Search or add a thesis

Advanced Search (Beta)
Home > Ion Beam Irradiation-Induced Effects in Metal Nanowires Used for Transparent Electrodes

Ion Beam Irradiation-Induced Effects in Metal Nanowires Used for Transparent Electrodes

Thesis Info

Access Option

External Link

Author

Honey, Shehla

Program

PhD

Institute

University of the Punjab

City

Lahore

Province

Punjab

Country

Pakistan

Thesis Completing Year

2018

Thesis Completion Status

Completed

Subject

Physics

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/9663/1/Shehla_Honey_Solid_State_Physics_HSR_2018_UoP_Punjab_11.09.2018.pdf

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676726521938

Asian Research Index Whatsapp Chanel
Asian Research Index Whatsapp Chanel

Join our Whatsapp Channel to get regular updates.

Similar


Metal Nanowires (MNWs) are promising as a kind of novel conducting materials for next generation of nanodevices for space applications either in form of interconnecting conducting nanowires to integrate nanodevices or for Transparent Electrodes (TEs) for solar cells. In this work, ions irradiation induced damage study of MNWs e.g., (Ag, Cu) at different energies, doses and ions species is presented. After irradiation, samples are characterized using scanning electron microscopy (SEM), x-ray diffraction (XRD) and transmission electron microscopy (TEM). The results of irradiated samples are then compared with un-irradiated samples. Finally, a database of effects of ions irradiation on MNWs is made. This database will be useful for future design of MNWs based devices to be used under harsh conditions such as upper space. Mechanism of damage creation in MNWs by ions irradiation is explained by collision cascade effect and thermal spike model. Moreover, MeV proton and argon beam irradiation-induced nanowelding technique to fabricate X-, Y-, II- and T-shaped molecular junctions between Ag-NWs is presented. These nanowires are irradiated by 2.5MeV protons at a dose of 5x1015ions/cm2 and 3.5 MeV argons at dose of 5x1016 at room temperature. Transmission electron microscopy (TEM), scanning electron microscopy (SEM) and x-ray diffraction (XRD) results reveal that nano-welding of Ag-NWs is achieved with stable crystal structure. Thereafter, a random two-dimensional large scale network of Ag-NWs is fabricated by 3 MeV proton ion beam irradiation induced welding of Ag-NWs at intersecting positions. Proton ion beam induced network fabrication on large scale is confirmed by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). It is observed that at a beam fluence of 1x1015ions/cm2, perfect X-, II-, and V-shape molecular junctions between Ag-NWs are achieved and ultimately lead to an optimum welded network without distorting the morphology of nanowires. Structure of Ag-NWs remains stable under proton ion beam and networks are optically transparent. The results exhibit that the formation of Ag-NWs network proceed through three steps: ion beam induced thermal spikes lead to local heating of Ag-NWs, formation of simple junctions on small scale, and the formation of large scale network. Furthermore, an important consideration for space applications is that the material should be as radiation hard as possible in order for it to reliably operate for extended periods. Therefore, total dose radiation tolerance of Ag-NWs under proton environment is investigated. Ag-NWs are irradiated with 5 MeV proton ions at different doses ranging from 5x1015 to 8x1016 protons/cm2 and their effect on morphology and structure is studied. It is observed that Ag-NWs remain stable under proton beam irradiation at high doses. In addition, “amorphous Ag-NW have been fabricated from crystalline Ag-NWs using 5 MeV helium (He+) ions beam irradiation. At low beam fluence (5x1015 ion/cm2), few defects are created in Ag-NW with increase in density while increasing He+ ions beam. As dose increases, more damage of the crystalline structure of Ag-NWs is observed. Finally at high dose (5x1016 ions/cm2), the face-centered cubic (FCC) structure of Ag- NWs is transformed into amorphous structure with similar morphology as un-irradiated Ag-NWs. Phase transformation of crystalline Ag-NWs upon irradiation with 5 MeV He+ ions is observed through high resolution transmission electron microscopy (HRTEM).” Besides, the effect of g-irradiations on the structural and morphological properties of copper nanowires (Cu-NWs) within the g fluencies varying from 6 to 25 kGy are also studied. At 9 kGy, the Cu-NWs start to join, forming perfect X-, V-, II-, and Y-shaped molecular junctions. Further increasing the g fluence up to 15 kGy cause the Cu-NWs to fuse and form larger diameter NWs. At the highest fluence of 25 kGy, Cu-NWs converted into a continuous Cu thin film. However, x-ray diffraction (XRD) results show that the structure of the Cu-NWs remains stable even after converting into a thin film. The formation of cuprite (CuO) phases is observed at higher fluencies. The mechanism of forming welded networks of Cu-NWs and Cu thin films is explained via the thermal spike model.
Loading...
Loading...

Similar Books

Loading...

Similar Chapters

Loading...

Similar News

Loading...

Similar Articles

Loading...

Similar Article Headings

Loading...

