 mM, 8 mM, 16 mM and 24 mM were selected to raise M2 population assessed for thermo tolerance by using same traits as in M1 population. On the basis of results obtained for thermo tolerance related traits, twenty four mutants were selected and raised as M3 population for assessing their genetic diversity/similarity with parent Rio Grande. On the basis of results obtained from all experiments, suitable doses and concentrations of physical and chemical mutagens were identified for mutation in tomato. Membrane stability index percentage and proline contents were found as suitable selection criteria for heat tolerance studies in tomato crop. Twenty four mutants were identified with enhanced thermotolerance which proved genetically distant from their parent “Rio Grande”.