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Synthesis, Characterization and Application of Fluorescent Brightening Agents on Synthetic Fibers

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Author

Mahwish, ,

Program

PhD

Institute

University of Karachi

City

Karachi

Province

Sindh

Country

Pakistan

Thesis Completing Year

2015

Thesis Completion Status

Completed

Subject

Chemistry

Language

English

Link

http://prr.hec.gov.pk/jspui/bitstream/123456789/13281/1/Mehwish_Applied_Chemistry_2015_Univ_of_Karachi_15.6.206.docx

Added

2021-02-17 19:49:13

Modified

2024-03-24 20:25:49

ARI ID

1676727504086

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Names like “Fluorescent Whitening Agents”, “Optical Brighteners” and “Optical Bleach” are all used to describe the product “Fluorescent Brightening Agents”, but the term “FBAs” is preferably used because it has been taken from Chemical Abstracts. FBA is an organic compound. Most commercially available fluorescent brighteners are stilbene based having symmetric or asymmetric structures. Symmetric compounds are derivatives of 4,4''-bis(1,3,5-triazinylamino)stilbene-2,2''-disulfonic acid prepared by the reaction of 1mole of 4,4''-diaminostilbene-2,2''-disulfonic acid with 2 mole of cyanuric chloride. Synthesis of asymmetric compounds is also more expensive than symmetric compounds that’s why asymmetric compounds never become commercially important. The change in structure will effect on solubility, substrate affinity and on other properties. In this research stilbene based FBAs were synthesized from reaction of 4,4''-diaminostilbene-2,2''-disulfonic acid with 2,4,6-trichloro-1,3,5-triazine and then substitution of different nucleophilic amines on triazine moiety yielded FBAs. Substitution of different electron donating, electron withdrawing and solubilizing groups on these nucleophilic amines has great effect on properties of FBAs. The newly synthesized FBAs were characterized by UV-Visible, IR, Mass and 1H-NMR spectral data and applied on polyamide and cotton fabrics. All FBAs were light yellow in color. The performance of these FBAs was evaluated by different fastness measurements. All FBAs showed fastness grating in the range of 4-5 that is good quality performance. The color of FBAs were characterized by color co-ordinates L*, a*, b*, which in turn provide very powerful tool of objective color measurement, practiced in a modern industrial world. 3D-QSPR technique with the help of CoMFA model was applied on our synthesized FBAs.In this research we correlate CoMFA model with the absorbtivity of FBAs. A negative correlation has been observed because FBAs had low value of absorbtivity. The reason behind that is FBAs are light colored compounds they do not form covalent linkage with the fiber as like reactive dyes. They just adsorb on the fiber that’s why they had low value of absorbtivity.
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والدہ، ڈاکٹر جوہر قاضی

ڈاکٹر جوہر قاضی والدہ
تعزیت
رُکن مجلسِ ادارت اعزازی ماہنامہ برہان ڈاکٹر جوہر قاضی کی والدہ محترمہ ۵؍ جولائی ۱۹۹۷ء کو شنبہ کی صبح مختصر علالت کے بعد دہلی میں اپنی رہائش گاہ پر انتقال کرگئیں۔انا ﷲ وانا الیہ راجعون۔
مرحومہ کی عمر تقریباً پچھترسال تھی۔ وہ ایک دین دار خاتون تھیں۔ان کی وفات بلاشبہ ڈاکٹر جوہر قاضی،اہل خاندان اوران کے رفیق سفر جناب حکیم قاضی محمدیٰسین عالم صاحب مدیر اعلیٰ ماہنامہ ’راحت وصحت‘ کے لیے ایک عظیم صدمہ ہے۔ میں اپنی طرف سے اور کارکنانِ ادارہ کی طرف سے دعا کرتا ہوں کہ اﷲ تعالیٰ مرحومہ کواپنے جوار رحمت میں جگہ دے اور لواحقین کو صبرجمیل عطا فرمائے۔
ہم جناب ڈاکٹر جوہرقاضی اوران کے اہل خاندان کے اس غم میں برابر کے شریک ہیں۔مجھے بذاتِ خوداس سانحۂ ارتحال سے سخت جھٹکا لگاہے۔
[عمیدالرحمن عثمانی،جولائی واگست ۱۹۹۷ء]

 

ظہرین کے اوقات میں اشتراکات: اسلام کے پانچ بڑے فقہی مکاتب فکر کے تناظر میں

In India scholar‘s had played incredible role for ‘Hadith’. The service of Indian Muslim scholars about methodology of Hadith is much more than other countries scholars in the last 50 years of thirteenth century. Their name should be written in golden words. There services about the methodology of Hadith are great one. Muslim scholars of sub-continent had taken keen interest in the research work of Hadith and its explanation. If we evaluate the theological history of India that ; Shah Waiullah ‘and his family worked day and night for expansion and publishing of’ Hadith  ‘ Thirteenth century of hire is called a century of revolution as concerned for Hadith. Because in that era proper theological institutions were set up and very strong institutions had spread knowledge and study of methodology of Hadith

Study of Divalent and Trivalent Cations Substitution on X-Type Hexagonal Ferrites

In the present research work four X-type hexagonal ferrites series with compositions Ba2-xMgxCo2-ySryFe28O46, Sr2-xCaxNi2-yBayFe28O46, SrBaCu2-xCoxCryFe28-yO46 and SrBaZn2-xNixAlyFe28-yO46 where x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and y= 0.0, 0.1, 0.2, 0.3, 0.4, 0.5 have been synthesized by sol gel auto-combustion method. The characterization of the entire compositions has been done by thermo-gravimetric analysis (TGA), x-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), dielectric measurements, vibrating sample magnetometer (VSM) and scanning electron microscopy (SEM). Thermo-gravimetric investigation reveals that hexagonal phase begins to form at a temperature ~1050 ºC and is completed at 1250 ºC for X-type hexagonal phase formation, which is also complimented by the XRD studies. The average crystalline sizes of four compositions were found within the range of 19-40nm. The variations in the lattice constants were in accordance with the dissimilarity in ionic radii of the host and substituted ions. FTIR analysis of entire synthesized compositions was observed in the range of 400-800cm-1 which indicated the existence of two vibrational bands appeared due to the octahedral and tetrahedral stretching vibrations. SEM images showed the hexagonal platelets structure which is best for microwave applications. The dielectric measurements of all synthesized composition were evaluated as the function of frequency and their behavior was described on the basis of Maxwell-Wagner and Koop’s theories. The obtained results revealed that dielectric constants, tan loss and the conductivities were found to be increased with the increased ratio of Mg-Sr, Ca-Ba and Co-Cr substituted synthesized samples. While the decreased trend in the dielectric constant for Ni-Al substituted samples are observed. Electric modulus studies were done to examine the relaxation behavior for all samples. To ensure the influence on magnetic characteristics of different divalent and trivalent cations substitution in synthesized compositions, vibrating sample magnetometer (VSM) was used. The variation in saturation magnetization, coercivity and remanence was observed on the basis of allocated cations in the different hexagonal lattice sites. The linear increase in saturation magnetization, remanence and coercivity in Co-Cr and Ni-Al substituted hexaferrite made them useful as permanent magnets while the decrease in saturation magnetization and coercivity in Mg-Sr and Ca-Ba substituted samples proposed these materials best for magnetic recording media as well as for microwave devices.