۔مراتب اختر کی غزل گوئی

مراتب اختر کی غزل گوئی

                ساٹھ کی دہائی میں شہرت حاصل کرنے والے شعراء میں ایک اہم نام مراتب اختر کا بھی ہے۔ مراتب اختر منفرد لہجے کے جدید شاعر تھے۔ جنھوں نے غزل میں نئے نئے تجربات کیے۔ یہ ایک حقیقت ہے کہ شاعری کی اساس اسلوب ہے اور اسلوب کی خوبصورتی الفاظ کے انتخاب کی مرہونِ منت ہے۔ لفظوں کا خوبصورت انتخاب کلام میں آہنگ اور موسیقیت پیدا کرتا ہے اور الفاظ کی لطافت، فصاحت اور موزونیت ایک دوسرے کے ساتھ تقابل کے بعد واضح ہوتی ہے۔ مراتب اختر اُردو غزل میں جدیدیت کے علم برداروں میں اہم مقام رکھتے ہیں اور اُن کا اسلوب اس کا آئینہ دار ہے۔ انھوں نے اپنے کلام میں جدیدلفظیات کو استعمال کر کے جدید غزل کو ایک نیا رنگ دیا۔ مراتب اختر کی شاعری کے حوالے سے معروف شاعر اور نقاد افتخارجالبؔ لکھتے ہیں:

مراتب اختر نے جو شاعری کی ہے۔ اس میں رکھ رکھائو، ڈِکش کی ملائمت، نفاست اور مروّجہ شعریت نہیں ہے۔ سب کچھ اُکھڑا اُکھڑا دکھائی دیتا ہے۔ یہ خرابیاں کہ امکان سے نابلد، اندھے اور بے مغز لوگوںں کو گراں گزرتی ہیں۔ درحقیقت مراتب اختر کی خالص خوبیاں ہیں۔(۱)

                مراتب اختر شاعری کے میدان میں لکیر کے فقیر ثابت نہ ہوئے بلکہ انھوں نے عرصہ دراز سے استعمال ہونے والے سادہ الفاظ کو اس نئے رنگ سے اپنی شاعری میں استعمال کیا کہ وہ اُن کی پہچان بن گئے۔ مراتب اختر کے حوالے سے وحید اطہر اپنے مضمون ’’مراتب اختر اور ہم‘‘ میں یوں رقم طراز ہیں:

مراتب اختر کے ہاں گل و بلبل کی شاعری نہیں ہے۔وہ زمانے کے ساتھ ساتھ رہا۔ اس نے دیومالائی قصے کہانیوں کا سہارا نہیں لیا۔ وہ جیتے...

Hybrid Warfare and its Impacts on Pakistan

In modern times, the conventional means of warfare are increasingly becoming less usable. However, the states are involved in waging hybrid warfare to the maximum to fulfill their foreign policy goals. In nuclearized South Asia, direct war between India and Pakistan seems unlikely given that both the states know that escalation could lead to nuclear catastrophe in the region. This compels both the states to find other means of warfare to undermine each other’s interests. India wants to weaken Pakistan so that it may abandon claim on Indian occupied Jammu and Kashmir. For that, India is using all tools of hybrid warfare against Pakistan. In this context, this paper aims at to unearth India’s hybrid warfare in the region and its implications for Pakistan. The main focus of the paper is to explain tools and methods of India hybrid warfare. At the same time the research also tries to unravel few other case studies. It also notes how Pakistan can counter hybrid threats posed by its arch rival.

Distribution, Genetic and Biochemical Characterization of Wild and Cultivated Olive in Azad Jammu and Kashmir

The floristic composition within 25 stands was recorded from 390 m to 2158 m on gentle slopes of Azad Jammu and Kashmir. There were 87 plants species of 39 families; Poaceae, Astraceae and Papilionaceae were important families in the investigated area. Four plant associations, Olea-Berberis-Punica, Olea-Olea-Dodonaea, Olea-Olea Zanthoxylum and Olea-Ficus-Ricinus were recorded by cluster analysis and Detrendent correspondence analysis (DCA) technique. The dense Olea forests were found within the range of 390-1500 m, considered as potential sites, whereas the sparse populations were found beyond the range of 1500 m. This area has suitable climatic conditions to support cultivation of olive in Azad Jammu and Kashmir. Wild (O. cuspidata) and cultivated olive (O. europaea) grow in northern regions of Pakistan and Azad Jammu and Kashmir are expected to have considerable inter and intra-species genetic variability due to adaptation to the various environmental conditions. In present study the genetic relationship was investigated in wild and cultivated olive populations growing in Azad Jammu and Kashmir by using four primer combinations during amplified fragment length polymorphism (AFLP) analysis. Genetic relationships were displayed in a dendrogram based on Unweighted Pair Group Method (UPGMA) and Principal Component Analysis (PCA). Four clusters were clearly separating wild and cultivated olive populations from each other indicates that the Olea cuspidata (wild) and Olea europaea (cultivated) were divergent. The insightful difference between wild and cultivated populations and the close relationship among Olea europaea accessions had confirmed that the cultivated olive did not develop locally but were introduced from abroad, propagated by grafting on local wild olive. Moreover, analysis of cultivated olive showed that they are probably from same population with common ancestory. In the actual application, the measurement of genetic variation among these populations is needed to guide the on-going grafting of Olea europaea while ensuring that a substantial genetic diversity is preserved within the study area. For the Olea europaea nursery industry, this study can be useful to eliminate duplication of the clones and ensure diversity of the propagated clones for grafting on Olea cuspidata.